Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024500.D Acq On : 13 Jun 2018 11:56 Operator : MD/SY Sample : VSTDICC005 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 3 Sample Multiplier: 1 Quant Time: Jun 13 13:11:56 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:03:59 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 195345 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 303052 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 280445 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 158455 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.32 65 16702 4.32 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.64% 35) Dibromofluoromethane 4.89 113 13172 4.23 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.46% 50) Toluene-d8 7.57 98 46850 4.03 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.06% 62) 4-Bromofluorobenzene 10.31 95 17743 4.19 ug/l 0.00 Spiked Amount 50.000 Recovery = 8.38% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 12061 4.073 ug/l 98 3) Chloromethane 1.33 50 12647 3.666 ug/l 95 4) Vinyl Chloride 1.40 62 13415 3.493 ug/l 100 5) Bromomethane 1.62 94 6301 2.985 ug/l 100 6) Chloroethane 1.70 64 8053 3.099 ug/l 96 7) Trichlorofluoromethane 1.89 101 20143 3.862 ug/l 93 8) Diethyl Ether 2.10 74 7783 3.733 ug/l 82 9) 1,1,2-Trichlorotrifluoroet 2.29 101 12212 4.206 ug/l # 93 10) Methyl Iodide 2.41 142 4246 2.307 ug/l # 91 11) Tert butyl alcohol 2.83 59 22890 31.153 ug/l 96 12) 1,1-Dichloroethene 2.28 96 12171 4.475 ug/l 89 13) Acrolein 2.19 56 11383 14.883 ug/l 98 14) Allyl chloride 2.60 41 22032 4.775 ug/l 93 15) Acrylonitrile 2.94 53 38071 19.400 ug/l 99 16) Acetone 2.32 43 41539 16.822 ug/l 99 17) Carbon Disulfide 2.48 76 36329 4.342 ug/l 99 18) Methyl Acetate 2.62 43 17485 3.563 ug/l 99 19) Methyl tert-butyl Ether 3.00 73 42125 4.929 ug/l 100 20) Methylene Chloride 2.70 84 13524 3.986 ug/l 97 21) trans-1,2-Dichloroethene 2.99 96 12171 4.171 ug/l 98 22) Diisopropyl ether 3.57 45 42115 4.530 ug/l # 86 23) Vinyl Acetate 3.53 43 185010 27.074 ug/l 99 24) 1,1-Dichloroethane 3.45 63 23602 4.054 ug/l 97 25) 2-Butanone 4.27 43 56253 19.051 ug/l 96 26) 2,2-Dichloropropane 4.23 77 22412 5.050 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 14571 4.595 ug/l 100 28) Bromochloromethane 4.55 49 10792 5.062 ug/l 90 29) Tetrahydrofuran 4.64 42 35533 21.088 ug/l 96 30) Chloroform 4.68 83 24034 4.075 ug/l 99 31) Cyclohexane 5.00 56 25753 4.461 ug/l # 88 32) 1,1,1-Trichloroethane 4.92 97 21786 4.592 ug/l 97 36) 1,1-Dichloropropene 5.14 75 18143 4.195 ug/l 95 37) Ethyl Acetate 4.39 43 19044 3.927 ug/l # 89 38) Carbon Tetrachloride 5.14 117 20081 4.876 ug/l 98 39) Methylcyclohexane 6.42 83 21450 4.590 ug/l 95 40) Benzene 5.39 78 51570 