Quantitation Report (QT Reviewed) Data Path : Z:\VOASRV\HPCHEM1\MSVOA_U\DATA\VU061318\ Data File : VU024519.D Acq On : 13 Jun 2018 19:41 Operator : MD/SY Sample : VU0613WBSD01 Misc : 5.0mL/MSVOA_U/WATER ALS Vial : 22 Sample Multiplier: 1 Quant Time: Jun 14 02:51:30 2018 Quant Method : Z:\VOASRV\HPCHEM1\MSVOA_U\METHOD\82U061318W.M Quant Title : SW846 8260 QLast Update : Wed Jun 13 13:55:26 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 4.99 168 186907 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 5.89 114 302076 50.00 ug/l 0.00 63) Chlorobenzene-d5 9.09 117 284742 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 11.49 152 166169 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 5.31 65 147749 48.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.84% 35) Dibromofluoromethane 4.89 113 123483 49.26 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.52% 50) Toluene-d8 7.57 98 450646 49.28 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.56% 62) 4-Bromofluorobenzene 10.31 95 174745 48.13 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.26% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.21 85 43622 18.646 ug/l 100 3) Chloromethane 1.33 50 49266 20.612 ug/l 100 4) Vinyl Chloride 1.41 62 49093 19.917 ug/l 94 5) Bromomethane 1.63 94 25789 21.643 ug/l 99 6) Chloroethane 1.70 64 31039 21.944 ug/l 99 7) Trichlorofluoromethane 1.89 101 73274 19.479 ug/l 98 8) Diethyl Ether 2.11 74 27182 20.108 ug/l 85 9) 1,1,2-Trichlorotrifluoroet 2.29 101 43627 18.694 ug/l 97 10) Methyl Iodide 2.41 142 34087 20.722 ug/l 100 11) Tert butyl alcohol 2.82 59 66818 90.039 ug/l 99 12) 1,1-Dichloroethene 2.29 96 41330 19.420 ug/l 92 13) Acrolein 2.20 56 36695 94.163 ug/l 95 14) Allyl chloride 2.60 41 71744 18.156 ug/l 93 15) Acrylonitrile 2.94 53 147870 102.414 ug/l 98 16) Acetone 2.32 43 130336 79.499 ug/l 98 17) Carbon Disulfide 2.48 76 131754 19.334 ug/l 100 18) Methyl Acetate 2.62 43 68293 19.431 ug/l 97 19) Methyl tert-butyl Ether 3.00 73 151691 18.962 ug/l 99 20) Methylene Chloride 2.71 84 49343 19.182 ug/l 96 21) trans-1,2-Dichloroethene 2.99 96 45845 19.558 ug/l 95 22) Diisopropyl ether 3.57 45 152024 19.407 ug/l # 88 23) Vinyl Acetate 3.53 43 706008 100.614 ug/l 98 24) 1,1-Dichloroethane 3.45 63 87068 19.322 ug/l 97 25) 2-Butanone 4.27 43 212501 96.496 ug/l 97 26) 2,2-Dichloropropane 4.24 77 73844 17.258 ug/l 99 27) cis-1,2-Dichloroethene 4.23 96 53864 19.988 ug/l 95 28) Bromochloromethane 4.55 49 44134 22.235 ug/l 89 29) Tetrahydrofuran 4.64 42 137459 100.796 ug/l 98 30) Chloroform 4.68 83 87846 19.260 ug/l 98 31) Cyclohexane 5.00 56 81768 19.218 ug/l 96 32) 1,1,1-Trichloroethane 4.92 97 81149 19.240 ug/l 96 36) 1,1-Dichloropropene 5.14 75 64516 18.175 ug/l 96 37) Ethyl Acetate 4.38 43 79809 20.629 ug/l 98 38) Carbon Tetrachloride 5.14 117 72523 18.579 ug/l 99 39) Methylcyclohexane 6.42 83 79577 17.965 ug/l 96 40) Benzene 5.40 78 192621 19.044 ug/l 100 41) Methacrylonitrile 4.55 41 42531 20.389 ug/l 97 42) 1,2-Dichloroethane 5.41 62 70564 18.318 ug/l 100 43) Isopropyl Acetate 5.55 43 130264 19.479 ug/l 99 44) Trichloroethene 6.19 130 53482 18.579 ug/l 96 45) 1,2-Dichloropropane 6.44 63 54397 20.156 ug/l 99 46) Dibromomethane 6.56 93 36716 19.368 ug/l 96 47) Bromodichloromethane 6.76 83 71954 19.062 ug/l 99 48) Methyl methacrylate 6.63 41 62385 19.158 ug/l 99 49) 1,4-Dioxane 6.62 88 22217 348.869 ug/l 97 51) 4-Methyl-2-Pentanone 7.46 43 416263 99.077 ug/l 98 52) Toluene 7.64 92 124083 19.068 ug/l 97 53) t-1,3-Dichloropropene 7.88 75 78151 18.436 ug/l 99 54) cis-1,3-Dichloropropene 7.27 75 83702 18.530 ug/l 98 55) 1,1,2-Trichloroethane 8.07 97 48767 18.436 ug/l 99 56) Ethyl methacrylate 8.02 69 84519 19.091 ug/l 100 57) 1,3-Dichloropropane 8.25 76 85614 19.187 ug/l 100 58) 2-Chloroethyl Vinyl ether 7.13 63 170522 100.537 ug/l 97 59) 2-Hexanone 8.36 43 329255 95.991 ug/l 100 60) Dibromochloromethane 8.48 129 60190 18.248 ug/l 98 61) 1,2-Dibromoethane 8.59 107 54921 18.654 ug/l 100 64) Tetrachloroethene 8.23 164 45961 16.981 ug/l 98 65) Chlorobenzene 9.12 112 138178 18.996 ug/l 98 66) 1,1,1,2-Tetrachloroethane 9.21 131 52472 18.987 ug/l 99 67) Ethyl Benzene 9.25 91 243975 19.132 ug/l 98 68) m/p-Xylenes 9.38 106 185283 37.838 ug/l 99 69) o-Xylene 9.78 106 91451 18.871 ug/l 97 70) Styrene 9.80 104 151701 19.049 ug/l 99 71) Bromoform 9.96 173 50450 19.206 ug/l # 99 73) Isopropylbenzene 10.17 105 243615 19.095 ug/l 99 74) N-amyl acetate 10.01 43 118284 19.492 ug/l 97 75) 1,1,2,2-Tetrachloroethane 10.46 83 85519 20.004 ug/l 99 76) 1,2,3-Trichloropropane 10.50 75 75775m 20.712 ug/l 77) Bromobenzene 10.46 156 61555 19.058 ug/l 97 78) n-propylbenzene 10.59 91 290325 19.318 ug/l 97 79) 2-Chlorotoluene 10.66 91 168970 19.066 ug/l 98 80) 1,3,5-Trimethylbenzene 10.78 105 208861 18.888 ug/l 97 81) trans-1,4-Dichloro-2-buten 10.51 75 31114m 19.683 ug/l 82) 4-Chlorotoluene 10.78 91 197099 19.108 ug/l 98 83) tert-Butylbenzene 11.10 119 207677 19.525 ug/l 99 84) 1,2,4-Trimethylbenzene 11.15 105 214797 19.061 ug/l 100 85) sec-Butylbenzene 11.33 105 255162 19.164 ug/l 98 86) p-Isopropyltoluene 11.48 119 224955 18.865 ug/l 99 87) 1,3-Dichlorobenzene 11.42 146 111585 18.700 ug/l 99 88) 1,4-Dichlorobenzene 11.51 146 113910 18.966 ug/l 98 89) n-Butylbenzene 11.89 91 204752 19.340 ug/l 98 90) Hexachloroethane 12.15 117 44986 19.339 ug/l 99 91) 1,2-Dichlorobenzene 11.88 146 112857 18.883 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 12.66 75 23138 19.614 ug/l 91 93) 1,2,4-Trichlorobenzene 13.51 180 73791 19.993 ug/l 99 94) Hexachlorobutadiene 13.70 225 38773 18.664 ug/l 98 95) Naphthalene 13.75 128 230711 19.305 ug/l 99 96) 1,2,3-Trichlorobenzene 13.99 180 76324 20.753 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed