Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024503.D Acq On : 13 Jun 2018 13:05 Operator : MD/SY Sample : VSTDICC100 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 6 Sample Multiplier: 1 Quant Time: Jun 13 13:30:26 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:15:08 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 195580 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 311868 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 299176 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 187056 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 314073 81.11 ug/l 0.00 Spiked Amount 50.000 Recovery = 162.22% 35) Dibromofluoromethane 4.89 113 254696 79.52 ug/l 0.00 Spiked Amount 50.000 Recovery = 159.04% 50) Toluene-d8 7.57 98 932408 77.89 ug/l 0.00 Spiked Amount 50.000 Recovery = 155.78% 62) 4-Bromofluorobenzene 10.31 95 374746 85.90 ug/l 0.00 Spiked Amount 50.000 Recovery = 171.80% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 230228 77.661 ug/l 100 3) Chloromethane 1.33 50 221992 64.265 ug/l 99 4) Vinyl Chloride 1.40 62 242722 63.118 ug/l 98 5) Bromomethane 1.61 94 131557 62.254 ug/l 98 6) Chloroethane 1.69 64 141311 54.323 ug/l 99 7) Trichlorofluoromethane 1.88 101 361651 69.255 ug/l 99 8) Diethyl Ether 2.10 74 130767 62.638 ug/l 87 9) 1,1,2-Trichlorotrifluoroet 2.28 101 222248 76.459 ug/l 98 10) Methyl Iodide 2.41 142 217703 118.123 ug/l 99 11) Tert butyl alcohol 2.83 59 347956 472.998 ug/l 99 12) 1,1-Dichloroethene 2.28 96 211583 77.699 ug/l 94 13) Acrolein 2.19 56 194279 253.706 ug/l 99 14) Allyl chloride 2.59 41 385677 83.480 ug/l 97 15) Acrylonitrile 2.94 53 736096 374.638 ug/l 99 16) Acetone 2.32 43 793100 320.802 ug/l 99 17) Carbon Disulfide 2.48 76 675699 80.653 ug/l 99 18) Methyl Acetate 2.62 43 350833 71.409 ug/l 98 19) Methyl tert-butyl Ether 3.00 73 796449 93.072 ug/l 96 20) Methylene Chloride 2.70 84 242153 71.282 ug/l 97 21) trans-1,2-Dichloroethene 2.99 96 230492 78.885 ug/l 97 22) Diisopropyl ether 3.57 45 779368 83.721 ug/l 98 23) Vinyl Acetate 3.53 43 3547887 518.569 ug/l 99 24) 1,1-Dichloroethane 3.45 63 448293 76.915 ug/l 99 25) 2-Butanone 4.26 43 1126583 381.082 ug/l 97 26) 2,2-Dichloropropane 4.23 77 418809 94.249 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 267096 84.125 ug/l 100 28) Bromochloromethane 4.55 49 203492 95.338 ug/l 89 29) Tetrahydrofuran 4.63 42 672106 398.396 ug/l 97 30) Chloroform 4.68 83 452996 76.709 ug/l 99 31) Cyclohexane 5.00 56 412430 71.355 ug/l 96 32) 1,1,1-Trichloroethane 4.92 97 416490 87.688 ug/l 96 36) 1,1-Dichloropropene 5.14 75 344413 77.385 ug/l 98 37) Ethyl Acetate 4.38 43 400888 80.338 ug/l 97 38) Carbon Tetrachloride 5.14 117 383033 90.380 ug/l 99 39) Methylcyclohexane 6.42 83 420908 87.532 ug/l 95 40) Benzene 5.39 78 984314 73.376 ug/l 99 41) Methacrylonitrile 4.54 41 217154 77.649 ug/l 98 42) 1,2-Dichloroethane 5.41 62 373948 72.787 ug/l 100 43) Isopropyl Acetate 5.55 43 653324 85.966 ug/l 98 44) Trichloroethene 6.19 130 277256 79.323 ug/l 98 45) 1,2-Dichloropropane 6.44 63 263974 73.219 ug/l 99 46) Dibromomethane 6.56 93 187960 78.749 ug/l 98 47) Bromodichloromethane 6.76 83 373188 80.815 ug/l 99 48) Methyl methacrylate 6.63 41 318712 85.544 ug/l 98 49) 1,4-Dioxane 6.62 88 119671 1522.509 ug/l 98 51) 4-Methyl-2-Pentanone 7.46 43 2051613 374.175 ug/l 99 52) Toluene 7.64 92 633526 79.577 ug/l 98 53) t-1,3-Dichloropropene 7.88 75 432910 90.148 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 446031 85.124 ug/l 98 55) 1,1,2-Trichloroethane 8.07 97 252909 74.050 ug/l 99 56) Ethyl methacrylate 8.02 69 435195 97.768 ug/l 99 57) 1,3-Dichloropropane 8.25 76 433449 73.901 ug/l 99 58) 2-Chloroethyl Vinyl ether 7.13 63 865437 378.026 ug/l 96 59) 2-Hexanone 8.36 43 1683447 383.759 ug/l 99 60) Dibromochloromethane 8.48 129 316738 91.399 ug/l 100 61) 1,2-Dibromoethane 8.59 107 284733 79.708 ug/l 99 64) Tetrachloroethene 8.23 164 265873 89.396 ug/l 99 65) Chlorobenzene 9.12 112 717250 82.382 ug/l 99 66) 1,1,1,2-Tetrachloroethane 9.21 131 268812 89.951 ug/l 97 67) Ethyl Benzene 9.25 91 1237463 88.151 ug/l 97 68) m/p-Xylenes 9.38 106 964415 180.350 ug/l 97 69) o-Xylene 9.78 106 477305 96.835 ug/l 94 70) Styrene 9.80 104 796335 94.886 ug/l 98 71) Bromoform 9.96 173 263429 102.130 ug/l # 100 73) Isopropylbenzene 10.17 105 1268995 98.404 ug/l 98 74) N-amyl acetate 10.01 43 626772 107.377 ug/l 97 75) 1,1,2,2-Tetrachloroethane 10.46 83 428904 76.682 ug/l 99 76) 1,2,3-Trichloropropane 10.50 75 375638m 95.743 ug/l 77) Bromobenzene 10.45 156 325578 91.176 ug/l 97 78) n-propylbenzene 10.59 91 1511726 94.554 ug/l 97 79) 2-Chlorotoluene 10.66 91 882619 90.950 ug/l 99 80) 1,3,5-Trimethylbenzene 10.78 105 1097973 100.398 ug/l 99 81) trans-1,4-Dichloro-2-buten 10.51 75 171741m 92.863 ug/l 82) 4-Chlorotoluene 10.78 91 1042536 92.598 ug/l 99 83) tert-Butylbenzene 11.10 119 1063086 99.861 ug/l 99 84) 1,2,4-Trimethylbenzene 11.15 105 1139797 103.137 ug/l 99 85) sec-Butylbenzene 11.33 105 1350654 101.053 ug/l 98 86) p-Isopropyltoluene 11.48 119 1209844 102.422 ug/l 99 87) 1,3-Dichlorobenzene 11.42 146 621206 90.511 ug/l 100 88) 1,4-Dichlorobenzene 11.51 146 624804 86.965 ug/l 99 89) n-Butylbenzene 11.89 91 1120305 96.387 ug/l 97 90) Hexachloroethane 12.15 117 234761 110.861 ug/l 100 91) 1,2-Dichlorobenzene 11.88 146 609339 88.786 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 12.66 75 125520 109.941 ug/l 95 93) 1,2,4-Trichlorobenzene 13.51 180 441586 108.928 ug/l 99 94) Hexachlorobutadiene 13.70 225 219655 91.217 ug/l 98 95) Naphthalene 13.74 128 1363320 122.987 ug/l 99 96) 1,2,3-Trichlorobenzene 13.99 180 440487 107.529 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed