Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001526.D Acq On : 08 May 2018 20:41 Operator : JC/MD Sample : VX0508WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 20 Sample Multiplier: 1 Quant Time: May 09 07:35:47 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 209539 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 282763 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 265233 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 186409 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 168597 55.98 ug/l 0.00 Spiked Amount 50.000 Recovery = 111.96% 35) Dibromofluoromethane 5.51 113 135392 53.83 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.66% 50) Toluene-d8 8.72 98 468267 51.01 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.02% 62) 4-Bromofluorobenzene 11.14 95 175121 49.69 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.38% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 59726 21.17 ug/l 98 3) Chloromethane 1.32 50 62470 22.74 ug/l 98 4) Vinyl Chloride 1.40 62 64882 22.63 ug/l 100 5) Bromomethane 1.64 94 36437 26.12 ug/l 100 6) Chloroethane 1.72 64 45153 23.83 ug/l 98 7) Trichlorofluoromethane 1.93 101 97397 22.57 ug/l 100 8) Diethyl Ether 2.19 74 40123 23.72 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 53481 21.14 ug/l 99 10) Methyl Iodide 2.51 142 67587 18.52 ug/l 100 11) Tert butyl alcohol 3.09 59 82117 129.32 ug/l 99 12) 1,1-Dichloroethene 2.37 96 52872 22.80 ug/l 98 13) Acrolein 2.30 56 15135 114.59 ug/l 93 14) Allyl chloride 2.73 41 100090 23.15 ug/l 98 15) Acrylonitrile 3.15 53 176378 122.92 ug/l 99 16) Acetone 2.45 43 160075 117.05 ug/l 99 17) Carbon Disulfide 2.57 76 118698 20.12 ug/l 98 18) Methyl Acetate 2.78 43 94350 26.26 ug/l 97 19) Methyl tert-butyl Ether 3.21 73 195270 24.19 ug/l 99 20) Methylene Chloride 2.86 84 62112 22.94 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 57139 22.08 ug/l 97 22) Diisopropyl ether 3.88 45 182351 22.58 ug/l 98 23) Vinyl Acetate 3.83 43 760304 112.95 ug/l 99 24) 1,1-Dichloroethane 3.70 63 109430 24.25 ug/l 99 25) 2-Butanone 4.72 43 236269 119.52 ug/l 99 26) 2,2-Dichloropropane 4.59 77 60096 17.25 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 62311 22.61 ug/l 96 28) Bromochloromethane 5.03 49 48166 24.62 ug/l 97 29) Tetrahydrofuran 5.18 42 151343 119.66 ug/l 100 30) Chloroform 5.22 83 110636 23.80 ug/l 99 31) Cyclohexane 5.58 56 77020 19.87 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 93485 23.01 ug/l 98 36) 1,1-Dichloropropene 5.81 75 72537 20.17 ug/l 98 37) Ethyl Acetate 4.87 43 90009 22.83 ug/l 99 38) Carbon Tetrachloride 5.79 117 81623 21.28 ug/l 97 39) Methylcyclohexane 7.46 83 76128 17.90 ug/l 96 40) Benzene 6.15 78 231130 22.00 ug/l 98 41) Methacrylonitrile 5.07 41 51743 22.94 ug/l 98 42) 1,2-Dichloroethane 6.20 62 93894 23.25 ug/l 99 43) Isopropyl Acetate 6.48 43 136227 22.51 ug/l 100 44) Trichloroethene 7.22 130 69403 21.61 ug/l 100 45) 1,2-Dichloropropane 7.52 63 58224 22.23 ug/l 98 46) Dibromomethane 7.67 93 41836 22.56 ug/l 99 47) Bromodichloromethane 7.90 83 76214 22.21 ug/l 99 48) Methyl methacrylate 7.79 41 74208 22.52 ug/l 99 49) 1,4-Dioxane 7.76 88 33571 471.47 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 476464 118.46 ug/l 99 52) Toluene 8.79 92 148370 21.60 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 82314 21.23 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 73894 19.86 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 62483 22.58 ug/l 98 56) Ethyl methacrylate 9.19 69 85672 21.47 ug/l 98 57) 1,3-Dichloropropane 9.38 76 103331 22.58 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 226082 115.54 ug/l 99 59) 2-Hexanone 9.51 43 357788 116.17 ug/l 99 60) Dibromochloromethane 9.59 129 62033 21.89 ug/l 99 61) 1,2-Dibromoethane 9.68 107 65357 22.49 ug/l 100 64) Tetrachloroethene 9.34 164 81062 21.93 ug/l 98 65) Chlorobenzene 10.15 112 169466 21.79 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 63646 22.87 ug/l 99 67) Ethyl Benzene 10.26 91 267443 20.98 ug/l 99 68) m/p-Xylenes 10.37 106 215195 42.72 ug/l 99 69) o-Xylene 10.70 106 106096 21.67 ug/l 99 70) Styrene 10.72 104 174554 21.95 ug/l 100 71) Bromoform 10.86 173 48968 20.56 ug/l # 100 73) Isopropylbenzene 11.02 105 281908 21.85 ug/l 99 74) N-amyl acetate 6.48 43 136227 23.24 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 88545 23.23 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 88779m 23.48 ug/l 77) Bromobenzene 11.26 156 82032 21.86 ug/l 99 78) n-propylbenzene 11.37 91 303809 21.62 ug/l 99 79) 2-Chlorotoluene 11.43 91 189966 21.97 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 232648 21.65 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 19211 19.10 ug/l 87 82) 4-Chlorotoluene 11.52 91 220236 22.08 ug/l 99 83) tert-Butylbenzene 11.77 119 225662 21.11 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 243614 22.06 ug/l 99 85) sec-Butylbenzene 11.95 105 273175 21.29 ug/l 100 86) p-Isopropyltoluene 12.07 119 252782 21.47 ug/l 98 87) 1,3-Dichlorobenzene 12.03 146 142441 21.24 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 143540 20.98 ug/l 97 89) n-Butylbenzene 12.40 91 192605 19.75 ug/l 99 90) Hexachloroethane 12.60 117 37172 20.97 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 148393 21.75 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 20641 24.65 ug/l 93 93) 1,2,4-Trichlorobenzene 13.65 180 103084 20.65 ug/l 100 94) Hexachlorobutadiene 13.79 225 54472 19.94 ug/l 98 95) Naphthalene 13.84 128 313267 22.69 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 110173 21.50 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed