Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024499.D Acq On : 13 Jun 2018 11:33 Operator : MD/SY Sample : VSTDICC001 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: Jun 13 13:17:46 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:03:59 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 200290 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 299246 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 277275 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 155341 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 0.00 65 0d 0.00 ug/l Spiked Amount 50.000 Recovery = 0.00% 35) Dibromofluoromethane 0.00 113 0d 0.00 ug/l Spiked Amount 50.000 Recovery = 0.00% 50) Toluene-d8 0.00 98 0d 0.00 ug/l Spiked Amount 50.000 Recovery = 0.00% 62) 4-Bromofluorobenzene 0.00 95 0d 0.00 ug/l Spiked Amount 50.000 Recovery = 0.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 2932 0.966 ug/l 96 3) Chloromethane 1.33 50 3207 0.907 ug/l 95 4) Vinyl Chloride 1.40 62 2986 0.758 ug/l # 82 5) Bromomethane 1.63 94 1307 0.604 ug/l 92 6) Chloroethane 1.70 64 2795 1.049 ug/l # 88 7) Trichlorofluoromethane 1.89 101 4810 0.899 ug/l 92 8) Diethyl Ether 2.10 74 2174 1.017 ug/l 58 9) 1,1,2-Trichlorotrifluoroet 2.29 101 3170 1.065 ug/l # 84 12) 1,1-Dichloroethene 2.29 96 2342 0.840 ug/l 95 14) Allyl chloride 2.59 41 4449 0.940 ug/l 99 15) Acrylonitrile 2.94 53 7568 3.761 ug/l 95 16) Acetone 2.32 43 10620 4.195 ug/l 94 17) Carbon Disulfide 2.48 76 8119 0.946 ug/l 99 18) Methyl Acetate 2.62 43 4382 0.871 ug/l 97 19) Methyl tert-butyl Ether 3.00 73 9575 1.093 ug/l 97 20) Methylene Chloride 2.71 84 3554 1.022 ug/l 89 21) trans-1,2-Dichloroethene 2.99 96 2911 0.973 ug/l 93 22) Diisopropyl ether 3.58 45 9103 0.955 ug/l # 85 23) Vinyl Acetate 3.53 43 39997 5.709 ug/l 96 24) 1,1-Dichloroethane 3.45 63 5318 0.891 ug/l # 94 25) 2-Butanone 4.27 43 11660 3.851 ug/l 93 26) 2,2-Dichloropropane 4.23 77 5399 1.186 ug/l 82 27) cis-1,2-Dichloroethene 4.24 96 3220m 0.990 ug/l 28) Bromochloromethane 4.55 49 2011 0.920 ug/l # 80 29) Tetrahydrofuran 4.64 42 8191 4.741 ug/l 94 30) Chloroform 4.68 83 5535 0.915 ug/l 88 31) Cyclohexane 5.00 56 9141 1.544 ug/l # 57 32) 1,1,1-Trichloroethane 4.91 97 5326 1.095 ug/l 93 36) 1,1-Dichloropropene 5.14 75 4062 0.951 ug/l # 73 37) Ethyl Acetate 4.40 43 3366 0.703 ug/l # 93 38) Carbon Tetrachloride 5.13 117 4282 1.053 ug/l 91 39) Methylcyclohexane 6.42 83 5442 1.179 ug/l 97 40) Benzene 5.40 78 11206 0.871 ug/l 92 41) Methacrylonitrile 4.55 41 1701m 0.634 ug/l 42) 1,2-Dichloroethane 5.41 62 4359 0.884 ug/l 84 43) Isopropyl Acetate 5.56 43 7451 1.022 ug/l # 89 44) Trichloroethene 6.20 130 3452 1.029 ug/l 78 45) 1,2-Dichloropropane 6.44 63 2925 0.846 ug/l 94 46) Dibromomethane 6.57 93 1939 0.847 ug/l 97 47) Bromodichloromethane 6.76 83 4016 0.906 ug/l # 95 48) Methyl methacrylate 6.63 41 3454 0.966 ug/l # 83 49) 1,4-Dioxane 6.63 88 1414 18.748 ug/l # 64 51) 4-Methyl-2-Pentanone 7.46 43 21678 4.120 ug/l 96 52) Toluene 7.65 92 7458 0.976 ug/l 96 53) t-1,3-Dichloropropene 7.89 75 4290 0.931 ug/l 94 54) cis-1,3-Dichloropropene 7.28 75 5108 1.016 ug/l 95 55) 1,1,2-Trichloroethane 8.08 97 3335 1.018 ug/l # 91 56) Ethyl methacrylate 8.02 69 4786 1.121 ug/l 96 57) 1,3-Dichloropropane 8.25 76 5028 0.893 ug/l 91 58) 2-Chloroethyl Vinyl ether 7.14 63 8668 3.946 ug/l 99 59) 2-Hexanone 8.37 43 17971 4.269 ug/l 91 60) Dibromochloromethane 8.48 129 4096 1.232 ug/l 92 61) 1,2-Dibromoethane 8.59 107 3373 0.984 ug/l 97 64) Tetrachloroethene 8.23 164 2965 1.076 ug/l # 90 65) Chlorobenzene 9.12 112 8032 0.995 ug/l 91 66) 1,1,1,2-Tetrachloroethane 9.21 131 3059 1.104 ug/l 85 67) Ethyl Benzene 9.26 91 14453 1.111 ug/l 90 68) m/p-Xylenes 9.38 106 10822 2.184 ug/l 97 69) o-Xylene 9.79 106 5312 1.163 ug/l 96 70) Styrene 9.80 104 8522 1.096 ug/l 95 71) Bromoform 9.97 173 2835 1.186 ug/l # 95 73) Isopropylbenzene 10.17 105 14125 1.319 ug/l 97 74) N-amyl acetate 10.02 43 6422 1.325 ug/l # 85 75) 1,1,2,2-Tetrachloroethane 10.46 83 4967 1.069 ug/l 90 76) 1,2,3-Trichloropropane 10.50 75 3427 1.052 ug/l 84 77) Bromobenzene 10.46 156 3528 1.190 ug/l 95 78) n-propylbenzene 10.59 91 16077 1.211 ug/l 94 79) 2-Chlorotoluene 10.67 91 10098 1.253 ug/l 100 80) 1,3,5-Trimethylbenzene 10.78 105 12626 1.390 ug/l 96 81) trans-1,4-Dichloro-2-buten 10.53 75 1390m 0.905 ug/l 82) 4-Chlorotoluene 10.78 91 11274 1.206 ug/l 99 83) tert-Butylbenzene 11.10 119 11739 1.328 ug/l 100 84) 1,2,4-Trimethylbenzene 11.15 105 12165 1.326 ug/l 97 85) sec-Butylbenzene 11.33 105 14275 1.286 ug/l 94 86) p-Isopropyltoluene 11.48 119 13209 1.347 ug/l 92 87) 1,3-Dichlorobenzene 11.43 146 6367 1.117 ug/l 98 88) 1,4-Dichlorobenzene 11.51 146 6352m 1.065 ug/l 89) n-Butylbenzene 11.90 91 10695 1.108 ug/l 96 90) Hexachloroethane 12.15 117 2720 1.547 ug/l 81 91) 1,2-Dichlorobenzene 11.89 146 6658 1.168 ug/l 96 92) 1,2-Dibromo-3-Chloropropan 12.66 75 1177 1.241 ug/l 83 93) 1,2,4-Trichlorobenzene 13.52 180 2732 0.812 ug/l 98 94) Hexachlorobutadiene 13.70 225 2145 1.073 ug/l 93 95) Naphthalene 13.76 128 6956 0.756 ug/l # 89 96) 1,2,3-Trichlorobenzene 14.00 180 2694 0.792 ug/l 92 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed