Quantitation Report (Not Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001528.D Acq On : 08 May 2018 22:01 Operator : JC/MD Sample : BFB Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Time: May 09 06:49:31 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 1025 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.86 114 890 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 529 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 582 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 803 54.51 ug/l 0.00 Spiked Amount 50.000 Recovery = 109.02% 35) Dibromofluoromethane 5.51 113 209 26.40 ug/l 0.00 Spiked Amount 50.000 Recovery = 52.80% 50) Toluene-d8 8.72 98 1032 35.71 ug/l 0.00 Spiked Amount 50.000 Recovery = 71.42% 62) 4-Bromofluorobenzene 11.14 95 28116 2534.63 ug/l 0.00 Spiked Amount 50.000 Recovery = 5069.26% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 126 9.13 ug/l # 64 3) Chloromethane 1.32 50 323 24.04 ug/l 91 4) Vinyl Chloride 1.40 62 143 10.20 ug/l # 86 5) Bromomethane 1.65 94 1273 209.29 ug/l 92 6) Chloroethane 1.73 64 186 20.06 ug/l # 43 7) Trichlorofluoromethane 1.93 101 219 10.38 ug/l # 56 8) Diethyl Ether 2.15 74 24 2.90 ug/l # 2 9) 1,1,2-Trichlorotrifluoroet 2.39 101 161 13.01 ug/l # 89 10) Methyl Iodide 2.51 142 1853 103.78 ug/l 96 11) Tert butyl alcohol 3.02 59 2250 724.36 ug/l # 72 12) 1,1-Dichloroethene 2.37 96 104 9.17 ug/l # 52 13) Acrolein 2.30 56 57 85.40 ug/l # 1 14) Allyl chloride 2.74 41 65 3.07 ug/l # 1 15) Acrylonitrile 3.16 53 270 38.47 ug/l # 47 16) Acetone 2.45 43 804 120.18 ug/l # 41 17) Carbon Disulfide 2.57 76 1190 41.23 ug/l # 86 18) Methyl Acetate 2.79 43 180 10.24 ug/l # 52 19) Methyl tert-butyl Ether 3.11 73 22 0.56 ug/l # 1 20) Methylene Chloride 2.86 84 462 34.88 ug/l # 45 21) trans-1,2-Dichloroethene 3.17 96 378 29.86 ug/l # 78 22) Diisopropyl ether 3.87 45 50 1.27 ug/l # 61 23) Vinyl Acetate 3.83 43 233 7.08 ug/l # 71 24) 1,1-Dichloroethane 3.68 63 50 2.27 ug/l # 81 25) 2-Butanone 4.72 43 383 39.61 ug/l # 49 26) 2,2-Dichloropropane 4.67 77 22 1.29 ug/l # 53 27) cis-1,2-Dichloroethene 4.61 96 38 2.82 ug/l # 1 28) Bromochloromethane 5.21 49 19 1.99 ug/l # 7 29) Tetrahydrofuran 5.20 42 776 125.42 ug/l # 67 30) Chloroform 5.21 83 25 1.10 ug/l # 18 31) Cyclohexane 5.58 56 145 7.65 ug/l # 76 36) 1,1-Dichloropropene 5.81 75 197 17.40 ug/l # 59 37) Ethyl Acetate 4.86 43 180 14.50 ug/l # 69 39) Methylcyclohexane 7.47 83 116 8.67 ug/l # 17 40) Benzene 6.16 78 152 4.60 ug/l # 51 41) Methacrylonitrile 5.06 41 91 12.82 ug/l # 2 42) 1,2-Dichloroethane 6.21 62 21 1.65 ug/l # 74 43) Isopropyl Acetate 6.45 43 43 2.26 ug/l # 61 44) Trichloroethene 7.21 130 149 14.74 ug/l 90 45) 1,2-Dichloropropane 7.57 63 19 2.30 ug/l # 44 46) Dibromomethane 7.67 93 88 15.08 ug/l # 1 47) Bromodichloromethane 7.91 83 26 2.41 ug/l # 25 48) Methyl methacrylate 7.79 41 85 8.19 ug/l # 46 51) 4-Methyl-2-Pentanone 8.66 43 327 25.83 ug/l # 47 52) Toluene 8.79 92 213 9.85 ug/l 90 53) t-1,3-Dichloropropene 8.45 75 39 3.20 ug/l # 44 54) cis-1,3-Dichloropropene 9.04 75 157 14.14 ug/l # 67 56) Ethyl methacrylate 9.16 69 23 1.83 ug/l # 1 58) 2-Chloroethyl Vinyl ether 8.33 63 27 4.38 ug/l # 43 59) 2-Hexanone 9.50 43 26 2.68 ug/l # 25 60) Dibromochloromethane 9.34 129 174 19.51 ug/l # 11 61) 1,2-Dibromoethane 9.68 107 41 4.48 ug/l # 2 64) Tetrachloroethene 9.34 164 95 12.88 ug/l # 27 65) Chlorobenzene 10.14 112 301 19.40 ug/l 94 67) Ethyl Benzene 10.26 91 375 14.75 ug/l 96 68) m/p-Xylenes 10.36 106 252 25.08 ug/l 75 70) Styrene 10.72 104 203 12.80 ug/l # 87 73) Isopropylbenzene 11.02 105 311 7.72 ug/l 97 74) N-amyl acetate 6.49 43 109 5.96 ug/l # 58 76) 1,2,3-Trichloropropane 11.14 75 14246 1206.91 ug/l # 38 77) Bromobenzene 11.26 156 110 9.39 ug/l # 52 78) n-propylbenzene 11.37 91 530 12.08 ug/l 93 79) 2-Chlorotoluene 11.51 91 413 15.30 ug/l 79 80) 1,3,5-Trimethylbenzene 11.51 105 322 9.60 ug/l 93 81) trans-1,4-Dichloro-2-buten 11.14 75 14246 3522.35 ug/l # 7 82) 4-Chlorotoluene 11.51 91 413 13.26 ug/l 85 83) tert-Butylbenzene 11.77 119 277 8.30 ug/l # 80 84) 1,2,4-Trimethylbenzene 11.82 105 416 12.07 ug/l 76 85) sec-Butylbenzene 11.95 105 351 8.76 ug/l # 54 86) p-Isopropyltoluene 12.07 119 383 10.42 ug/l # 62 87) 1,3-Dichlorobenzene 12.04 146 368 17.57 ug/l 95 88) 1,4-Dichlorobenzene 12.10 146 436 20.41 ug/l 89 89) n-Butylbenzene 12.39 91 276 9.06 ug/l # 69 91) 1,2-Dichlorobenzene 12.40 146 241 11.31 ug/l 92 93) 1,2,4-Trichlorobenzene 13.65 180 452 29.00 ug/l # 69 94) Hexachlorobutadiene 13.79 225 47 5.51 ug/l # 54 95) Naphthalene 13.84 128 489 11.34 ug/l # 81 96) 1,2,3-Trichlorobenzene 14.04 180 243 15.19 ug/l 88 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed