Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024511.D Acq On : 13 Jun 2018 16:36 Operator : MD/SY Sample : VU0613WBS01 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 14 Sample Multiplier: 1 Quant Time: Jun 13 17:22:04 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:55:26 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 192743 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 303840 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 284633 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 166199 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 149070 47.38 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.76% 35) Dibromofluoromethane 4.89 113 123847 49.11 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.22% 50) Toluene-d8 7.57 98 445711 48.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.92% 62) 4-Bromofluorobenzene 10.31 95 175049 47.93 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.86% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 44778 18.561 ug/l 99 3) Chloromethane 1.33 50 47329 19.202 ug/l 98 4) Vinyl Chloride 1.41 62 48149 18.942 ug/l 98 5) Bromomethane 1.63 94 25400 20.671 ug/l 96 6) Chloroethane 1.70 64 27721 18.860 ug/l 98 7) Trichlorofluoromethane 1.89 101 72435 18.673 ug/l 98 8) Diethyl Ether 2.10 74 27018 19.311 ug/l 90 9) 1,1,2-Trichlorotrifluoroet 2.29 101 44294 18.405 ug/l 100 10) Methyl Iodide 2.41 142 25964 16.688 ug/l 98 11) Tert butyl alcohol 2.82 59 65425 85.492 ug/l 98 12) 1,1-Dichloroethene 2.29 96 41089 18.722 ug/l 91 13) Acrolein 2.20 56 35960 89.483 ug/l 96 14) Allyl chloride 2.60 41 74101 18.185 ug/l 94 15) Acrylonitrile 2.94 53 145712 97.864 ug/l 99 16) Acetone 2.32 43 150052 88.754 ug/l 98 17) Carbon Disulfide 2.48 76 132107 18.799 ug/l 100 18) Methyl Acetate 2.62 43 67927 18.742 ug/l 96 19) Methyl tert-butyl Ether 3.00 73 156899 19.019 ug/l 97 20) Methylene Chloride 2.71 84 49483 18.653 ug/l 96 21) trans-1,2-Dichloroethene 2.99 96 44657 18.475 ug/l 98 22) Diisopropyl ether 3.58 45 152589 18.890 ug/l 94 23) Vinyl Acetate 3.53 43 706157 97.588 ug/l 99 24) 1,1-Dichloroethane 3.45 63 88760 19.101 ug/l 98 25) 2-Butanone 4.27 43 218654 96.284 ug/l 96 26) 2,2-Dichloropropane 4.23 77 80313 18.201 ug/l 98 27) cis-1,2-Dichloroethene 4.24 96 53826 19.369 ug/l 98 28) Bromochloromethane 4.55 49 39542 19.319 ug/l 88 29) Tetrahydrofuran 4.64 42 134744 95.814 ug/l 97 30) Chloroform 4.68 83 89405 19.008 ug/l 95 31) Cyclohexane 5.00 56 83098 18.909 ug/l 93 32) 1,1,1-Trichloroethane 4.92 97 79848 18.358 ug/l 96 36) 1,1-Dichloropropene 5.14 75 64832 18.158 ug/l 97 37) Ethyl Acetate 4.38 43 79420 20.409 ug/l # 95 38) Carbon Tetrachloride 5.14 117 75284 19.175 ug/l 100 39) Methylcyclohexane 6.42 83 81541 18.301 ug/l 97 40) Benzene 5.40 78 190943 18.769 ug/l 99 41) Methacrylonitrile 4.55 41 43023 20.506 ug/l 99 42) 1,2-Dichloroethane 5.41 62 73047 18.852 ug/l 98 43) Isopropyl Acetate 5.55 43 127333 18.930 ug/l 98 44) Trichloroethene 6.19 130 53646 18.528 ug/l 95 45) 1,2-Dichloropropane 6.44 63 53643 19.761 ug/l 97 46) Dibromomethane 6.56 93 37083 19.449 ug/l 97 47) Bromodichloromethane 6.76 83 72348 19.055 ug/l 99 48) Methyl methacrylate 6.63 41 63474 19.379 ug/l 99 49) 1,4-Dioxane 6.62 88 21825 340.724 ug/l 98 51) 4-Methyl-2-Pentanone 7.46 43 410511 97.141 ug/l 98 52) Toluene 7.64 92 121988 18.638 ug/l 99 53) t-1,3-Dichloropropene 7.89 75 80159 18.800 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 84167 18.525 ug/l 99 55) 1,1,2-Trichloroethane 8.07 97 48329 18.165 ug/l 98 56) Ethyl methacrylate 8.02 69 86601 19.447 ug/l 100 57) 1,3-Dichloropropane 8.25 76 86634 19.303 ug/l 100 58) 2-Chloroethyl Vinyl ether 7.13 63 170142 99.730 ug/l 97 59) 2-Hexanone 8.36 43 326608 94.667 ug/l 99 60) Dibromochloromethane 8.48 129 59925 18.062 ug/l 99 61) 1,2-Dibromoethane 8.59 107 57120 19.289 ug/l 96 64) Tetrachloroethene 8.23 164 44818 16.565 ug/l 94 65) Chlorobenzene 9.12 112 140175 19.278 ug/l 98 66) 1,1,1,2-Tetrachloroethane 9.21 131 51708 18.718 ug/l 98 67) Ethyl Benzene 9.25 91 243044 19.066 ug/l 100 68) m/p-Xylenes 9.38 106 186040 38.007 ug/l 97 69) o-Xylene 9.78 106 91585 18.906 ug/l 97 70) Styrene 9.80 104 151024 18.971 ug/l 98 71) Bromoform 9.96 173 48755 18.568 ug/l # 97 73) Isopropylbenzene 10.17 105 246271 19.300 ug/l 99 74) N-amyl acetate 10.01 43 116237 19.152 ug/l 97 75) 1,1,2,2-Tetrachloroethane 10.46 83 83214 19.461 ug/l 98 76) 1,2,3-Trichloropropane 10.50 75 78544m 21.465 ug/l 77) Bromobenzene 10.46 156 61298 18.975 ug/l 97 78) n-propylbenzene 10.59 91 288508 19.194 ug/l 97 79) 2-Chlorotoluene 10.66 91 166336 18.765 ug/l 98 80) 1,3,5-Trimethylbenzene 10.78 105 206979 18.715 ug/l 98 81) trans-1,4-Dichloro-2-buten 10.51 75 31178m 19.720 ug/l 82) 4-Chlorotoluene 10.78 91 196319 19.029 ug/l 100 83) tert-Butylbenzene 11.10 119 207998 19.551 ug/l 100 84) 1,2,4-Trimethylbenzene 11.15 105 212920 18.891 ug/l 100 85) sec-Butylbenzene 11.33 105 253257 19.018 ug/l 98 86) p-Isopropyltoluene 11.48 119 221462 18.569 ug/l 97 87) 1,3-Dichlorobenzene 11.42 146 111280 18.646 ug/l 99 88) 1,4-Dichlorobenzene 11.51 146 113983 18.975 ug/l 99 89) n-Butylbenzene 11.89 91 202351 19.110 ug/l 97 90) Hexachloroethane 12.15 117 43298 18.610 ug/l 99 91) 1,2-Dichlorobenzene 11.88 146 112744 18.860 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 12.66 75 22532 19.097 ug/l 92 93) 1,2,4-Trichlorobenzene 13.51 180 75456 20.441 ug/l 99 94) Hexachlorobutadiene 13.70 225 39724 19.119 ug/l 99 95) Naphthalene 13.75 128 228143 19.094 ug/l 99 96) 1,2,3-Trichlorobenzene 13.99 180 76926 20.913 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed