Quantitation Report (QT Reviewed) Data Path : Z:\voasrv\HPCHEM1\MSVOA_U\Data\VU061318\ Data File : VU024501.D Acq On : 13 Jun 2018 12:19 Operator : MD/SY Sample : VSTDICC020 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: Jun 13 13:13:11 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:03:59 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 198881 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 311978 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 294986 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 169294 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 65695 16.68 ug/l 0.00 Spiked Amount 50.000 Recovery = 33.36% 35) Dibromofluoromethane 4.89 113 51947 16.21 ug/l 0.00 Spiked Amount 50.000 Recovery = 32.42% 50) Toluene-d8 7.57 98 190597 15.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 31.84% 62) 4-Bromofluorobenzene 10.31 95 73533 16.85 ug/l 0.00 Spiked Amount 50.000 Recovery = 33.70% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 48875 16.213 ug/l 99 3) Chloromethane 1.33 50 49358 14.052 ug/l 100 4) Vinyl Chloride 1.41 62 50179 12.832 ug/l 95 5) Bromomethane 1.63 94 25539 11.885 ug/l 99 6) Chloroethane 1.70 64 29694 11.226 ug/l 97 7) Trichlorofluoromethane 1.89 101 78541 14.791 ug/l 98 8) Diethyl Ether 2.10 74 29140 13.726 ug/l 85 9) 1,1,2-Trichlorotrifluoroet 2.29 101 47123 15.942 ug/l 97 10) Methyl Iodide 2.41 142 31101 16.595 ug/l 99 11) Tert butyl alcohol 2.82 59 81691 109.204 ug/l 97 12) 1,1-Dichloroethene 2.29 96 45154 16.307 ug/l 95 13) Acrolein 2.20 56 41132 52.822 ug/l 98 14) Allyl chloride 2.60 41 81886 17.430 ug/l 97 15) Acrylonitrile 2.94 53 158616 79.388 ug/l 99 16) Acetone 2.32 43 173681 69.087 ug/l 98 17) Carbon Disulfide 2.48 76 142299 16.703 ug/l 99 18) Methyl Acetate 2.62 43 74594 14.931 ug/l 96 19) Methyl tert-butyl Ether 3.00 73 168057 19.313 ug/l 96 20) Methylene Chloride 2.71 84 52077 15.075 ug/l 98 21) trans-1,2-Dichloroethene 2.99 96 49275 16.584 ug/l 96 22) Diisopropyl ether 3.58 45 167772 17.723 ug/l 92 23) Vinyl Acetate 3.53 43 744862 107.064 ug/l 99 24) 1,1-Dichloroethane 3.45 63 96159 16.224 ug/l 99 25) 2-Butanone 4.26 43 243329 80.943 ug/l 97 26) 2,2-Dichloropropane 4.23 77 89129 19.725 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 55976 17.338 ug/l 98 28) Bromochloromethane 4.55 49 44282 20.402 ug/l 92 29) Tetrahydrofuran 4.64 42 148142 86.355 ug/l 97 30) Chloroform 4.68 83 95215 15.856 ug/l 98 31) Cyclohexane 5.00 56 90422 15.384 ug/l 97 32) 1,1,1-Trichloroethane 4.92 97 88187 18.259 ug/l 96 36) 1,1-Dichloropropene 5.14 75 70987 15.944 ug/l 96 37) Ethyl Acetate 4.38 43 85268 17.082 ug/l # 97 38) Carbon Tetrachloride 5.14 117 79289 18.702 ug/l 100 39) Methylcyclohexane 6.42 83 88970 18.496 ug/l 96 40) Benzene 5.39 78 206838 15.413 ug/l 100 41) Methacrylonitrile 4.55 41 46278 16.542 ug/l 98 42) 1,2-Dichloroethane 5.41 62 78799 15.332 ug/l 99 43) Isopropyl Acetate 5.55 43 138322 18.194 ug/l 98 44) Trichloroethene 6.19 130 57825 16.538 ug/l 94 45) 1,2-Dichloropropane 6.44 63 55715 15.448 ug/l 97 46) Dibromomethane 6.56 93 39006 16.337 ug/l 97 47) Bromodichloromethane 6.76 83 76999 16.668 ug/l 99 48) Methyl methacrylate 6.63 41 67277 18.051 ug/l 99 49) 1,4-Dioxane 6.62 88 27728 352.644 ug/l 97 51) 4-Methyl-2-Pentanone 7.46 43 441909 80.567 ug/l 99 52) Toluene 7.64 92 128763 16.168 ug/l 98 53) t-1,3-Dichloropropene 7.88 75 86038 17.910 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 90260 17.220 ug/l 97 55) 1,1,2-Trichloroethane 8.07 97 51267 15.005 ug/l 98 56) Ethyl methacrylate 8.02 69 91343 20.513 ug/l 98 57) 1,3-Dichloropropane 8.25 76 90111 15.358 ug/l 98 58) 2-Chloroethyl Vinyl ether 7.13 63 163279 71.296 ug/l 97 59) 2-Hexanone 8.36 43 357269 81.414 ug/l 100 60) Dibromochloromethane 8.48 129 63104 18.203 ug/l 99 61) 1,2-Dibromoethane 8.59 107 57555 16.106 ug/l 97 64) Tetrachloroethene 8.23 164 55748 19.011 ug/l 98 65) Chlorobenzene 9.12 112 145897 16.995 ug/l 100 66) 1,1,1,2-Tetrachloroethane 9.21 131 55533 18.847 ug/l 98 67) Ethyl Benzene 9.25 91 259683 18.761 ug/l 97 68) m/p-Xylenes 9.38 106 198140 37.579 ug/l 98 69) o-Xylene 9.78 106 98668 20.302 ug/l 96 70) Styrene 9.80 104 159899 19.323 ug/l 98 71) Bromoform 9.96 173 51919 20.415 ug/l # 100 73) Isopropylbenzene 10.17 105 264998 22.705 ug/l 99 74) N-amyl acetate 10.01 43 122600 23.207 ug/l 98 75) 1,1,2,2-Tetrachloroethane 10.46 83 86657 17.119 ug/l 99 76) 1,2,3-Trichloropropane 10.50 75 76154m 21.447 ug/l 77) Bromobenzene 10.45 156 65061 20.132 ug/l 99 78) n-propylbenzene 10.59 91 312370 21.588 ug/l 98 79) 2-Chlorotoluene 10.66 91 180544 20.556 ug/l 99 80) 1,3,5-Trimethylbenzene 10.78 105 222581 22.488 ug/l 99 81) trans-1,4-Dichloro-2-buten 10.51 75 32667m 19.517 ug/l 82) 4-Chlorotoluene 10.78 91 209740 20.584 ug/l 100 83) tert-Butylbenzene 11.10 119 217370 22.561 ug/l 99 84) 1,2,4-Trimethylbenzene 11.15 105 230190 23.015 ug/l 100 85) sec-Butylbenzene 11.33 105 274368 22.681 ug/l 98 86) p-Isopropyltoluene 11.48 119 240901 22.534 ug/l 98 87) 1,3-Dichlorobenzene 11.42 146 120700 19.431 ug/l 98 88) 1,4-Dichlorobenzene 11.51 146 119217 18.335 ug/l 99 89) n-Butylbenzene 11.89 91 217149 20.643 ug/l 97 90) Hexachloroethane 12.15 117 45300 23.636 ug/l 99 91) 1,2-Dichlorobenzene 11.88 146 120049 19.327 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 12.66 75 24452 23.664 ug/l 93 93) 1,2,4-Trichlorobenzene 13.51 180 78280 21.336 ug/l 100 94) Hexachlorobutadiene 13.70 225 42364 19.439 ug/l 99 95) Naphthalene 13.75 128 243070 24.228 ug/l 99 96) 1,2,3-Trichlorobenzene 13.99 180 79810 21.527 ug/l 98 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed 82U061318W.M Fri Jun 22 11:49:13 2018