Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050818\ Data File : VX001551.D Acq On : 09 May 2018 08:41 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 47 Sample Multiplier: 1 Quant Time: May 09 09:00:19 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 228466 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 296713 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 288760 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 210681 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 168267 51.24 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.48% 35) Dibromofluoromethane 5.51 113 138023 52.30 ug/l 0.00 Spiked Amount 50.000 Recovery = 104.60% 50) Toluene-d8 8.72 98 500808 51.99 ug/l 0.00 Spiked Amount 50.000 Recovery = 103.98% 62) 4-Bromofluorobenzene 11.14 95 188337 50.93 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.86% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 160951 52.33 ug/l 99 3) Chloromethane 1.32 50 152687 50.98 ug/l 100 4) Vinyl Chloride 1.40 62 160828 51.45 ug/l 98 5) Bromomethane 1.64 94 74064 51.90 ug/l 100 6) Chloroethane 1.72 64 108078 52.30 ug/l 100 7) Trichlorofluoromethane 1.93 101 252730 53.72 ug/l 100 8) Diethyl Ether 2.19 74 95612 51.85 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 141719 51.38 ug/l 99 10) Methyl Iodide 2.51 142 208509 52.39 ug/l 99 11) Tert butyl alcohol 3.09 59 183200 264.61 ug/l 98 12) 1,1-Dichloroethene 2.37 96 133969 52.99 ug/l 98 13) Acrolein 2.30 56 29888 217.47 ug/l 97 14) Allyl chloride 2.73 41 236902 50.26 ug/l 99 15) Acrylonitrile 3.15 53 409813 261.94 ug/l 99 16) Acetone 2.45 43 371370 249.06 ug/l 100 17) Carbon Disulfide 2.57 76 317945 49.42 ug/l 100 18) Methyl Acetate 2.78 43 223884 57.15 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 473259 53.77 ug/l 100 20) Methylene Chloride 2.86 84 151640 51.36 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 143207 50.76 ug/l 98 22) Diisopropyl ether 3.88 45 473340 53.75 ug/l 99 23) Vinyl Acetate 3.83 43 1906614 259.77 ug/l 100 24) 1,1-Dichloroethane 3.70 63 244441 49.69 ug/l 100 25) 2-Butanone 4.71 43 561105 260.33 ug/l 98 26) 2,2-Dichloropropane 4.59 77 107959 28.42 ug/l 93 27) cis-1,2-Dichloroethene 4.60 96 157960 52.57 ug/l 94 28) Bromochloromethane 5.03 49 113601 53.26 ug/l 98 29) Tetrahydrofuran 5.17 42 365039 264.70 ug/l 100 30) Chloroform 5.22 83 279712 55.20 ug/l 96 31) Cyclohexane 5.58 56 223296 52.85 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 248526 56.11 ug/l 99 36) 1,1-Dichloropropene 5.81 75 199154 52.77 ug/l 99 37) Ethyl Acetate 4.87 43 217029 52.46 ug/l 99 38) Carbon Tetrachloride 5.79 117 224874 55.86 ug/l 99 39) Methylcyclohexane 7.46 83 231043 51.78 ug/l 97 40) Benzene 6.15 78 598915 54.33 ug/l 100 41) Methacrylonitrile 5.07 41 125599 53.06 ug/l 99 42) 1,2-Dichloroethane 6.20 62 233426 55.09 ug/l 100 43) Isopropyl Acetate 6.48 43 347130 54.66 ug/l 100 44) Trichloroethene 7.22 130 181205 53.78 ug/l 97 45) 1,2-Dichloropropane 7.52 63 152016 55.31 ug/l 100 46) Dibromomethane 7.67 93 105864 54.41 ug/l 99 47) Bromodichloromethane 7.90 83 207012 57.49 ug/l 98 48) Methyl methacrylate 7.79 41 188238 54.43 ug/l 99 49) 1,4-Dioxane 7.76 88 80606 1078.81 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1182969 280.29 ug/l 99 52) Toluene 8.79 92 398899 55.34 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 216095 53.10 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 195645 46.66 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 159395 54.89 ug/l 99 56) Ethyl methacrylate 9.19 69 233939 55.88 ug/l 99 57) 1,3-Dichloropropane 9.38 76 261929 54.55 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 585225 285.02 ug/l 100 59) 2-Hexanone 9.51 43 883746 273.45 ug/l 100 60) Dibromochloromethane 9.59 129 173156 58.22 ug/l 98 61) 1,2-Dibromoethane 9.68 107 170741 56.00 ug/l 99 64) Tetrachloroethene 9.34 164 226860 56.36 ug/l 100 65) Chlorobenzene 10.15 112 451738 53.34 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 171028 56.46 ug/l 100 67) Ethyl Benzene 10.26 91 748022 53.89 ug/l 100 68) m/p-Xylenes 10.37 106 604330 110.19 ug/l 99 69) o-Xylene 10.71 106 296133 55.56 ug/l 99 70) Styrene 10.72 104 493317 56.97 ug/l 99 71) Bromoform 10.87 173 141257 48.59 ug/l 100 73) Isopropylbenzene 11.02 105 789256 54.11 ug/l 100 74) N-amyl acetate 6.48 43 347130 52.40 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 228120 52.96 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 223898m 52.40 ug/l 77) Bromobenzene 11.26 156 222915 52.57 ug/l 99 78) n-propylbenzene 11.37 91 877167 55.23 ug/l 99 79) 2-Chlorotoluene 11.43 91 524929 53.71 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 663221 54.62 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 52324 39.98 ug/l 97 82) 4-Chlorotoluene 11.52 91 613286 54.39 ug/l 100 83) tert-Butylbenzene 11.77 119 638397 52.84 ug/l 97 84) 1,2,4-Trimethylbenzene 11.81 105 684841 54.87 ug/l 100 85) sec-Butylbenzene 11.95 105 793699 54.73 ug/l 100 86) p-Isopropyltoluene 12.07 119 732822 55.08 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 399886 52.76 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 405898 52.50 ug/l 100 89) n-Butylbenzene 12.40 91 580286 52.64 ug/l 100 90) Hexachloroethane 12.60 117 114610 57.21 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 412936 53.55 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 53959 57.01 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 300686 53.28 ug/l 100 94) Hexachlorobutadiene 13.79 225 156275 50.61 ug/l 100 95) Naphthalene 13.84 128 877393 56.22 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 314403 54.30 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed