Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_U\DATA\VU051418\ Data File : VU023850.D Acq On : 14 May 2018 12:58 Operator : MD/SY Sample : VU0514WBSD01 Misc : 25.0mL/MSVOA_U/WATER ALS Vial : 5 Sample Multiplier: 1 Quant Time: May 15 04:28:48 2018 Quant Method : W:\HPCHEM1\MSVOA_U\METHOD\524U043018DW.M Quant Title : METHOD 524.2 VOLATILES DRINKING WATER QLast Update : Thu May 03 10:23:54 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Fluorobenzene 5.75 96 41002 1.00 ug/l 0.00 System Monitoring Compounds 57) 4-Bromofluorobenzene 10.31 95 14422 1.08 ug/l 0.00 Spiked Amount 1.000 Recovery = 108.00% 68) 1,2-Dichlorobenzene-d4 11.87 152 15504 1.19 ug/l 0.00 Spiked Amount 1.000 Recovery = 119.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 28966 2.176 ug/l 100 3) Chloromethane 1.33 50 31607 2.049 ug/l 96 4) Vinyl Chloride 1.40 62 32354 2.186 ug/l 98 5) Bromomethane 1.63 94 16390 2.072 ug/l 93 6) Chloroethane 1.70 64 19744 2.397 ug/l 97 7) Trichlorofluoromethane 1.89 101 39907 2.349 ug/l 98 8) 1,1,2-Trichloro-1,2,2-trif 2.29 101 23627 2.264 ug/l 96 9) 1,1-Dichloroethene 2.29 96 21438 2.213 ug/l 94 10) Iodomethane 2.41 142 13079 1.135 ug/l 99 11) Allyl Chloride 2.60 41 39216 2.202 ug/l 91 12) Acrylonitrile 2.94 53 10407 5.205 ug/l 94 13) Acetone 2.32 43 48168 28.386 ug/l 100 14) Carbon Disulfide 2.48 76 71834 2.254 ug/l 98 15) Methylene Chloride 2.70 84 24652 2.234 ug/l 95 16) trans-1,2-Dichloroethene 2.99 96 23176 2.233 ug/l 98 17) 1,1-Dichloroethane 3.45 63 46650 2.282 ug/l 100 18) 2-Butanone 4.28 43 46813 17.072 ug/l 99 19) Cyclohexane 5.00 56 30123 1.705 ug/l 95 20) Methylcyclohexane 6.42 83 31907 1.770 ug/l 97 21) 2,2-Dichloropropane 4.23 77 34414 2.123 ug/l 99 22) cis-1,2-Dichloroethene 4.23 96 23946 2.132 ug/l 99 23) Diethyl Ether 2.10 59 17248 2.178 ug/l 97 24) tert-Butyl Alcohol 2.83 59 17128 28.677 ug/l # 85 25) Methyl tert-Butyl Ether 3.00 73 53277 2.188 ug/l 95 26) Bromochloromethane 4.55 128 10408 2.345 ug/l 96 27) Chloroform 4.68 83 43400 2.254 ug/l 96 28) 1,1,1-Trichloroethane 4.92 97 35352 2.238 ug/l 98 29) 1,1-Dichloropropene 5.14 75 31024 2.002 ug/l 99 30) Carbon Tetrachloride 5.14 117 29078 2.188 ug/l 95 31) Isopropyl Ether 3.58 45 67985 1.970 ug/l 93 32) Ethyl-t-butyl ether 4.08 59 52844 1.792 ug/l 97 33) Tert-Amyl methyl ether 5.59 73 42792 1.714 ug/l 99 34) Propionitrile 4.34 54 8735 11.188 ug/l # 88 35) Benzene 5.39 78 93362 2.027 ug/l 100 36) 1,2-Dichloroethane 5.41 62 27103 2.080 ug/l 97 37) Trichloroethene 6.19 130 23665 1.914 ug/l 98 38) 1,2-Dichloropropane 6.44 63 24393 1.931 ug/l 99 39) Methacrylonitrile 4.55 41 7409 1.856 ug/l 96 40) Methyl acrylate 4.43 55 10499 1.896 ug/l 98 41) Tetrahydrofuran 4.65 42 7659 3.723 ug/l 98 42) 1-Chlorobutane 5.07 56 43817 1.951 ug/l 98 43) Dibromomethane 6.56 93 11286 2.077 ug/l 99 44) Bromodichloromethane 6.76 83 29120 2.133 ug/l 100 45) 4-Methyl-2-Pentanone 7.47 43 65990 10.275 ug/l 98 46) t-1,4-Dichloro-2-butene 10.52 75 8168m 4.302 ug/l 47) Methyl methacrylate 6.63 69 18589 3.776 ug/l 96 48) Ethyl methacrylate 8.02 69 15129 1.758 ug/l 92 49) Toluene 7.64 92 51732 1.944 ug/l 97 50) t-1,3-Dichloropropene 7.89 75 22770 1.954 ug/l 98 51) cis-1,3-Dichloropropene 7.27 75 28687 1.891 ug/l 98 52) 1,1,2-Trichloroethane 8.07 97 15852 2.050 ug/l 98 53) 1,3-Dichloropropane 8.25 76 28058 2.041 ug/l 99 54) 2-Hexanone 8.37 43 59229 13.539 ug/l 94 55) Dibromochloromethane 8.48 129 17503 2.066 ug/l 98 56) 1,2-Dibromoethane 8.59 107 14201 2.132 ug/l 98 58) Tetrachloroethene 8.23 164 22677 2.011 ug/l 96 59) Chlorobenzene 9.12 112 57831 2.030 ug/l 99 60) 1,1,1,2-Tetrachloroethane 9.21 131 20525 2.122 ug/l 100 61) Pentachloroethane 11.10 117 17346 2.526 ug/l 91 62) Hexachloroethane 12.15 117 16165 2.453 ug/l 97 63) Ethyl Benzene 9.25 91 89901 1.899 ug/l 99 64) m/p-Xylenes 9.38 106 70580 3.866 ug/l 99 65) o-Xylene 9.78 106 34831 1.981 ug/l 99 66) Styrene 9.80 104 57024 1.967 ug/l 97 67) Bromoform 9.96 173 9528 2.153 ug/l 93 69) Isopropylbenzene 10.17 105 89023 1.966 ug/l 99 70) 1,1,2,2-Tetrachloroethane 10.46 83 20282 2.327 ug/l 98 71) 1,2,3-Trichloropropane 10.50 75 23665 3.794 ug/l # 76 72) Bromobenzene 10.46 156 24162 2.143 ug/l 96 73) n-propylbenzene 10.59 120 25439 2.032 ug/l 93 74) 2-Chlorotoluene 10.66 126 24140 2.181 ug/l 94 75) 1,3,5-Trimethylbenzene 10.78 105 80183 2.102 ug/l 100 76) 4-Chlorotoluene 10.78 126 25691 2.240 ug/l 96 77) tert-Butylbenzene 11.10 119 78143 2.186 ug/l 99 78) 1,2,4-Trimethylbenzene 11.15 105 81277 2.110 ug/l 99 79) sec-Butylbenzene 11.33 105 109604 2.190 ug/l 100 80) Nitrobenzene 12.88 77 2409 8.746 ug/l # 86 81) p-Isopropyltoluene 11.48 119 89736 2.182 ug/l 98 82) 1,3-Dichlorobenzene 11.42 146 52990 2.355 ug/l 99 83) 1,4-Dichlorobenzene 11.51 146 53141 2.365 ug/l 100 84) n-Butylbenzene 11.90 91 88401 2.201 ug/l 97 85) 1,2-Dichlorobenzene 11.88 146 46803 2.304 ug/l 98 86) 1,2-Dibromo-3-Chloropropan 12.66 75 3048 2.478 ug/l 99 87) 1,2,4-Trichlorobenzene 13.51 180 28946 1.970 ug/l 99 88) Hexachlorobutadiene 13.70 225 22442 2.519 ug/l 98 89) Naphthalene 13.75 128 36507 1.650 ug/l 99 90) 1,2,3-Trichlorobenzene 13.99 180 26947 1.954 ug/l 98 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed