Library Search Compound Report Data Path : W:\HPCHEM1\MSVOA_W\DATA\VW052418\ Data File : VW002843.D Acq On : 24 May 2018 13:35 Operator : JC/SY Sample : J3030-01RE Misc : 4.10G/10ML/MSVOA_W/SOIL ALS Vial : 1 Sample Multiplier: 1 Quant Method : W:\HPCHEM1\MSVOA_W\METHOD\SOM2WLM052218S.M Quant Title : VOC Analysis TIC Library : C:\DATABASE\NIST11.L TIC Integration Parameters: LSCINT.P ********************************************************************* Peak Number 1 (DEL) Alkane: Straight-Chai... Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 3.01 1.69 ug/L 38013 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Butane, 2-methyl- 72 C5H12 000078-78-4 72 2 Butane, 2-methyl- 72 C5H12 000078-78-4 64 3 Butane, 2-methyl- 72 C5H12 000078-78-4 59 4 2(3H)-Furanone, dihydro-4-methyl- 100 C5H8O2 001679-49-8 25 5 3-Buten-1-ol 72 C4H8O 000627-27-0 9 ********************************************************************* Peak Number 2 (DEL) Alkane: Straight-Chai... Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 3.37 2.14 ug/L 48156 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Pentane 72 C5H12 000109-66-0 80 2 Pentane 72 C5H12 000109-66-0 80 3 Pentane 72 C5H12 000109-66-0 53 4 Pentane 72 C5H12 000109-66-0 42 5 Butane, 2-methyl- 72 C5H12 000078-78-4 33 ********************************************************************* Peak Number 3 1-Propene, 3-methoxy- Concentration Rank 14 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 5.78 2.10 ug/L 47216 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 1-Propene, 3-methoxy- 72 C4H8O 000627-40-7 59 2 Propanal, 2-methyl- 72 C4H8O 000078-84-2 58 3 Propanal, 2-methyl- 72 C4H8O 000078-84-2 58 4 Butanal 72 C4H8O 000123-72-8 56 5 Isobutylene epoxide 72 C4H8O 000558-30-5 43 ********************************************************************* Peak Number 4 Butanal Concentration Rank 17 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 6.90 1.58 ug/L 35601 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Butanal 72 C4H8O 000123-72-8 91 2 Butanal 72 C4H8O 000123-72-8 87 3 Butanal 72 C4H8O 000123-72-8 49 4 Butanal 72 C4H8O 000123-72-8 47 5 Propane 44 C3H8 000074-98-6 47 ********************************************************************* Peak Number 5 Cyclopropanecarboxamide Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 8.56 2.95 ug/L 66312 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Cyclopropanecarboxamide 85 C4H7NO 006228-73-5 50 2 Pentanal 86 C5H10O 000110-62-3 49 3 Butanal, 3-methyl- 86 C5H10O 000590-86-3 46 4 Butanal, 3-methyl- 86 C5H10O 000590-86-3 43 5 Ethanol, 2-(2-propenyloxy)- 102 C5H10O2 000111-45-5 37 ********************************************************************* Peak Number 6 unknown-01 Concentration Rank 12 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 8.71 2.24 ug/L 50337 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Pentan-2-ol, 1-tert-buthylamino-... 173 C10H23NO 339196-64-4 40 2 1-Hexene, 4-methyl- 98 C7H14 003769-23-1 38 3 Heptane, 1-(2-propenyloxy)- 156 C10H20O 016519-24-7 32 4 2-Butene 56 C4H8 000107-01-7 27 5 Oxetane, 2,2-dimethyl- 86 C5H10O 006245-99-4 25 ********************************************************************* Peak Number 7 Pentanal Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 9.41 5.80 ug/L 130557 1,4-Difluorobenzene 8.85 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Pentanal 86 C5H10O 000110-62-3 87 2 Butanal, 3-methyl- 86 C5H10O 000590-86-3 83 3 Pentanal 86 C5H10O 000110-62-3 64 4 Pentanal 86 C5H10O 000110-62-3 64 5 Cyclopropyl carbinol 72 C4H8O 002516-33-8 50 ********************************************************************* Peak Number 8 Hexanal Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 11.08 43.05 ug/L 939694 Chlorobenzene-d5 11.64 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Hexanal 100 C6H12O 000066-25-1 72 2 Hexanal 100 C6H12O 000066-25-1 64 3 Hexanal 100 C6H12O 000066-25-1 64 4 Hexanal 100 C6H12O 000066-25-1 59 5 2,2-Dimethyl-3-hydroxypropionald... 102 C5H10O2 000597-31-9 37 ********************************************************************* Peak Number 9 Heptanal Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 12.35 2.42 ug/L 52723 Chlorobenzene-d5 11.64 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Heptanal 114 C7H14O 000111-71-7 80 2 Heptanal 114 C7H14O 000111-71-7 80 3 Heptanal 114 C7H14O 000111-71-7 72 4 Heptanal 114 C7H14O 000111-71-7 64 5 3-Butenamide 85 C4H7NO 028446-58-4 35 ********************************************************************* Peak Number 10 2-Hexyn-1-ol Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.11 1.28 ug/L 14901 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 2-Hexyn-1-ol 98 C6H10O 000764-60-3 27 2 Dodecyl propyl carbonate 272 C16H32O3 959272-51-6 23 3 2-Undecanethiol, 2-methyl- 202 C12H26S 010059-13-9 12 4 1-Undecene 154 C11H22 000821-95-4 12 5 3-Dodecene, (Z)- 168 C12H24 007239-23-8 12 ********************************************************************* Peak Number 11 Benzene, 1,2,3-trimethyl- Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.26 2.00 ug/L 23226 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Benzene, 1,2,3-trimethyl- 120 C9H12 000526-73-8 87 2 Mesitylene 120 C9H12 000108-67-8 83 3 Mesitylene 120 C9H12 000108-67-8 83 4 Mesitylene 120 C9H12 000108-67-8 80 5 Benzene, 1,2,4-trimethyl- 120 C9H12 000095-63-6 80 ********************************************************************* Peak Number 12 Octanal Concentration Rank 9 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 13.41 2.68 ug/L 31135 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Octanal 128 C8H16O 000124-13-0 86 2 3-Hexene, (Z)- 84 C6H12 007642-09-3 25 3 3-Hexene, (Z)- 84 C6H12 007642-09-3 25 4 Cyclopentanol, 2-methyl-, cis- 100 C6H12O 025144-05-2 25 5 3-Hexene, (E)- 84 C6H12 013269-52-8 25 ********************************************************************* Peak Number 13 Nonanal Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. --------------------------------------------------------------------- 14.34 2.51 ug/L 29089 1,4-Dichlorobenzene-d4 13.57 Hit# of 5 Tentative ID MW MolForm CAS# Qual --------------------------------------------------------------------- 1 Nonanal 142 C9H18O 000124-19-6 53 2 2-Propen-1-amine, N-2-propenyl- 97 C6H11N 000124-02-7 43 3 Cyclohexanol, 2-methyl- 114 C7H14O 000583-59-5 38 4 2-Nonen-1-ol, (E)- 142 C9H18O 031502-14-4 27 5 Cyclohexanol, 2-methyl-, trans- 114 C7H14O 007443-52-9 25