Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024504.D Acq On : 13 Jun 2018 13:28 Operator : MD/SY Sample : VSTDICC150 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 7 Sample Multiplier: 1 Quant Time: Jun 13 13:49:32 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:15:08 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 192535 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 304625 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 301137 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 193059 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 445713 116.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 233.84% 35) Dibromofluoromethane 4.89 113 362857 115.98 ug/l 0.00 Spiked Amount 50.000 Recovery = 231.96% 50) Toluene-d8 7.57 98 1342614 114.83 ug/l 0.00 Spiked Amount 50.000 Recovery = 229.66% 62) 4-Bromofluorobenzene 10.31 95 574678 134.86 ug/l 0.00 Spiked Amount 50.000 Recovery = 269.72% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 342569 117.384 ug/l 99 3) Chloromethane 1.33 50 351149 103.262 ug/l 99 4) Vinyl Chloride 1.40 62 363963 96.143 ug/l 99 5) Bromomethane 1.61 94 163560 78.622 ug/l 99 6) Chloroethane 1.68 64 209993 82.002 ug/l 98 7) Trichlorofluoromethane 1.88 101 537052 104.470 ug/l 98 8) Diethyl Ether 2.10 74 191940 93.394 ug/l 88 9) 1,1,2-Trichlorotrifluoroet 2.28 101 325883 113.885 ug/l 98 10) Methyl Iodide 2.41 142 330991 182.431 ug/l 99 11) Tert butyl alcohol 2.84 59 545290 752.968 ug/l 99 12) 1,1-Dichloroethene 2.28 96 306995 114.520 ug/l 95 13) Acrolein 2.19 56 292902 388.546 ug/l 99 14) Allyl chloride 2.59 41 621655 136.685 ug/l 90 15) Acrylonitrile 2.94 53 1097925 567.630 ug/l 99 16) Acetone 2.32 43 1208120 496.403 ug/l 99 17) Carbon Disulfide 2.47 76 1011413 122.634 ug/l 99 18) Methyl Acetate 2.62 43 513986 106.271 ug/l 98 19) Methyl tert-butyl Ether 3.00 73 1173711 139.327 ug/l 97 20) Methylene Chloride 2.70 84 363048 108.560 ug/l 99 21) trans-1,2-Dichloroethene 2.98 96 342667 119.132 ug/l 97 22) Diisopropyl ether 3.57 45 1146437 125.100 ug/l 98 23) Vinyl Acetate 3.53 43 5193302 771.072 ug/l 99 24) 1,1-Dichloroethane 3.45 63 659738 114.984 ug/l 99 25) 2-Butanone 4.27 43 1695005 582.427 ug/l 98 26) 2,2-Dichloropropane 4.23 77 616139 140.850 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 394624 126.258 ug/l 100 28) Bromochloromethane 4.55 49 283590 134.967 ug/l 88 29) Tetrahydrofuran 4.64 42 986575 594.049 ug/l 97 30) Chloroform 4.68 83 664194 114.251 ug/l 99 31) Cyclohexane 5.00 56 598392 105.166 ug/l 97 32) 1,1,1-Trichloroethane 4.92 97 612410 130.977 ug/l 96 36) 1,1-Dichloropropene 5.14 75 509556 117.212 ug/l 98 37) Ethyl Acetate 4.38 43 591108 121.274 ug/l 96 38) Carbon Tetrachloride 5.14 117 560317 135.355 ug/l 99 39) Methylcyclohexane 6.42 83 627796 133.660 ug/l 96 40) Benzene 5.39 78 1441696 110.027 ug/l 100 41) Methacrylonitrile 4.54 41 324420 118.763 ug/l 99 42) 1,2-Dichloroethane 5.41 62 553343 110.266 ug/l 100 43) Isopropyl Acetate 5.55 43 979224 131.912 ug/l 98 44) Trichloroethene 6.19 130 411617 120.563 ug/l 97 45) 1,2-Dichloropropane 6.44 63 391798 111.257 ug/l 99 46) Dibromomethane 6.56 93 279326 119.812 ug/l 97 47) Bromodichloromethane 6.76 83 552942 122.588 ug/l 98 48) Methyl methacrylate 6.63 41 487206 133.877 ug/l 98 49) 1,4-Dioxane 6.62 88 200874 2616.375 ug/l 98 51) 4-Methyl-2-Pentanone 7.47 43 3176483 593.104 ug/l 98 52) Toluene 7.64 92 943470 121.327 ug/l 98 53) t-1,3-Dichloropropene 7.88 75 662358 141.207 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 667282 130.377 ug/l 98 55) 1,1,2-Trichloroethane 8.07 97 385751 115.631 ug/l 98 56) Ethyl methacrylate 8.02 69 673809 154.973 ug/l 99 57) 1,3-Dichloropropane 8.25 76 652798 113.946 ug/l 98 58) 2-Chloroethyl Vinyl ether 7.13 63 1328598 594.135 ug/l 96 59) 2-Hexanone 8.37 43 2650445 618.561 ug/l 99 60) Dibromochloromethane 8.48 129 486109 143.608 ug/l 100 61) 1,2-Dibromoethane 8.59 107 433928 124.362 ug/l 99 64) Tetrachloroethene 8.23 164 385106 128.643 ug/l 99 65) Chlorobenzene 9.12 112 1099160 125.425 ug/l 100 66) 1,1,1,2-Tetrachloroethane 9.21 131 417723 138.871 ug/l 98 67) Ethyl Benzene 9.25 91 1882404 133.221 ug/l 97 68) m/p-Xylenes 9.38 106 1473528 273.761 ug/l 96 69) o-Xylene 9.78 106 728219 146.779 ug/l 94 70) Styrene 9.80 104 1247481 147.674 ug/l 99 71) Bromoform 9.96 173 430500 165.815 ug/l # 99 73) Isopropylbenzene 10.17 105 1970017 148.015 ug/l 99 74) N-amyl acetate 10.02 43 994659 165.104 ug/l 98 75) 1,1,2,2-Tetrachloroethane 10.46 83 684914 118.645 ug/l 100 76) 1,2,3-Trichloropropane 10.50 75 620897m 153.334 ug/l 77) Bromobenzene 10.46 156 517586 140.440 ug/l 98 78) n-propylbenzene 10.59 91 2359120 142.968 ug/l 97 79) 2-Chlorotoluene 10.66 91 1383608 138.141 ug/l 98 80) 1,3,5-Trimethylbenzene 10.78 105 1717267 152.143 ug/l 100 81) trans-1,4-Dichloro-2-buten 10.51 75 295021m 154.562 ug/l 82) 4-Chlorotoluene 10.78 91 1644711 141.541 ug/l 99 83) tert-Butylbenzene 11.10 119 1676629 152.597 ug/l 100 84) 1,2,4-Trimethylbenzene 11.15 105 1798637 157.693 ug/l 100 85) sec-Butylbenzene 11.33 105 2129487 154.369 ug/l 98 86) p-Isopropyltoluene 11.48 119 1914925 157.072 ug/l 99 87) 1,3-Dichlorobenzene 11.42 146 992516 140.115 ug/l 100 88) 1,4-Dichlorobenzene 11.51 146 995594 134.266 ug/l 100 89) n-Butylbenzene 11.89 91 1783561 148.680 ug/l 97 90) Hexachloroethane 12.15 117 376813 172.409 ug/l 100 91) 1,2-Dichlorobenzene 11.88 146 964467 136.161 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 12.66 75 199898 169.644 ug/l 96 93) 1,2,4-Trichlorobenzene 13.51 180 710428 169.795 ug/l 99 94) Hexachlorobutadiene 13.70 225 350175 140.898 ug/l 100 95) Naphthalene 13.74 128 2157965 188.620 ug/l 100 96) 1,2,3-Trichlorobenzene 13.99 180 694142 164.181 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed