Library Search Compound Report Data Path : W:\HPCHEM1\MSVOA_W\DATA\VW052218\ Data File : VW002793.D Acq On : 22 May 2018 18:57 Operator : JC/SY Sample : J2952-09 Misc : 4.77G/10ML/MSVOA_W/SOIL ALS Vial : 1 Sample Multiplier: 1 Quant Method : W:\HPCHEM1\MSVOA_W\METHOD\SOM2WLM052218S.M Quant Title : VOC Analysis TIC Library : C:\DATABASE\NIST11.L TIC Integration Parameters: LSCINT.P ********************************************************************* Peak Number 1 Tricyclo[2.2.1.0(2,6)]hepta... Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 12.38 1.85 ug/L 45264 Chlorobenzene-d5 11.64 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Tricyclo[2.2.1.0(2,6)]heptane, 1... 136 C10H16 000508-32-7 93 2 .gamma.-Terpinene 136 C10H16 000099-85-4 93 3 (1S)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16 007785-26-4 90 4 3-Carene 136 C10H16 013466-78-9 87 5 .gamma.-Terpinene 136 C10H16 000099-85-4 87 ********************************************************************* Peak Number 2 .alpha.-Pinene Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 12.48 361.83 ug/L 8841950 Chlorobenzene-d5 11.64 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 .alpha.-Pinene 136 C10H16 000080-56-8 97 2 (1R)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16 007785-70-8 96 3 .alpha.-Pinene 136 C10H16 000080-56-8 95 4 (1R)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16 007785-70-8 94 5 .gamma.-Terpinene 136 C10H16 000099-85-4 94 ********************************************************************* Peak Number 3 Bicyclo[3.1.1]heptane, 6,6-... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.04 212.94 ug/L 5440130 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Bicyclo[3.1.1]heptane, 6,6-dimet... 136 C10H16 018172-67-3 96 2 .beta.-Pinene 136 C10H16 000127-91-3 96 3 .beta.-Pinene 136 C10H16 000127-91-3 94 4 .alpha.-Pinene 136 C10H16 000080-56-8 91 5 Cyclohexene, 4-methylene-1-(1-me... 136 C10H16 000099-84-3 91 ********************************************************************* Peak Number 4 (+)-4-Carene Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.37 1.85 ug/L 47179 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 (+)-4-Carene 136 C10H16 029050-33-7 96 2 1,3-Cyclohexadiene, 1-methyl-4-(... 136 C10H16 000099-86-5 95 3 Cyclohexene, 1-methyl-4-(1-methy... 136 C10H16 000586-62-9 93 4 2-Carene 136 C10H16 000554-61-0 93 5 1,3-Cyclohexadiene, 1-methyl-4-(... 136 C10H16 000099-86-5 90 ********************************************************************* Peak Number 5 D-Limonene Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.48 25.88 ug/L 661181 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 D-Limonene 136 C10H16 005989-27-5 98 2 D-Limonene 136 C10H16 005989-27-5 95 3 D-Limonene 136 C10H16 005989-27-5 93 4 Limonene 136 C10H16 000138-86-3 87 5 D-Limonene 136 C10H16 005989-27-5 76 ********************************************************************* Peak Number 6 .gamma.-Terpinene Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.73 1.70 ug/L 43367 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 .gamma.-Terpinene 136 C10H16 000099-85-4 94 2 (1S)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16 007785-26-4 93 3 .gamma.-Terpinene 136 C10H16 000099-85-4 87 4 .gamma.-Terpinene 136 C10H16 000099-85-4 87 5 (1R)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16 007785-70-8 81 ********************************************************************* Peak Number 7 Cyclohexene, 1-methyl-4-(1-... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 14.01 4.35 ug/L 111009 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Cyclohexene, 1-methyl-4-(1-methy... 136 C10H16 000586-62-9 98 2 (+)-4-Carene 136 C10H16 029050-33-7 95 3 Cyclohexene, 1-methyl-4-(1-methy... 136 C10H16 000586-62-9 93 4 2-Carene 136 C10H16 000554-61-0 93 5 Cyclohexene, 1-methyl-4-(1-methy... 136 C10H16 000586-62-9 93 ********************************************************************* Peak Number 8 Pinocarvone Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 15.17 2.82 ug/L 71950 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Pinocarvone 150 C10H14O 030460-92-5 83 2 Pinocarvone 150 C10H14O 030460-92-5 72 3 Pinocarvone 150 C10H14O 030460-92-5 50 4 1,1-Dicyanoethane 80 C4H4N2 003696-36-4 47 5 Benzyl alcohol 108 C7H8O 000100-51-6 25