Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\Data\VX050918\ Data File : VX001553.D Acq On : 09 May 2018 13:11 Operator : JC/MD Sample : VSTDCCC020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 10 04:37:22 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X043018W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Tue May 01 09:17:40 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.02 128 57016 30.00 ug/l -0.01 28) 1,4-Difluorobenzene 6.87 114 303914 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 283811 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 125630 30.55 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 101.83% 60) 4-Bromofluorobenzene 11.14 95 135780 28.56 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 95.20% 63) Toluene-d8 8.72 98 377704 31.03 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 103.43% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 58811 15.73 ug/l 98 3) Chloromethane 1.32 50 52905 15.16 ug/l 96 4) Vinyl Chloride 1.40 62 56867 15.54 ug/l 99 5) Bromomethane 1.64 94 38589 13.96 ug/l 99 6) Chloroethane 1.73 64 36454 16.28 ug/l 99 7) Trichlorofluoromethane 1.93 101 89932 14.79 ug/l 100 8) Diethyl Ether 2.19 74 32997 15.63 ug/l 89 9) 1,1,2-Trichlorotrifluoroet 2.39 101 53450 15.50 ug/l 94 10) 1,1-Dichloroethene 2.37 96 46328 14.83 ug/l 91 11) Methyl Iodide 2.51 142 65732 17.30 ug/l 95 12) Methyl Acetate 2.78 43 74232 18.08 ug/l 99 13) Acrolein 2.29 56 14698 30.01 ug/l 98 14) Acrylonitrile 3.15 53 136922 83.79 ug/l 98 15) Acetone 2.45 58 42530 83.64 ug/l 100 16) Carbon Disulfide 2.57 76 106465 12.82 ug/l 99 17) Allyl chloride 2.73 41 84401 15.23 ug/l 91 18) Methylene Chloride 2.86 84 51774 15.21 ug/l 98 19) trans-1,2-Dichloroethene 3.17 96 49272 14.63 ug/l 94 20) Diisopropyl ether 3.87 45 164234 15.06 ug/l 97 21) 1,1-Dichloroethane 3.70 63 92880 15.85 ug/l 98 22) cis-1,2-Dichloroethene 4.60 96 55076 14.65 ug/l 96 23) tert-Butyl Alcohol 3.07 59 63044 94.40 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 158800 14.83 ug/l 97 25) Chloroform 5.21 83 96528 15.13 ug/l 95 26) Cyclohexane 5.57 56 76809 14.41 ug/l # 96 29) 1,1-Dichloropropene 5.80 75 67740 15.04 ug/l 99 30) 2-Butanone 4.71 43 191012 82.78 ug/l 97 31) 2,2-Dichloropropane 4.59 77 72141 14.68 ug/l 98 32) 1,1,1-Trichloroethane 5.49 97 81855 15.02 ug/l 98 33) Carbon Tetrachloride 5.78 117 73338 14.94 ug/l 98 34) Benzene 6.15 78 200352 15.02 ug/l 94 35) Methacrylonitrile 5.07 41 41448 16.19 ug/l 90 36) 1,2-Dichloroethane 6.20 62 80842 15.79 ug/l 98 37) Trichloroethene 7.21 130 61982 15.32 ug/l 96 38) Methylcyclohexane 7.46 83 79854 15.07 ug/l 94 39) 1,2-Dichloropropane 7.52 63 50806 15.02 ug/l 95 40) Dibromomethane 7.67 93 36255 15.23 ug/l 86 41) Bromodichloromethane 7.90 83 65772 14.63 ug/l 98 42) Vinyl Acetate 3.82 43 685304 75.51 ug/l 99 43) Ethyl Acetate 4.87 43 67041 15.09 ug/l 97 44) Isopropyl Acetate 6.47 43 110578 14.63 ug/l 100 45) 1,4-Dioxane 7.76 88 24368 354.58 ug/l 95 46) Methyl methacrylate 7.78 41 59422 15.11 ug/l 89 47) n-amyl Acetate 10.90 43 93358 12.87 ug/l 95 48) t-1,3-Dichloropropene 8.44 75 73752 13.93 ug/l 99 49) cis-1,3-Dichloropropene 9.05 75 68001 13.41 ug/l 96 50) 1,1,2-Trichloroethane 9.22 97 54047 15.29 ug/l 97 51) Ethyl methacrylate 9.19 69 71051 14.11 ug/l 97 52) 1,3-Dichloropropane 9.38 76 88105 15.42 ug/l 98 53) Dibromochloromethane 9.59 129 53408 13.69 ug/l 97 54) 1,2-Dibromoethane 9.68 107 55032 14.54 ug/l 97 55) 2-Chloroethyl vinyl ether 8.32 63 197098 79.88 ug/l 98 56) Bromoform 10.86 173 40192 12.59 ug/l # 96 58) 4-Methyl-2-Pentanone 8.65 43 374832 79.57 ug/l 99 59) 2-Hexanone 9.50 43 288022 78.48 ug/l 98 61) Tetrachloroethene 9.34 164 76046 17.48 ug/l 90 62) Toluene 8.79 91 228820 15.00 ug/l 97 64) Chlorobenzene 10.14 112 150417 14.62 ug/l 100 65) 1,1,1,2-Tetrachloroethane 10.23 131 55418 14.75 ug/l 97 66) Ethyl Benzene 10.26 91 245018 14.39 ug/l 99 67) m/p-Xylenes 10.37 106 197109 29.15 ug/l 97 68) o-Xylene 10.71 106 94223 14.41 ug/l 99 69) Styrene 10.72 104 153874 14.14 ug/l 100 70) Isopropylbenzene 11.02 105 255264 14.38 ug/l 99 71) 1,1,2,2-Tetrachloroethane 11.27 83 73561 14.13 ug/l 99 72) 1,2,3-Trichloropropane 11.30 75 63787m 13.69 ug/l 73) Bromobenzene 11.26 156 72325 14.02 ug/l 97 74) n-propylbenzene 11.37 91 290306 14.48 ug/l 99 75) 2-Chlorotoluene 11.43 91 175515 14.50 ug/l 100 76) 1,3,5-Trimethylbenzene 11.51 105 217996 14.41 ug/l 65 77) t-1,4-Dichloro-2-butene 11.08 75 17480 12.61 ug/l 80 78) 4-Chlorotoluene 11.52 91 200126 13.87 ug/l 99 79) tert-butylbenzene 12.07 119 242604 14.99 ug/l 93 80) 1,2,4-Trimethylbenzene 11.81 105 221878 14.41 ug/l 99 81) sec-Butylbenzene 11.95 105 262989 14.97 ug/l 99 82) p-Isopropyltoluene 12.07 119 242604 14.99 ug/l 98 83) 1,3-Dichlorobenzene 12.03 146 133987 14.24 ug/l 97 84) 1,4-Dichlorobenzene 12.10 146 133687 13.94 ug/l 99 85) n-Butylbenzene 12.40 91 194497 13.90 ug/l 97 86) Hexachloroethane 12.60 117 33850 13.68 ug/l 73 87) 1,2-Dichlorobenzene 12.40 146 133821 14.31 ug/l 97 88) 1,2-Dibromo-3-Chloropropan 13.01 75 15563 14.30 ug/l 93 89) 1,2,4-Trichlorobenzene 13.65 180 97938 13.82 ug/l 98 90) Hexachlorobutadiene 13.79 225 55613 16.90 ug/l 98 91) Naphthalene 13.84 128 263375 14.32 ug/l 99 92) 1,2,3-Trichlorobenzene 14.02 180 100281 14.34 ug/l 96 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed