Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001529.D Acq On : 08 May 2018 22:28 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 24 Sample Multiplier: 1 Quant Time: May 09 07:40:01 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 231900 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 305722 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 295916 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 216407 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 173053 51.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.84% 35) Dibromofluoromethane 5.51 113 140077 51.51 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.02% 50) Toluene-d8 8.72 98 506834 51.06 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.12% 62) 4-Bromofluorobenzene 11.14 95 194127 50.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.90% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 160143 51.30 ug/l 99 3) Chloromethane 1.32 50 155999 51.31 ug/l 99 4) Vinyl Chloride 1.40 62 162432 51.19 ug/l 98 5) Bromomethane 1.64 94 77080 53.30 ug/l 99 6) Chloroethane 1.72 64 109396 52.16 ug/l 99 7) Trichlorofluoromethane 1.92 101 255971 53.60 ug/l 100 8) Diethyl Ether 2.19 74 98376 52.56 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.38 101 146201 52.22 ug/l 98 10) Methyl Iodide 2.51 142 201518 49.89 ug/l 100 11) Tert butyl alcohol 3.09 59 190773 271.47 ug/l 100 12) 1,1-Dichloroethene 2.37 96 135623 52.85 ug/l 99 13) Acrolein 2.30 56 36613 264.99 ug/l 99 14) Allyl chloride 2.73 41 251676 52.60 ug/l 99 15) Acrylonitrile 3.15 53 438322 276.02 ug/l 99 16) Acetone 2.45 43 390107 257.75 ug/l 99 17) Carbon Disulfide 2.57 76 329584 50.47 ug/l 99 18) Methyl Acetate 2.78 43 230935 58.08 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 482344 53.99 ug/l 98 20) Methylene Chloride 2.86 84 154863 51.68 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 146692 51.22 ug/l 99 22) Diisopropyl ether 3.88 45 476729 53.33 ug/l 99 23) Vinyl Acetate 3.83 43 1973323 264.88 ug/l 100 24) 1,1-Dichloroethane 3.70 63 272932 54.66 ug/l 99 25) 2-Butanone 4.72 43 587270 268.43 ug/l 99 26) 2,2-Dichloropropane 4.59 77 157718 40.90 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 159500 52.30 ug/l 96 28) Bromochloromethane 5.03 49 119000 54.96 ug/l 97 29) Tetrahydrofuran 5.18 42 381278 272.38 ug/l 100 30) Chloroform 5.22 83 283319 55.08 ug/l 99 31) Cyclohexane 5.58 56 224287 52.29 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 250264 55.67 ug/l 99 36) 1,1-Dichloropropene 5.81 75 198369 51.01 ug/l 100 37) Ethyl Acetate 4.87 43 227380 53.34 ug/l 99 38) Carbon Tetrachloride 5.79 117 227016 54.73 ug/l 99 39) Methylcyclohexane 7.46 83 231243 50.30 ug/l 97 40) Benzene 6.15 78 605948 53.35 ug/l 99 41) Methacrylonitrile 5.07 41 129536 53.11 ug/l 99 42) 1,2-Dichloroethane 6.20 62 235080 53.85 ug/l 100 43) Isopropyl Acetate 6.48 43 359648 54.96 ug/l 100 44) Trichloroethene 7.22 130 185107 53.32 ug/l 99 45) 1,2-Dichloropropane 7.52 63 151080 53.35 ug/l 100 46) Dibromomethane 7.67 93 107712 53.73 ug/l 99 47) Bromodichloromethane 7.90 83 210045 56.61 ug/l 99 48) Methyl methacrylate 7.79 41 196541 55.16 ug/l 99 49) 1,4-Dioxane 7.76 88 82394 1070.24 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1224117 281.49 ug/l 99 52) Toluene 8.79 92 397934 53.58 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 230214 54.90 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 209913 48.49 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 161858 54.09 ug/l 99 56) Ethyl methacrylate 9.19 69 237994 55.18 ug/l 100 57) 1,3-Dichloropropane 9.38 76 267379 54.04 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 613717 290.09 ug/l 99 59) 2-Hexanone 9.51 43 928775 278.91 ug/l 100 60) Dibromochloromethane 9.59 129 174787 57.04 ug/l 98 61) 1,2-Dibromoethane 9.68 107 172308 54.84 ug/l 99 64) Tetrachloroethene 9.34 164 224864 54.52 ug/l 99 65) Chlorobenzene 10.15 112 455430 52.48 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 173788 55.98 ug/l 100 67) Ethyl Benzene 10.26 91 758913 53.35 ug/l 100 68) m/p-Xylenes 10.37 106 606173 107.85 ug/l 100 69) o-Xylene 10.71 106 296838 54.34 ug/l 99 70) Styrene 10.72 104 495059 55.79 ug/l 99 71) Bromoform 10.87 173 145007 48.67 ug/l # 99 73) Isopropylbenzene 11.02 105 794417 53.03 ug/l 100 74) N-amyl acetate 6.48 43 359648 52.85 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 234558 53.01 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 231593m 52.77 ug/l 77) Bromobenzene 11.26 156 226739 52.06 ug/l 99 78) n-propylbenzene 11.37 91 883483 54.16 ug/l 100 79) 2-Chlorotoluene 11.43 91 528260 52.62 ug/l 98 80) 1,3,5-Trimethylbenzene 11.51 105 673748 54.02 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 59971 44.12 ug/l 97 82) 4-Chlorotoluene 11.52 91 620377 53.57 ug/l 100 83) tert-Butylbenzene 11.77 119 650365 52.40 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 691091 53.91 ug/l 100 85) sec-Butylbenzene 11.95 105 807041 54.18 ug/l 100 86) p-Isopropyltoluene 12.07 119 742590 54.34 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 403332 51.80 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 412077 51.89 ug/l 100 89) n-Butylbenzene 12.40 91 592570 52.33 ug/l 99 90) Hexachloroethane 12.60 117 115607 56.18 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 415157 52.41 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 55709 57.31 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 305264 52.66 ug/l 99 94) Hexachlorobutadiene 13.79 225 164091 51.74 ug/l 99 95) Naphthalene 13.84 128 903059 56.33 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 319622 53.74 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed