Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_U\DATA\VU051418\ Data File : VU023853.D Acq On : 14 May 2018 15:23 Operator : MD/SY Sample : VSTDCCC010 Misc : 25.0mL/MSVOA_U/WATER ALS Vial : 8 Sample Multiplier: 1 Quant Time: May 15 04:38:12 2018 Quant Method : W:\HPCHEM1\MSVOA_U\METHOD\524U043018DW.M Quant Title : METHOD 524.2 VOLATILES DRINKING WATER QLast Update : Thu May 03 10:23:54 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Fluorobenzene 5.75 96 40978 1.00 ug/l 0.00 System Monitoring Compounds 57) 4-Bromofluorobenzene 10.31 95 15561 1.16 ug/l 0.00 Spiked Amount 1.000 Recovery = 116.00% 68) 1,2-Dichlorobenzene-d4 11.86 152 15796 1.21 ug/l 0.00 Spiked Amount 1.000 Recovery = 121.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 139192 10.461 ug/l 100 3) Chloromethane 1.33 50 152205 9.873 ug/l 99 4) Vinyl Chloride 1.40 62 152654 10.322 ug/l 100 5) Bromomethane 1.63 94 69956 8.848 ug/l 99 6) Chloroethane 1.70 64 91569 11.123 ug/l 99 7) Trichlorofluoromethane 1.89 101 189954 11.190 ug/l 99 8) 1,1,2-Trichloro-1,2,2-trif 2.29 101 112412 10.779 ug/l 97 9) 1,1-Dichloroethene 2.29 96 102438 10.579 ug/l 96 10) Iodomethane 2.41 142 84516 7.340 ug/l 97 11) Allyl Chloride 2.60 41 196493 11.040 ug/l 96 12) Acrylonitrile 2.94 53 48694 24.369 ug/l 95 13) Acetone 2.32 43 215903 127.307 ug/l 97 14) Carbon Disulfide 2.48 76 348235 10.932 ug/l 100 15) Methylene Chloride 2.70 84 115130 10.439 ug/l 97 16) trans-1,2-Dichloroethene 2.98 96 111801 10.777 ug/l 99 17) 1,1-Dichloroethane 3.44 63 217063 10.622 ug/l 99 18) 2-Butanone 4.28 43 228054 83.218 ug/l 100 19) Cyclohexane 4.99 56 160089 9.067 ug/l 93 20) Methylcyclohexane 6.42 83 173916 9.655 ug/l 99 21) 2,2-Dichloropropane 4.23 77 161936 9.993 ug/l 99 22) cis-1,2-Dichloroethene 4.23 96 117679 10.482 ug/l 97 23) Diethyl Ether 2.10 59 84403 10.662 ug/l 97 24) tert-Butyl Alcohol 2.84 59 84416 141.420 ug/l # 83 25) Methyl tert-Butyl Ether 3.00 73 261103 10.730 ug/l 99 26) Bromochloromethane 4.55 128 49327 11.119 ug/l 94 27) Chloroform 4.68 83 203675 10.584 ug/l 99 28) 1,1,1-Trichloroethane 4.92 97 166972 10.577 ug/l 100 29) 1,1-Dichloropropene 5.14 75 156088 10.077 ug/l 98 30) Carbon Tetrachloride 5.14 117 143009 10.768 ug/l 98 31) Isopropyl Ether 3.58 45 325032 9.423 ug/l 94 32) Ethyl-t-butyl ether 4.08 59 278701 9.456 ug/l 98 33) Tert-Amyl methyl ether 5.59 73 223406 8.955 ug/l 99 34) Propionitrile 4.34 54 42254 54.152 ug/l # 90 35) Benzene 5.39 78 452263 9.824 ug/l 99 36) 1,2-Dichloroethane 5.41 62 123925 9.518 ug/l 100 37) Trichloroethene 6.19 130 115674 9.360 ug/l 98 38) 1,2-Dichloropropane 6.44 63 120204 9.520 ug/l 100 39) Methacrylonitrile 4.55 41 37615 9.428 ug/l 96 40) Methyl acrylate 4.43 55 53626 9.690 ug/l 98 41) Tetrahydrofuran 4.65 42 38319 18.639 ug/l 99 42) 1-Chlorobutane 5.07 56 225382 10.039 ug/l 99 43) Dibromomethane 6.56 93 53531 9.857 ug/l 99 44) Bromodichloromethane 6.76 83 136931 10.034 ug/l 99 45) 4-Methyl-2-Pentanone 7.47 43 345429 53.819 ug/l 99 46) t-1,4-Dichloro-2-butene 10.52 75 46758m 24.640 ug/l 47) Methyl methacrylate 6.63 69 100610 20.447 ug/l 98 48) Ethyl methacrylate 8.02 69 88617 10.300 ug/l 99 49) Toluene 7.64 92 272857 10.261 ug/l 99 50) t-1,3-Dichloropropene 7.89 75 119706 10.277 ug/l 99 51) cis-1,3-Dichloropropene 7.27 75 146192 9.643 ug/l 99 52) 1,1,2-Trichloroethane 8.07 97 74658 9.662 ug/l 99 53) 1,3-Dichloropropane 8.25 76 136004 9.901 ug/l 99 54) 2-Hexanone 8.37 43 319762 73.136 ug/l 99 55) Dibromochloromethane 8.48 129 89234 10.539 ug/l 99 56) 1,2-Dibromoethane 8.59 107 68077 10.225 ug/l 98 58) Tetrachloroethene 8.23 164 111918 9.932 ug/l 98 59) Chlorobenzene 9.12 112 288344 10.130 ug/l 98 60) 1,1,1,2-Tetrachloroethane 9.21 131 100303 10.375 ug/l 99 61) Pentachloroethane 11.10 117 74650 10.878 ug/l 97 62) Hexachloroethane 12.15 117 78190 11.872 ug/l 99 63) Ethyl Benzene 9.25 91 501832 10.607 ug/l 100 64) m/p-Xylenes 9.38 106 414239 22.703 ug/l 99 65) o-Xylene 9.78 106 192681 10.966 ug/l 98 66) Styrene 9.80 104 331328 11.434 ug/l 100 67) Bromoform 9.96 173 49458 11.184 ug/l 99 69) Isopropylbenzene 10.17 105 495688 10.952 ug/l 100 70) 1,1,2,2-Tetrachloroethane 10.46 83 93916 10.783 ug/l 100 71) 1,2,3-Trichloropropane 10.50 75 59124 9.485 ug/l # 94 72) Bromobenzene 10.46 156 122716 10.890 ug/l 99 73) n-propylbenzene 10.59 120 146731 11.728 ug/l 99 74) 2-Chlorotoluene 10.66 126 125630 11.356 ug/l 94 75) 1,3,5-Trimethylbenzene 10.78 105 451351 11.836 ug/l 99 76) 4-Chlorotoluene 10.78 126 130669 11.402 ug/l 98 77) tert-Butylbenzene 11.10 119 414293 11.597 ug/l 99 78) 1,2,4-Trimethylbenzene 11.15 105 464388 12.063 ug/l 100 79) sec-Butylbenzene 11.33 105 590984 11.814 ug/l 99 80) Nitrobenzene 12.87 77 16970 47.204 ug/l 99 81) p-Isopropyltoluene 11.48 119 502899 12.234 ug/l 99 82) 1,3-Dichlorobenzene 11.42 146 255607 11.365 ug/l 100 83) 1,4-Dichlorobenzene 11.51 146 260579 11.602 ug/l 98 84) n-Butylbenzene 11.89 91 488126 12.163 ug/l 99 85) 1,2-Dichlorobenzene 11.88 146 232727 11.462 ug/l 100 86) 1,2-Dibromo-3-Chloropropan 12.66 75 14855 12.086 ug/l 99 87) 1,2,4-Trichlorobenzene 13.51 180 164253 11.184 ug/l 98 88) Hexachlorobutadiene 13.70 225 107073 12.024 ug/l 100 89) Naphthalene 13.75 128 247284 11.181 ug/l 100 90) 1,2,3-Trichlorobenzene 13.99 180 155320 11.267 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed