Library Search Compound Report Data Path : W:\HPCHEM1\MSVOA_U\DATA\VU050818\ Data File : VU023746.D Acq On : 08 May 2018 19:36 Operator : MD/SY Sample : J2725-13 20X Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Method : W:\HPCHEM1\MSVOA_U\METHOD\SOMULM050818WMA.M Quant Title : VOC Analysis TIC Library : C:\DATABASE\NIST11.L TIC Integration Parameters: LSCINT.P ********************************************************************* Peak Number 1 Sulfur dioxide Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 1.30 40.14 ug/L 642939 1,4-Difluorobenzene 5.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Sulfur dioxide 64 O2S 007446-09-5 83 2 Aminomethanesulfonic acid 111 CH5NO3S 013881-91-9 74 3 L-Alanine, 3-sulfo- 169 C3H7NO5S 000498-40-8 9 4 Aminomethanesulfonic acid 111 CH5NO3S 013881-91-9 9 5 Ethene, 1,1-difluoro- 64 C2H2F2 000075-38-7 4 ********************************************************************* Peak Number 2 Benzene, 1-ethyl-3-methyl- Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 10.69 2.63 ug/L 56632 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzene, 1-ethyl-3-methyl- 120 C9H12 000620-14-4 95 2 Benzene, 1-ethyl-4-methyl- 120 C9H12 000622-96-8 95 3 Benzene, 1-ethyl-3-methyl- 120 C9H12 000620-14-4 95 4 Benzene, 1-ethyl-2-methyl- 120 C9H12 000611-14-3 94 5 Benzene, 1-ethyl-3-methyl- 120 C9H12 000620-14-4 91 ********************************************************************* Peak Number 3 Mesitylene Concentration Rank 18 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 10.78 2.80 ug/L 60220 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Mesitylene 120 C9H12 000108-67-8 97 2 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 95 3 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 95 4 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 94 5 Mesitylene 120 C9H12 000108-67-8 94 ********************************************************************* Peak Number 4 Benzene, 1,2,3-trimethyl- Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 11.15 9.41 ug/L 202706 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 95 2 Mesitylene 120 C9H12 000108-67-8 94 3 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 94 4 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 94 5 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 93 ********************************************************************* Peak Number 5 3-Hydroxyphenylacetylene Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 11.40 50.95 ug/L 1097700 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 3-Hydroxyphenylacetylene 118 C8H6O 010401-11-3 91 2 Benzofuran 118 C8H6O 000271-89-6 90 3 Benzofuran 118 C8H6O 000271-89-6 87 4 Benzofuran 118 C8H6O 000271-89-6 87 5 2H-Cyclopenta[d]pyridazine 118 C7H6N2 000270-64-4 64 ********************************************************************* Peak Number 6 Indane Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 11.77 56.56 ug/L 1218500 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Indane 118 C9H10 000496-11-7 95 2 Indane 118 C9H10 000496-11-7 91 3 Benzene, 2-propenyl- 118 C9H10 000300-57-2 80 4 Tetracyclo[3.3.1.0(2,8).0(4,6)]-... 118 C9H10 1000191-13-7 80 5 Benzene, 1-ethenyl-4-methyl- 118 C9H10 000622-97-9 74 ********************************************************************* Peak Number 7 Indene Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 11.99 79.79 ug/L 1718890 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Indene 116 C9H8 000095-13-6 97 2 Indene 116 C9H8 000095-13-6 96 3 Indene 116 C9H8 000095-13-6 95 4 3-Methylphenylacetylene 116 C9H8 000766-82-5 91 5 Benzene, 1-propynyl- 116 C9H8 000673-32-5 91 ********************************************************************* Peak Number 8 Benzofuran, 7-methyl- Concentration Rank 14 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 12.60 5.61 ug/L 120934 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzofuran, 7-methyl- 132 C9H8O 017059-52-8 96 2 Benzofuran, 2-methyl- 132 C9H8O 004265-25-2 94 3 Benzofuran, 2-methyl- 132 C9H8O 004265-25-2 94 4 Cinnamaldehyde, (E)- 132 C9H8O 014371-10-9 91 5 3-Phenyl-2-propyn-1-ol 132 C9H8O 001504-58-1 91 ********************************************************************* Peak Number 9 Benzofuran, 2-methyl- Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 12.70 16.25 ug/L 350029 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzofuran, 2-methyl- 132 C9H8O 004265-25-2 94 2 Benzofuran, 7-methyl- 132 C9H8O 017059-52-8 94 3 Benzofuran, 2-methyl- 132 C9H8O 004265-25-2 94 4 Benzofuran, 2-methyl- 132 C9H8O 004265-25-2 91 5 2-Propenal, 3-phenyl- 132 C9H8O 000104-55-2 91 ********************************************************************* Peak Number 10 Benzene, (1-methyl-1-propen... Concentration Rank 17 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.13 2.82 ug/L 60674 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzene, (1-methyl-1-propenyl)-,... 132 C10H12 000768-00-3 83 2 1H-Indene, 2,3-dihydro-5-methyl- 132 C10H12 000874-35-1 81 3 3-Phenylbut-1-ene 132 C10H12 000934-10-1 80 4 Benzene, (1-methyl-1-propenyl)-,... 132 C10H12 000767-99-7 80 5 Benzene, 1-methyl-4-(2-propenyl)- 132 C10H12 003333-13-9 74 ********************************************************************* Peak Number 11 Benzo[c]thiophene Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.86 33.56 ug/L 723093 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzo[c]thiophene 134 C8H6S 000270-82-6 97 2 Benzo[b]thiophene 134 C8H6S 000095-15-8 95 3 Benzo[b]thiophene 134 C8H6S 000095-15-8 94 4 Cyclopenta[c]thiapyran 134 C8H6S 000270-63-3 94 5 Benzo[b]thiophene 134 C8H6S 000095-15-8 91 ********************************************************************* Peak Number 12 Naphthalene, 1-methyl- Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 15.07 26.70 ug/L 575196 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Naphthalene, 2-methyl- 142 C11H10 000091-57-6 96 2 Naphthalene, 2-methyl- 142 C11H10 000091-57-6 96 3 Naphthalene, 1-methyl- 142 C11H10 000090-12-0 96 4 Naphthalene, 2-methyl- 142 C11H10 000091-57-6 94 5 Naphthalene, 1-methyl- 142 C11H10 000090-12-0 94 ********************************************************************* Peak Number 13 Biphenyl Concentration Rank 20 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 15.61 2.53 ug/L 54569 1,4-Dichlorobenzene-d4 11.49 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Biphenyl 154 C12H10 000092-52-4 95 2 Biphenyl 154 C12H10 000092-52-4 94 3 Biphenyl 154 C12H10 000092-52-4 94 4 Biphenyl 154 C12H10 000092-52-4 93 5 Biphenyl 154 C12H10 000092-52-4 90