3.956 ug/l 97 41) Methacrylonitrile 4.55 41 10502 3.864 ug/l # 96 42) 1,2-Dichloroethane 5.41 62 19202 3.846 ug/l 95 43) Isopropyl Acetate 5.55 43 33034 4.473 ug/l 96 44) Trichloroethene 6.19 130 14144 4.164 ug/l 99 45) 1,2-Dichloropropane 6.44 63 13658 3.899 ug/l 99 46) Dibromomethane 6.56 93 9774 4.214 ug/l 95 47) Bromodichloromethane 6.76 83 19522 4.351 ug/l # 98 48) Methyl methacrylate 6.63 41 16278 4.496 ug/l 96 49) 1,4-Dioxane 6.62 88 6064 79.393 ug/l # 78 51) 4-Methyl-2-Pentanone 7.46 43 106169 19.926 ug/l 97 52) Toluene 7.64 92 32799 4.240 ug/l 98 53) t-1,3-Dichloropropene 7.89 75 20597 4.414 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 22013 4.323 ug/l 99 55) 1,1,2-Trichloroethane 8.07 97 12601 3.797 ug/l 94 56) Ethyl methacrylate 8.02 69 21683 5.013 ug/l 96 57) 1,3-Dichloropropane 8.25 76 22364 3.924 ug/l 99 58) 2-Chloroethyl Vinyl ether 7.13 63 42363 19.043 ug/l 95 59) 2-Hexanone 8.36 43 85118 19.968 ug/l 99 60) Dibromochloromethane 8.48 129 15829 4.701 ug/l 99 61) 1,2-Dibromoethane 8.59 107 15039 4.332 ug/l 99 64) Tetrachloroethene 8.23 164 13962 5.008 ug/l 98 65) Chlorobenzene 9.12 112 36609 4.486 ug/l 99 66) 1,1,1,2-Tetrachloroethane 9.21 131 14186 5.064 ug/l 99 67) Ethyl Benzene 9.26 91 63907 4.856 ug/l 97 68) m/p-Xylenes 9.38 106 49256 9.826 ug/l 96 69) o-Xylene 9.78 106 24735 5.353 ug/l 94 70) Styrene 9.80 104 39411 5.010 ug/l 98 71) Bromoform 9.96 173 12764 5.279 ug/l # 95 73) Isopropylbenzene 10.17 105 63738 5.835 ug/l 98 74) N-amyl acetate 10.02 43 30047 6.077 ug/l 95 75) 1,1,2,2-Tetrachloroethane 10.46 83 20438 4.314 ug/l 98 76) 1,2,3-Trichloropropane 10.50 75 19256m 5.794 ug/l 77) Bromobenzene 10.46 156 16104 5.324 ug/l 93 78) n-propylbenzene 10.59 91 75667 5.587 ug/l 96 79) 2-Chlorotoluene 10.66 91 43538 5.296 ug/l 97 80) 1,3,5-Trimethylbenzene 10.78 105 55557 5.997 ug/l 99 81) trans-1,4-Dichloro-2-buten 10.51 75 7782m 4.967 ug/l 82) 4-Chlorotoluene 10.78 91 50997 5.347 ug/l 98 83) tert-Butylbenzene 11.10 119 53481 5.931 ug/l 98 84) 1,2,4-Trimethylbenzene 11.15 105 56228 6.006 ug/l 99 85) sec-Butylbenzene 11.33 105 66144 5.842 ug/l 97 86) p-Isopropyltoluene 11.48 119 58336 5.830 ug/l 98 87) 1,3-Dichlorobenzene 11.42 146 28681 4.933 ug/l 99 88) 1,4-Dichlorobenzene 11.51 146 29793 4.895 ug/l 98 89) n-Butylbenzene 11.90 91 50235 5.102 ug/l 96 90) Hexachloroethane 12.15 117 11278 6.287 ug/l 97 91) 1,2-Dichlorobenzene 11.88 146 29119 5.009 ug/l 97 92) 1,2-Dibromo-3-Chloropropan 12.66 75 5526 5.714 ug/l 94 93) 1,2,4-Trichlorobenzene 13.51 180 15864 4.620 ug/l 96 94) Hexachlorobutadiene 13.70 225 9879 4.843 ug/l 100 95) Naphthalene 13.75 128 44133 4.700 ug/l 98 96) 1,2,3-Trichlorobenzene 13.99 180 15680 4.519 ug/l 97 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed