Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001527.D Acq On : 08 May 2018 21:08 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 21 Sample Multiplier: 1 Quant Time: May 09 07:37:04 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 228153 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 299503 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 287490 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 211883 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 161258 49.17 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.34% 35) Dibromofluoromethane 5.51 113 131107 49.21 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.42% 50) Toluene-d8 8.72 98 481749 49.54 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.08% 62) 4-Bromofluorobenzene 11.14 95 183475 49.15 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.30% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 160798 52.35 ug/l 100 3) Chloromethane 1.32 50 150680 50.37 ug/l 99 4) Vinyl Chloride 1.40 62 159588 51.12 ug/l 99 5) Bromomethane 1.64 94 70564 49.34 ug/l 100 6) Chloroethane 1.72 64 109088 52.87 ug/l 99 7) Trichlorofluoromethane 1.92 101 248575 52.91 ug/l 100 8) Diethyl Ether 2.19 74 96712 52.52 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.38 101 141925 51.53 ug/l 100 10) Methyl Iodide 2.51 142 197533 49.70 ug/l 100 11) Tert butyl alcohol 3.09 59 194037 280.64 ug/l 99 12) 1,1-Dichloroethene 2.37 96 133059 52.70 ug/l 97 13) Acrolein 2.30 56 34520 253.43 ug/l 98 14) Allyl chloride 2.73 41 249288 52.96 ug/l 99 15) Acrylonitrile 3.15 53 428876 274.50 ug/l 99 16) Acetone 2.45 43 394435 264.89 ug/l 98 17) Carbon Disulfide 2.57 76 323836 50.40 ug/l 100 18) Methyl Acetate 2.78 43 228335 58.37 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 470744 53.56 ug/l 99 20) Methylene Chloride 2.86 84 149432 50.68 ug/l 97 21) trans-1,2-Dichloroethene 3.16 96 142892 50.72 ug/l 97 22) Diisopropyl ether 3.88 45 457814 52.05 ug/l 99 23) Vinyl Acetate 3.83 43 1888984 257.72 ug/l 100 24) 1,1-Dichloroethane 3.70 63 266254 54.20 ug/l 99 25) 2-Butanone 4.72 43 586052 272.27 ug/l 99 26) 2,2-Dichloropropane 4.59 77 168060 44.30 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 157212 52.39 ug/l 95 28) Bromochloromethane 5.03 49 109694 51.50 ug/l 98 29) Tetrahydrofuran 5.18 42 378229 274.64 ug/l 100 30) Chloroform 5.22 83 276703 54.68 ug/l 98 31) Cyclohexane 5.57 56 219482 52.02 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 244864 55.36 ug/l 99 36) 1,1-Dichloropropene 5.80 75 195736 51.38 ug/l 99 37) Ethyl Acetate 4.87 43 222341 53.24 ug/l 99 38) Carbon Tetrachloride 5.79 117 221123 54.42 ug/l 99 39) Methylcyclohexane 7.46 83 228192 50.66 ug/l 98 40) Benzene 6.15 78 591994 53.20 ug/l 99 41) Methacrylonitrile 5.07 41 128304 53.70 ug/l 98 42) 1,2-Dichloroethane 6.20 62 227995 53.31 ug/l 100 43) Isopropyl Acetate 6.48 43 354088 55.23 ug/l 100 44) Trichloroethene 7.22 130 179120 52.66 ug/l 100 45) 1,2-Dichloropropane 7.53 63 148395 53.49 ug/l 99 46) Dibromomethane 7.67 93 105216 53.57 ug/l 99 47) Bromodichloromethane 7.91 83 203134 55.89 ug/l 100 48) Methyl methacrylate 7.79 41 190567 54.59 ug/l 99 49) 1,4-Dioxane 7.76 88 84386 1118.88 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1212617 284.64 ug/l 99 52) Toluene 8.79 92 393160 54.03 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 229686 55.92 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 206294 48.64 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 155658 53.10 ug/l 98 56) Ethyl methacrylate 9.19 69 234173 55.42 ug/l 100 57) 1,3-Dichloropropane 9.38 76 259421 53.52 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 591433 285.36 ug/l 99 59) 2-Hexanone 9.51 43 919610 281.89 ug/l 99 60) Dibromochloromethane 9.59 129 171787 57.23 ug/l 99 61) 1,2-Dibromoethane 9.68 107 168430 54.72 ug/l 100 64) Tetrachloroethene 9.34 164 218524 54.53 ug/l 99 65) Chlorobenzene 10.15 112 444625 52.73 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 166545 55.22 ug/l 99 67) Ethyl Benzene 10.26 91 737700 53.38 ug/l 99 68) m/p-Xylenes 10.37 106 593614 108.71 ug/l 100 69) o-Xylene 10.71 106 291158 54.86 ug/l 100 70) Styrene 10.72 104 482561 55.97 ug/l 99 71) Bromoform 10.87 173 140750 48.63 ug/l # 100 73) Isopropylbenzene 11.02 105 777915 53.03 ug/l 99 74) N-amyl acetate 6.48 43 354088 53.15 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 228071 52.65 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 226371m 52.68 ug/l 77) Bromobenzene 11.26 156 219326 51.43 ug/l 99 78) n-propylbenzene 11.37 91 858866 53.77 ug/l 99 79) 2-Chlorotoluene 11.43 91 513938 52.29 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 650755 53.29 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 61117 45.75 ug/l 98 82) 4-Chlorotoluene 11.52 91 600705 52.98 ug/l 100 83) tert-Butylbenzene 11.77 119 650078 53.50 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 674375 53.73 ug/l 99 85) sec-Butylbenzene 11.95 105 787692 54.01 ug/l 99 86) p-Isopropyltoluene 12.07 119 723567 54.08 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 393858 51.67 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 401383 51.62 ug/l 100 89) n-Butylbenzene 12.40 91 584856 52.75 ug/l 100 90) Hexachloroethane 12.60 117 111779 55.48 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 404612 52.17 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 55130 57.92 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 297069 52.34 ug/l 99 94) Hexachlorobutadiene 13.79 225 155672 50.13 ug/l 100 95) Naphthalene 13.84 128 878441 55.97 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 314388 53.99 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed