Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001532.D Acq On : 09 May 2018 00:15 Operator : JC/MD Sample : VX0508WBSD02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 28 Sample Multiplier: 1 Quant Time: May 09 07:47:14 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 223608 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 294175 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 283402 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 197286 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 165074 51.36 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.72% 35) Dibromofluoromethane 5.51 113 130796 49.99 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.98% 50) Toluene-d8 8.72 98 470987 49.31 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.62% 62) 4-Bromofluorobenzene 11.14 95 174429 47.57 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.14% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 64082 21.29 ug/l 99 3) Chloromethane 1.32 50 61334 20.92 ug/l 99 4) Vinyl Chloride 1.40 62 64880 21.21 ug/l 98 5) Bromomethane 1.64 94 38789 26.05 ug/l 98 6) Chloroethane 1.72 64 42693 21.11 ug/l 99 7) Trichlorofluoromethane 1.93 101 99717 21.66 ug/l 98 8) Diethyl Ether 2.19 74 39426 21.85 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 56963 21.10 ug/l 99 10) Methyl Iodide 2.51 142 75053 19.27 ug/l 100 11) Tert butyl alcohol 3.09 59 80334 118.55 ug/l 98 12) 1,1-Dichloroethene 2.37 96 52337 21.15 ug/l 100 13) Acrolein 2.29 56 14942 105.09 ug/l 96 14) Allyl chloride 2.73 41 96037 20.82 ug/l 99 15) Acrylonitrile 3.15 53 175824 114.82 ug/l 99 16) Acetone 2.45 43 161476 110.65 ug/l 99 17) Carbon Disulfide 2.57 76 122921 19.52 ug/l 100 18) Methyl Acetate 2.78 43 96576 25.19 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 192622 22.36 ug/l 100 20) Methylene Chloride 2.86 84 61814 21.39 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 56779 20.56 ug/l 96 22) Diisopropyl ether 3.88 45 182224 21.14 ug/l 99 23) Vinyl Acetate 3.83 43 753859 104.94 ug/l 99 24) 1,1-Dichloroethane 3.70 63 105343 21.88 ug/l 99 25) 2-Butanone 4.72 43 237600 112.63 ug/l 98 26) 2,2-Dichloropropane 4.59 77 53755 14.46 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 61615 20.95 ug/l 97 28) Bromochloromethane 5.03 49 46741 22.39 ug/l 98 29) Tetrahydrofuran 5.18 42 151629 112.34 ug/l 99 30) Chloroform 5.22 83 108474 21.87 ug/l 99 31) Cyclohexane 5.57 56 83938 20.30 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 94783 21.87 ug/l 99 36) 1,1-Dichloropropene 5.81 75 75430 20.16 ug/l 99 37) Ethyl Acetate 4.87 43 89540 21.83 ug/l 99 38) Carbon Tetrachloride 5.79 117 84689 21.22 ug/l 98 39) Methylcyclohexane 7.46 83 84372 19.07 ug/l 97 40) Benzene 6.15 78 233223 21.34 ug/l 98 41) Methacrylonitrile 5.07 41 50685 21.60 ug/l 98 42) 1,2-Dichloroethane 6.21 62 93943 22.36 ug/l 99 43) Isopropyl Acetate 6.48 43 137948 21.91 ug/l 100 44) Trichloroethene 7.22 130 71229 21.32 ug/l 99 45) 1,2-Dichloropropane 7.52 63 58685 21.54 ug/l 99 46) Dibromomethane 7.67 93 41987 21.77 ug/l 99 47) Bromodichloromethane 7.90 83 76488 21.43 ug/l 99 48) Methyl methacrylate 7.79 41 74469 21.72 ug/l 99 49) 1,4-Dioxane 7.76 88 33928 458.00 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 481805 115.14 ug/l 99 52) Toluene 8.79 92 149382 20.90 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 82509 20.45 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 74032 19.21 ug/l 96 55) 1,1,2-Trichloroethane 9.22 97 63508 22.06 ug/l 96 56) Ethyl methacrylate 9.19 69 87044 20.97 ug/l 97 57) 1,3-Dichloropropane 9.38 76 104908 22.04 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 235633 115.75 ug/l 98 59) 2-Hexanone 9.51 43 363190 113.35 ug/l 99 60) Dibromochloromethane 9.59 129 63711 21.61 ug/l 99 61) 1,2-Dibromoethane 9.68 107 65955 21.82 ug/l 99 64) Tetrachloroethene 9.34 164 86699 21.95 ug/l 97 65) Chlorobenzene 10.15 112 171604 20.65 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 62983 21.18 ug/l 99 67) Ethyl Benzene 10.26 91 278231 20.42 ug/l 100 68) m/p-Xylenes 10.37 106 220874 41.03 ug/l 98 69) o-Xylene 10.71 106 109127 20.86 ug/l 98 70) Styrene 10.72 104 177758 20.92 ug/l 100 71) Bromoform 10.87 173 48727 19.39 ug/l 100 73) Isopropylbenzene 11.02 105 289963 21.23 ug/l 100 74) N-amyl acetate 6.48 43 137948 22.24 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 89088 22.09 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 87677m 21.91 ug/l 77) Bromobenzene 11.26 156 83501 21.03 ug/l 99 78) n-propylbenzene 11.37 91 315136 21.19 ug/l 99 79) 2-Chlorotoluene 11.43 91 194418 21.24 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 241649 21.25 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 18483 17.75 ug/l # 86 82) 4-Chlorotoluene 11.52 91 223728 21.19 ug/l 99 83) tert-Butylbenzene 11.77 119 232985 20.59 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 249535 21.35 ug/l 100 85) sec-Butylbenzene 11.95 105 286425 21.09 ug/l 100 86) p-Isopropyltoluene 12.07 119 260176 20.88 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 145740 20.53 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 149545 20.66 ug/l 99 89) n-Butylbenzene 12.40 91 202030 19.57 ug/l 98 90) Hexachloroethane 12.60 117 39356 20.98 ug/l 96 91) 1,2-Dichlorobenzene 12.40 146 151243 20.94 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 20332 22.94 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 105982 20.06 ug/l 99 94) Hexachlorobutadiene 13.79 225 57553 19.91 ug/l 99 95) Naphthalene 13.84 128 317885 21.75 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 112357 20.72 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed