Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_U\DATA\VU051418\ Data File : VU023847.D Acq On : 14 May 2018 10:48 Operator : MD/SY Sample : VSTDCCC010 Misc : 25.0mL/MSVOA_U/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 15 04:14:09 2018 Quant Method : W:\HPCHEM1\MSVOA_U\METHOD\524U043018DW.M Quant Title : METHOD 524.2 VOLATILES DRINKING WATER QLast Update : Thu May 03 10:23:54 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Fluorobenzene 5.75 96 40696 1.00 ug/l 0.00 System Monitoring Compounds 57) 4-Bromofluorobenzene 10.31 95 15209 1.14 ug/l 0.00 Spiked Amount 1.000 Recovery = 114.00% 68) 1,2-Dichlorobenzene-d4 11.86 152 16058 1.24 ug/l 0.00 Spiked Amount 1.000 Recovery = 124.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 141260 10.690 ug/l 99 3) Chloromethane 1.33 50 161744 10.565 ug/l 100 4) Vinyl Chloride 1.40 62 161662 11.007 ug/l 99 5) Bromomethane 1.63 94 72799 9.271 ug/l 98 6) Chloroethane 1.70 64 93263 11.407 ug/l 99 7) Trichlorofluoromethane 1.89 101 192405 11.413 ug/l 99 8) 1,1,2-Trichloro-1,2,2-trif 2.29 101 116137 11.213 ug/l 97 9) 1,1-Dichloroethene 2.29 96 106377 11.062 ug/l 96 10) Iodomethane 2.41 142 81637 7.140 ug/l 98 11) Allyl Chloride 2.60 41 200992 11.371 ug/l 99 12) Acrylonitrile 2.94 53 50816 25.607 ug/l 94 13) Acetone 2.33 43 241050 143.120 ug/l 99 14) Carbon Disulfide 2.48 76 355686 11.243 ug/l 100 15) Methylene Chloride 2.70 84 114928 10.493 ug/l 97 16) trans-1,2-Dichloroethene 2.98 96 111968 10.868 ug/l 99 17) 1,1-Dichloroethane 3.45 63 214703 10.580 ug/l 100 18) 2-Butanone 4.28 43 237490 87.262 ug/l 100 19) Cyclohexane 4.99 56 166561 9.499 ug/l 93 20) Methylcyclohexane 6.42 83 183614 10.264 ug/l 99 21) 2,2-Dichloropropane 4.23 77 161841 10.057 ug/l 99 22) cis-1,2-Dichloroethene 4.23 96 118774 10.653 ug/l 97 23) Diethyl Ether 2.11 59 89382 11.370 ug/l 97 24) tert-Butyl Alcohol 2.85 59 87185 147.071 ug/l # 81 25) Methyl tert-Butyl Ether 3.00 73 268959 11.130 ug/l 99 26) Bromochloromethane 4.55 128 50841 11.540 ug/l 94 27) Chloroform 4.68 83 202177 10.579 ug/l 100 28) 1,1,1-Trichloroethane 4.92 97 165913 10.583 ug/l 99 29) 1,1-Dichloropropene 5.14 75 161530 10.501 ug/l 99 30) Carbon Tetrachloride 5.14 117 144822 10.980 ug/l 100 31) Isopropyl Ether 3.58 45 330188 9.639 ug/l 97 32) Ethyl-t-butyl ether 4.08 59 279547 9.550 ug/l 98 33) Tert-Amyl methyl ether 5.59 73 239430 9.664 ug/l 99 34) Propionitrile 4.34 54 44130 56.948 ug/l # 94 35) Benzene 5.39 78 454304 9.937 ug/l 99 36) 1,2-Dichloroethane 5.41 62 123947 9.585 ug/l 100 37) Trichloroethene 6.19 130 115925 9.445 ug/l 97 38) 1,2-Dichloropropane 6.44 63 122842 9.796 ug/l 97 39) Methacrylonitrile 4.55 41 39163 9.884 ug/l 95 40) Methyl acrylate 4.43 55 54156 9.854 ug/l 97 41) Tetrahydrofuran 4.65 42 40995 20.079 ug/l 97 42) 1-Chlorobutane 5.07 56 229984 10.315 ug/l 99 43) Dibromomethane 6.56 93 56005 10.384 ug/l 98 44) Bromodichloromethane 6.76 83 139980 10.329 ug/l 99 45) 4-Methyl-2-Pentanone 7.47 43 362050 56.800 ug/l 99 46) t-1,4-Dichloro-2-butene 10.52 75 48370m 25.666 ug/l 47) Methyl methacrylate 6.63 69 107511 22.001 ug/l 97 48) Ethyl methacrylate 8.02 69 92061 10.775 ug/l 100 49) Toluene 7.64 92 276715 10.478 ug/l 99 50) t-1,3-Dichloropropene 7.89 75 125741 10.870 ug/l 99 51) cis-1,3-Dichloropropene 7.27 75 157518 10.462 ug/l 99 52) 1,1,2-Trichloroethane 8.07 97 77730 10.129 ug/l 98 53) 1,3-Dichloropropane 8.25 76 139318 10.212 ug/l 99 54) 2-Hexanone 8.37 43 341646 78.682 ug/l 99 55) Dibromochloromethane 8.48 129 91462 10.877 ug/l 100 56) 1,2-Dibromoethane 8.59 107 68719 10.393 ug/l 99 58) Tetrachloroethene 8.23 164 112622 10.064 ug/l 96 59) Chlorobenzene 9.12 112 294366 10.413 ug/l 99 60) 1,1,1,2-Tetrachloroethane 9.21 131 100407 10.457 ug/l 99 61) Pentachloroethane 11.10 117 77925 11.434 ug/l 99 62) Hexachloroethane 12.15 117 78595 12.016 ug/l 99 63) Ethyl Benzene 9.25 91 514514 10.950 ug/l 100 64) m/p-Xylenes 9.38 106 406358 22.425 ug/l 99 65) o-Xylene 9.78 106 195904 11.227 ug/l 100 66) Styrene 9.80 104 332898 11.568 ug/l 100 67) Bromoform 9.96 173 51846 11.806 ug/l 100 69) Isopropylbenzene 10.17 105 503209 11.195 ug/l 99 70) 1,1,2,2-Tetrachloroethane 10.46 83 96756 11.187 ug/l 99 71) 1,2,3-Trichloropropane 10.50 75 60701 9.806 ug/l # 94 72) Bromobenzene 10.45 156 124806 11.153 ug/l 98 73) n-propylbenzene 10.59 120 146941 11.826 ug/l 99 74) 2-Chlorotoluene 10.66 126 126408 11.506 ug/l 93 75) 1,3,5-Trimethylbenzene 10.78 105 450763 11.903 ug/l 100 76) 4-Chlorotoluene 10.78 126 132303 11.624 ug/l 98 77) tert-Butylbenzene 11.10 119 423632 11.941 ug/l 99 78) 1,2,4-Trimethylbenzene 11.15 105 462470 12.096 ug/l 99 79) sec-Butylbenzene 11.33 105 590717 11.891 ug/l 100 80) Nitrobenzene 12.87 77 16468 46.179 ug/l 96 81) p-Isopropyltoluene 11.48 119 511491 12.529 ug/l 99 82) 1,3-Dichlorobenzene 11.42 146 256415 11.480 ug/l 99 83) 1,4-Dichlorobenzene 11.51 146 260222 11.666 ug/l 100 84) n-Butylbenzene 11.89 91 489461 12.281 ug/l 100 85) 1,2-Dichlorobenzene 11.88 146 233977 11.603 ug/l 100 86) 1,2-Dibromo-3-Chloropropan 12.66 75 16006 13.113 ug/l 97 87) 1,2,4-Trichlorobenzene 13.51 180 173900 11.923 ug/l 98 88) Hexachlorobutadiene 13.70 225 110087 12.448 ug/l 98 89) Naphthalene 13.75 128 261235 11.893 ug/l 100 90) 1,2,3-Trichlorobenzene 13.99 180 160942 11.755 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed