Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001504.D Acq On : 08 May 2018 10:26 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 08 13:52:36 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 259225 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 320677 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 315734 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 233717 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 179868 48.28 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.56% 35) Dibromofluoromethane 5.51 113 146089 51.22 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.44% 50) Toluene-d8 8.72 98 534023 51.29 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.58% 62) 4-Bromofluorobenzene 11.14 95 208013 52.04 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.08% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 179323 51.39 ug/l 99 3) Chloromethane 1.32 50 162030 47.68 ug/l 99 4) Vinyl Chloride 1.40 62 167279 47.16 ug/l 98 5) Bromomethane 1.64 94 82325 50.76 ug/l 99 6) Chloroethane 1.72 64 108617 46.33 ug/l 97 7) Trichlorofluoromethane 1.93 101 269277 50.45 ug/l 100 8) Diethyl Ether 2.19 74 98455 47.06 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 158821 50.75 ug/l 99 10) Methyl Iodide 2.51 142 217231 48.11 ug/l 99 11) Tert butyl alcohol 3.07 59 168202 214.12 ug/l 99 12) 1,1-Dichloroethene 2.37 96 136915 47.73 ug/l 99 13) Acrolein 2.29 56 38414 247.96 ug/l 96 14) Allyl chloride 2.73 41 256339 47.93 ug/l 97 15) Acrylonitrile 3.15 53 402212 226.58 ug/l 100 16) Acetone 2.45 43 409350 241.95 ug/l 99 17) Carbon Disulfide 2.57 76 338326 46.35 ug/l 99 18) Methyl Acetate 2.78 43 211997 47.69 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 483766 48.44 ug/l 100 20) Methylene Chloride 2.85 84 152643 45.57 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 149184 46.60 ug/l 96 22) Diisopropyl ether 3.87 45 493095 49.35 ug/l 98 23) Vinyl Acetate 3.82 43 2136158 256.51 ug/l 100 24) 1,1-Dichloroethane 3.70 63 271384 48.62 ug/l 99 25) 2-Butanone 4.71 43 577198 236.02 ug/l 98 26) 2,2-Dichloropropane 4.59 77 225683 52.36 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 166823 48.93 ug/l 97 28) Bromochloromethane 5.02 49 123369 50.98 ug/l 98 29) Tetrahydrofuran 5.17 42 361632 231.11 ug/l 100 30) Chloroform 5.22 83 290186 50.47 ug/l 97 31) Cyclohexane 5.58 56 244368 50.97 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 260583 51.85 ug/l 100 36) 1,1-Dichloropropene 5.80 75 214969 52.70 ug/l 99 37) Ethyl Acetate 4.86 43 219272 49.04 ug/l 99 38) Carbon Tetrachloride 5.79 117 240077 55.18 ug/l 100 39) Methylcyclohexane 7.46 83 266936 55.35 ug/l 99 40) Benzene 6.15 78 626337 52.57 ug/l 99 41) Methacrylonitrile 5.06 41 126045 49.27 ug/l 99 42) 1,2-Dichloroethane 6.20 62 244499 53.39 ug/l 99 43) Isopropyl Acetate 6.47 43 357841 52.13 ug/l 100 44) Trichloroethene 7.21 130 194954 53.53 ug/l 99 45) 1,2-Dichloropropane 7.52 63 155652 52.40 ug/l 98 46) Dibromomethane 7.66 93 111306 52.93 ug/l 99 47) Bromodichloromethane 7.90 83 214704 55.17 ug/l 98 48) Methyl methacrylate 7.78 41 194773 52.11 ug/l 100 49) 1,4-Dioxane 7.76 88 76572 948.23 ug/l 98 51) 4-Methyl-2-Pentanone 8.65 43 1177573 258.16 ug/l 100 52) Toluene 8.79 92 421292 54.08 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 250919 57.05 ug/l 98 54) cis-1,3-Dichloropropene 9.04 75 236240 51.87 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 169543 54.02 ug/l 98 56) Ethyl methacrylate 9.18 69 248121 54.84 ug/l 99 57) 1,3-Dichloropropane 9.38 76 277663 53.50 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 625605 281.92 ug/l 100 59) 2-Hexanone 9.50 43 919914 263.37 ug/l 99 60) Dibromochloromethane 9.59 129 185975 57.86 ug/l 99 61) 1,2-Dibromoethane 9.68 107 179941 54.60 ug/l 99 64) Tetrachloroethene 9.34 164 241844 54.95 ug/l 98 65) Chlorobenzene 10.14 112 484833 52.36 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 182470 55.09 ug/l 99 67) Ethyl Benzene 10.26 91 818732 53.95 ug/l 99 68) m/p-Xylenes 10.37 106 664782 110.85 ug/l 99 69) o-Xylene 10.70 106 315890 54.20 ug/l 99 70) Styrene 10.72 104 533095 56.30 ug/l 99 71) Bromoform 10.86 173 148599 46.89 ug/l 99 73) Isopropylbenzene 11.02 105 844604 52.20 ug/l 99 74) N-amyl acetate 6.47 43 357841 48.69 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 233758 48.92 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 236072m 49.80 ug/l 77) Bromobenzene 11.26 156 234081 49.76 ug/l 100 78) n-propylbenzene 11.37 91 957448 54.34 ug/l 99 79) 2-Chlorotoluene 11.43 91 561163 51.76 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 716839 53.21 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 67538 45.82 ug/l 98 82) 4-Chlorotoluene 11.52 91 662334 52.95 ug/l 100 83) tert-Butylbenzene 11.77 119 690930 51.55 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 737334 53.26 ug/l 100 85) sec-Butylbenzene 11.95 105 881965 54.82 ug/l 100 86) p-Isopropyltoluene 12.07 119 818935 55.49 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 440199 52.35 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 445996 52.00 ug/l 100 89) n-Butylbenzene 12.40 91 692100 56.60 ug/l 100 90) Hexachloroethane 12.60 117 122168 54.97 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 438968 51.31 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54756 52.15 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 344940 55.10 ug/l 100 94) Hexachlorobutadiene 13.79 225 189931 55.45 ug/l 99 95) Naphthalene 13.84 128 929635 53.70 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 346120 53.88 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed