Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001507.D Acq On : 08 May 2018 12:13 Operator : JC/MD Sample : VX0508WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 5 Sample Multiplier: 1 Quant Time: May 08 14:14:59 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 254866 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 334645 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 316666 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 227563 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 188624 51.49 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.98% 35) Dibromofluoromethane 5.51 113 152092 51.10 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.20% 50) Toluene-d8 8.72 98 553957 50.98 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.96% 62) 4-Bromofluorobenzene 11.14 95 211433 50.69 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.38% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 72708 21.19 ug/l 99 3) Chloromethane 1.32 50 71520 21.40 ug/l 99 4) Vinyl Chloride 1.40 62 71729 20.57 ug/l 98 5) Bromomethane 1.64 94 46634 27.68 ug/l 99 6) Chloroethane 1.73 64 45504 19.74 ug/l 96 7) Trichlorofluoromethane 1.93 101 110345 21.03 ug/l 98 8) Diethyl Ether 2.19 74 42504 20.66 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 63682 20.70 ug/l 99 10) Methyl Iodide 2.51 142 77502 17.46 ug/l 98 11) Tert butyl alcohol 3.07 59 68050 88.11 ug/l 99 12) 1,1-Dichloroethene 2.38 96 58129 20.61 ug/l 97 13) Acrolein 2.29 56 14468 87.44 ug/l 96 14) Allyl chloride 2.73 41 107587 20.46 ug/l 99 15) Acrylonitrile 3.15 53 165148 94.63 ug/l 100 16) Acetone 2.45 43 158219 95.12 ug/l 99 17) Carbon Disulfide 2.57 76 136526 19.02 ug/l 100 18) Methyl Acetate 2.78 43 87499 20.02 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 204381 20.81 ug/l 100 20) Methylene Chloride 2.86 84 65032 19.75 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 62371 19.82 ug/l 98 22) Diisopropyl ether 3.88 45 199438 20.30 ug/l 100 23) Vinyl Acetate 3.83 43 830494 101.43 ug/l 100 24) 1,1-Dichloroethane 3.70 63 114566 20.88 ug/l 100 25) 2-Butanone 4.71 43 227875 94.77 ug/l 100 26) 2,2-Dichloropropane 4.59 77 94788 22.37 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 68117 20.32 ug/l 99 28) Bromochloromethane 5.03 49 51723 21.74 ug/l 99 29) Tetrahydrofuran 5.17 42 144104 93.67 ug/l 99 30) Chloroform 5.22 83 118913 21.03 ug/l 98 31) Cyclohexane 5.58 56 95038 20.16 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 105384 21.33 ug/l 99 36) 1,1-Dichloropropene 5.81 75 85174 20.01 ug/l 99 37) Ethyl Acetate 4.87 43 87546 18.76 ug/l 99 38) Carbon Tetrachloride 5.79 117 93257 20.54 ug/l 99 39) Methylcyclohexane 7.46 83 100154 19.90 ug/l 96 40) Benzene 6.15 78 256242 20.61 ug/l 100 41) Methacrylonitrile 5.07 41 51258 19.20 ug/l 99 42) 1,2-Dichloroethane 6.20 62 99927 20.91 ug/l 100 43) Isopropyl Acetate 6.48 43 144960 20.24 ug/l 99 44) Trichloroethene 7.22 130 78814 20.74 ug/l 98 45) 1,2-Dichloropropane 7.52 63 62320 20.11 ug/l 97 46) Dibromomethane 7.67 93 45146 20.57 ug/l 99 47) Bromodichloromethane 7.90 83 83946 20.67 ug/l 98 48) Methyl methacrylate 7.79 41 77931 19.98 ug/l 99 49) 1,4-Dioxane 7.76 88 27481 326.11 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 476292 100.06 ug/l 99 52) Toluene 8.79 92 168594 20.74 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 98167 21.39 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 87807 19.93 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 65668 20.05 ug/l 97 56) Ethyl methacrylate 9.19 69 94445 20.00 ug/l 100 57) 1,3-Dichloropropane 9.38 76 109219 20.17 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 254210 109.78 ug/l 100 59) 2-Hexanone 9.50 43 351167 96.34 ug/l 99 60) Dibromochloromethane 9.59 129 66975 19.97 ug/l 99 61) 1,2-Dibromoethane 9.68 107 70231 20.42 ug/l 100 64) Tetrachloroethene 9.34 164 91365 20.70 ug/l 98 65) Chlorobenzene 10.14 112 190452 20.51 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 69006 20.77 ug/l 99 67) Ethyl Benzene 10.26 91 313108 20.57 ug/l 100 68) m/p-Xylenes 10.37 106 251851 41.87 ug/l 100 69) o-Xylene 10.70 106 120474 20.61 ug/l 97 70) Styrene 10.72 104 199716 21.03 ug/l 99 71) Bromoform 10.87 173 52421 18.81 ug/l # 98 73) Isopropylbenzene 11.02 105 328758 20.87 ug/l 100 74) N-amyl acetate 6.48 43 144960 20.26 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 92011 19.78 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 94814m 20.54 ug/l 77) Bromobenzene 11.26 156 93772 20.47 ug/l 98 78) n-propylbenzene 11.37 91 369135 21.52 ug/l 99 79) 2-Chlorotoluene 11.43 91 218697 20.72 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 274235 20.91 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 23552 19.16 ug/l 91 82) 4-Chlorotoluene 11.52 91 260069 21.35 ug/l 99 83) tert-Butylbenzene 11.77 119 266995 20.46 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 283213 21.01 ug/l 100 85) sec-Butylbenzene 11.95 105 333881 21.31 ug/l 99 86) p-Isopropyltoluene 12.07 119 306271 21.31 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 170556 20.83 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 173008 20.72 ug/l 99 89) n-Butylbenzene 12.40 91 257063 21.59 ug/l 100 90) Hexachloroethane 12.60 117 43188 19.96 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 169325 20.33 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19987 19.55 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 129302 21.21 ug/l 99 94) Hexachlorobutadiene 13.79 225 69269 20.77 ug/l 100 95) Naphthalene 13.84 128 356461 21.15 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 130140 20.81 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed