Quantitation Report (QT Reviewed) Data Path : Z:\voasrv\HPCHEM1\MSVOA_U\Data\VU061318\ Data File : VU024505.D Acq On : 13 Jun 2018 13:54 Operator : MD/SY Sample : VSTDICV050 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 8 Sample Multiplier: 1 Quant Time: Jun 13 17:05:41 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:55:26 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 209361 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 320083 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 306834 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 184526 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 168888 49.41 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.82% 35) Dibromofluoromethane 4.89 113 137903 51.91 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.82% 50) Toluene-d8 7.57 98 504755 52.09 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.18% 62) 4-Bromofluorobenzene 10.31 95 199350 51.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.64% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 127180 48.532 ug/l 99 3) Chloromethane 1.33 50 134633 50.287 ug/l 98 4) Vinyl Chloride 1.40 62 133804 48.462 ug/l 98 5) Bromomethane 1.62 94 71804 53.797 ug/l 100 6) Chloroethane 1.70 64 77653 50.339 ug/l 100 7) Trichlorofluoromethane 1.89 101 194757 46.221 ug/l 99 8) Diethyl Ether 2.10 74 71668 49.979 ug/l 88 9) 1,1,2-Trichlorotrifluoroet 2.29 101 125618 48.055 ug/l 99 10) Methyl Iodide 2.41 142 93398 43.041 ug/l 100 11) Tert butyl alcohol 2.82 59 188298 226.523 ug/l 98 12) 1,1-Dichloroethene 2.28 96 117204 49.165 ug/l 91 13) Acrolein 2.19 56 101463 232.440 ug/l 97 14) Allyl chloride 2.60 41 210200 47.489 ug/l 97 15) Acrylonitrile 2.94 53 394004 243.618 ug/l 98 16) Acetone 2.32 43 441718 240.533 ug/l 99 17) Carbon Disulfide 2.48 76 382674 50.132 ug/l 99 18) Methyl Acetate 2.62 43 184382 46.834 ug/l 98 19) Methyl tert-butyl Ether 3.00 73 433870 48.418 ug/l 98 20) Methylene Chloride 2.70 84 134649 46.729 ug/l 98 21) trans-1,2-Dichloroethene 2.99 96 127392 48.519 ug/l 98 22) Diisopropyl ether 3.57 45 420034 47.871 ug/l 97 23) Vinyl Acetate 3.53 43 1932599 245.878 ug/l 99 24) 1,1-Dichloroethane 3.45 63 242928 48.127 ug/l 98 25) 2-Butanone 4.26 43 604503 245.064 ug/l 98 26) 2,2-Dichloropropane 4.23 77 232735 48.558 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 145628 48.244 ug/l 99 28) Bromochloromethane 4.55 49 114112 51.325 ug/l 89 29) Tetrahydrofuran 4.63 42 358918 234.962 ug/l 97 30) Chloroform 4.68 83 246789 48.304 ug/l 100 31) Cyclohexane 5.00 56 227307 50.739 ug/l 97 32) 1,1,1-Trichloroethane 4.92 97 222937 47.188 ug/l 96 36) 1,1-Dichloropropene 5.14 75 189454 50.370 ug/l 99 37) Ethyl Acetate 4.38 43 209691 51.151 ug/l 97 38) Carbon Tetrachloride 5.14 117 207682 50.212 ug/l 99 39) Methylcyclohexane 6.42 83 233808 49.813 ug/l 96 40) Benzene 5.39 78 532500 49.685 ug/l 100 41) Methacrylonitrile 4.54 41 115007 52.033 ug/l 99 42) 1,2-Dichloroethane 5.41 62 202051 49.500 ug/l 100 43) Isopropyl Acetate 5.55 43 343523 48.478 ug/l 98 44) Trichloroethene 6.19 130 150568 49.364 ug/l 98 45) 1,2-Dichloropropane 6.44 63 144397 50.494 ug/l 99 46) Dibromomethane 6.56 93 102474 51.016 ug/l 98 47) Bromodichloromethane 6.76 83 200130 50.035 ug/l 100 48) Methyl methacrylate 6.63 41 171269 49.636 ug/l 99 49) 1,4-Dioxane 6.61 88 65810 975.265 ug/l 97 51) 4-Methyl-2-Pentanone 7.46 43 1091631 245.208 ug/l 98 52) Toluene 7.64 92 342331 49.648 ug/l 99 53) t-1,3-Dichloropropene 7.88 75 235190 52.360 ug/l 100 54) cis-1,3-Dichloropropene 7.27 75 239919 50.126 ug/l 98 55) 1,1,2-Trichloroethane 8.07 97 133628 47.676 ug/l 99 56) Ethyl methacrylate 8.02 69 232061 49.467 ug/l 99 57) 1,3-Dichloropropane 8.25 76 235354 49.777 ug/l 99 58) 2-Chloroethyl Vinyl ether 7.13 63 476624 265.200 ug/l 97 59) 2-Hexanone 8.36 43 886630 243.947 ug/l 99 60) Dibromochloromethane 8.48 129 171753 49.141 ug/l 99 61) 1,2-Dibromoethane 8.59 107 153226 49.117 ug/l 99 64) Tetrachloroethene 8.23 164 145096 49.749 ug/l 98 65) Chlorobenzene 9.12 112 390986 49.880 ug/l 99 66) 1,1,1,2-Tetrachloroethane 9.21 131 145101 48.724 ug/l 98 67) Ethyl Benzene 9.25 91 680368 49.512 ug/l 99 68) m/p-Xylenes 9.38 106 528520 100.161 ug/l 97 69) o-Xylene 9.78 106 257251 49.261 ug/l 95 70) Styrene 9.80 104 426491 49.697 ug/l 99 71) Bromoform 9.96 173 137555 48.596 ug/l # 99 73) Isopropylbenzene 10.17 105 688165 48.575 ug/l 98 74) N-amyl acetate 10.01 43 323163 47.957 ug/l 98 75) 1,1,2,2-Tetrachloroethane 10.46 83 221331 46.621 ug/l 98 76) 1,2,3-Trichloropropane 10.50 75 210914m 51.916 ug/l 77) Bromobenzene 10.45 156 174707 48.711 ug/l 97 78) n-propylbenzene 10.59 91 828791 49.662 ug/l 97 79) 2-Chlorotoluene 10.66 91 486687 49.452 ug/l 100 80) 1,3,5-Trimethylbenzene 10.78 105 595341 48.483 ug/l 99 81) trans-1,4-Dichloro-2-buten 10.51 75 87476m 49.834 ug/l 82) 4-Chlorotoluene 10.78 91 569145 49.687 ug/l 99 83) tert-Butylbenzene 11.10 119 571168 48.356 ug/l 99 84) 1,2,4-Trimethylbenzene 11.15 105 616941 49.301 ug/l 99 85) sec-Butylbenzene 11.33 105 729865 49.364 ug/l 98 86) p-Isopropyltoluene 11.48 119 663805 50.129 ug/l 99 87) 1,3-Dichlorobenzene 11.42 146 329837 49.777 ug/l 99 88) 1,4-Dichlorobenzene 11.51 146 337389 50.588 ug/l 98 89) n-Butylbenzene 11.89 91 619881 52.728 ug/l 97 90) Hexachloroethane 12.15 117 124160 48.065 ug/l 99 91) 1,2-Dichlorobenzene 11.88 146 324063 48.826 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 12.66 75 64890 49.536 ug/l 96 93) 1,2,4-Trichlorobenzene 13.51 180 239248 58.374 ug/l 99 94) Hexachlorobutadiene 13.70 225 120222 52.115 ug/l 99 95) Naphthalene 13.74 128 742748 54.677 ug/l 99 96) 1,2,3-Trichlorobenzene 13.99 180 237051 58.045 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed 82U061318W.M Wed Jun 13 17:06:15 2018