Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001531.D Acq On : 08 May 2018 23:48 Operator : JC/MD Sample : VX0508WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 27 Sample Multiplier: 1 Quant Time: May 09 07:42:59 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 225755 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 297205 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 288896 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 200212 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 166252 51.24 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.48% 35) Dibromofluoromethane 5.51 113 131385 49.70 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.40% 50) Toluene-d8 8.72 98 473631 49.08 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.16% 62) 4-Bromofluorobenzene 11.14 95 176640 47.69 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.38% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 64325 21.17 ug/l 100 3) Chloromethane 1.32 50 61908 20.92 ug/l 100 4) Vinyl Chloride 1.40 62 66756 21.61 ug/l 97 5) Bromomethane 1.64 94 40345 26.95 ug/l 98 6) Chloroethane 1.72 64 43252 21.18 ug/l 96 7) Trichlorofluoromethane 1.93 101 100718 21.67 ug/l 98 8) Diethyl Ether 2.19 74 38683 21.23 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.39 101 57216 20.99 ug/l 99 10) Methyl Iodide 2.51 142 72046 18.32 ug/l 100 11) Tert butyl alcohol 3.08 59 82058 119.94 ug/l 100 12) 1,1-Dichloroethene 2.37 96 54163 21.68 ug/l 97 13) Acrolein 2.30 56 14503 100.56 ug/l 99 14) Allyl chloride 2.73 41 98137 21.07 ug/l 99 15) Acrylonitrile 3.15 53 174567 112.92 ug/l 100 16) Acetone 2.45 43 160077 108.64 ug/l 99 17) Carbon Disulfide 2.57 76 124778 19.63 ug/l 99 18) Methyl Acetate 2.78 43 93810 24.23 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 188788 21.71 ug/l 99 20) Methylene Chloride 2.86 84 61786 21.18 ug/l 94 21) trans-1,2-Dichloroethene 3.17 96 58252 20.89 ug/l 98 22) Diisopropyl ether 3.88 45 180893 20.79 ug/l 99 23) Vinyl Acetate 3.83 43 741263 102.21 ug/l 100 24) 1,1-Dichloroethane 3.70 63 108418 22.30 ug/l 99 25) 2-Butanone 4.72 43 232744 109.28 ug/l 98 26) 2,2-Dichloropropane 4.59 77 55934 14.90 ug/l 96 27) cis-1,2-Dichloroethene 4.60 96 62634 21.10 ug/l 96 28) Bromochloromethane 5.03 49 46870 22.24 ug/l 97 29) Tetrahydrofuran 5.18 42 150811 110.67 ug/l 100 30) Chloroform 5.23 83 110545 22.08 ug/l 99 31) Cyclohexane 5.58 56 85042 20.37 ug/l 94 32) 1,1,1-Trichloroethane 5.50 97 95060 21.72 ug/l 98 36) 1,1-Dichloropropene 5.81 75 76128 20.14 ug/l 98 37) Ethyl Acetate 4.87 43 89427 21.58 ug/l 99 38) Carbon Tetrachloride 5.78 117 85730 21.26 ug/l 95 39) Methylcyclohexane 7.46 83 86426 19.34 ug/l 95 40) Benzene 6.15 78 234601 21.25 ug/l 98 41) Methacrylonitrile 5.07 41 50273 21.20 ug/l 98 42) 1,2-Dichloroethane 6.21 62 93433 22.01 ug/l 99 43) Isopropyl Acetate 6.48 43 135088 21.23 ug/l 99 44) Trichloroethene 7.22 130 71174 21.09 ug/l 96 45) 1,2-Dichloropropane 7.52 63 57342 20.83 ug/l 98 46) Dibromomethane 7.67 93 42160 21.63 ug/l 98 47) Bromodichloromethane 7.91 83 77382 21.45 ug/l 100 48) Methyl methacrylate 7.79 41 73393 21.19 ug/l 100 49) 1,4-Dioxane 7.76 88 32605 435.65 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 471898 111.63 ug/l 98 52) Toluene 8.79 92 153559 21.27 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 83284 20.43 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 74252 19.08 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 61787 21.24 ug/l 98 56) Ethyl methacrylate 9.19 69 86242 20.57 ug/l 99 57) 1,3-Dichloropropane 9.38 76 102929 21.40 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 231734 112.68 ug/l 99 59) 2-Hexanone 9.51 43 351287 108.51 ug/l 100 60) Dibromochloromethane 9.59 129 62478 20.97 ug/l 100 61) 1,2-Dibromoethane 9.68 107 65198 21.35 ug/l 99 64) Tetrachloroethene 9.34 164 85199 21.16 ug/l 98 65) Chlorobenzene 10.15 112 174573 20.60 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 63269 20.88 ug/l 99 67) Ethyl Benzene 10.26 91 282567 20.35 ug/l 99 68) m/p-Xylenes 10.37 106 224994 41.00 ug/l 99 69) o-Xylene 10.71 106 109515 20.54 ug/l 99 70) Styrene 10.72 104 178770 20.63 ug/l 100 71) Bromoform 10.86 173 48959 19.17 ug/l # 99 73) Isopropylbenzene 11.02 105 294704 21.26 ug/l 100 74) N-amyl acetate 6.48 43 135088 21.46 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 88446 21.61 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 87274m 21.49 ug/l 77) Bromobenzene 11.26 156 83368 20.69 ug/l 99 78) n-propylbenzene 11.37 91 320583 21.24 ug/l 99 79) 2-Chlorotoluene 11.43 91 195857 21.09 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 246294 21.34 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 18671 17.69 ug/l 89 82) 4-Chlorotoluene 11.52 91 227787 21.26 ug/l 100 83) tert-Butylbenzene 11.77 119 235405 20.50 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 253556 21.38 ug/l 99 85) sec-Butylbenzene 11.95 105 290682 21.09 ug/l 100 86) p-Isopropyltoluene 12.07 119 265587 21.01 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 148713 20.65 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 150338 20.46 ug/l 99 89) n-Butylbenzene 12.40 91 202995 19.38 ug/l 100 90) Hexachloroethane 12.60 117 39365 20.68 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 153851 20.99 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 20107 22.36 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 105605 19.69 ug/l 99 94) Hexachlorobutadiene 13.79 225 57664 19.65 ug/l 100 95) Naphthalene 13.84 128 314941 21.24 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 113267 20.58 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed