Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001554.D Acq On : 09 May 2018 13:38 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 3 Sample Multiplier: 1 Quant Time: May 10 04:38:33 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 234192 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 296485 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 285686 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 208343 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 162254 48.20 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.40% 35) Dibromofluoromethane 5.51 113 132221 50.14 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.28% 50) Toluene-d8 8.72 98 483932 50.27 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.54% 62) 4-Bromofluorobenzene 11.14 95 183311 49.61 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.22% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 161558 51.25 ug/l 100 3) Chloromethane 1.32 50 149053 48.55 ug/l 98 4) Vinyl Chloride 1.40 62 158350 49.42 ug/l 100 5) Bromomethane 1.64 94 76247 52.13 ug/l 98 6) Chloroethane 1.72 64 104868 49.51 ug/l 100 7) Trichlorofluoromethane 1.93 101 250826 52.01 ug/l 100 8) Diethyl Ether 2.19 74 94993 50.26 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.38 101 145594 51.50 ug/l 99 10) Methyl Iodide 2.51 142 209321 51.31 ug/l 99 11) Tert butyl alcohol 3.08 59 182313 256.89 ug/l 100 12) 1,1-Dichloroethene 2.37 96 131178 50.62 ug/l 99 13) Acrolein 2.29 56 31091 220.87 ug/l 97 14) Allyl chloride 2.73 41 252141 52.18 ug/l 99 15) Acrylonitrile 3.15 53 409646 255.44 ug/l 100 16) Acetone 2.45 43 406262 265.80 ug/l 100 17) Carbon Disulfide 2.57 76 319332 48.42 ug/l 100 18) Methyl Acetate 2.78 43 218800 54.49 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 469918 52.08 ug/l 100 20) Methylene Chloride 2.86 84 149266 49.32 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 141195 48.82 ug/l 96 22) Diisopropyl ether 3.88 45 465338 51.55 ug/l 99 23) Vinyl Acetate 3.83 43 1946755 258.75 ug/l 99 24) 1,1-Dichloroethane 3.70 63 262848 52.12 ug/l 100 25) 2-Butanone 4.71 43 586681 265.54 ug/l 98 26) 2,2-Dichloropropane 4.59 77 216901 55.70 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 161047 52.29 ug/l 97 28) Bromochloromethane 5.03 49 115668 52.90 ug/l 98 29) Tetrahydrofuran 5.17 42 366335 259.14 ug/l 100 30) Chloroform 5.22 83 277378 53.40 ug/l 99 31) Cyclohexane 5.57 56 226071 52.20 ug/l 94 32) 1,1,1-Trichloroethane 5.50 97 246249 54.24 ug/l 99 36) 1,1-Dichloropropene 5.81 75 200781 53.24 ug/l 99 37) Ethyl Acetate 4.87 43 218534 52.86 ug/l 99 38) Carbon Tetrachloride 5.79 117 225561 56.08 ug/l 100 39) Methylcyclohexane 7.46 83 238646 53.52 ug/l 98 40) Benzene 6.15 78 594379 53.96 ug/l 99 41) Methacrylonitrile 5.07 41 125531 53.07 ug/l 99 42) 1,2-Dichloroethane 6.20 62 232251 54.86 ug/l 100 43) Isopropyl Acetate 6.48 43 351509 55.39 ug/l 100 44) Trichloroethene 7.22 130 183391 54.47 ug/l 99 45) 1,2-Dichloropropane 7.52 63 148643 54.13 ug/l 97 46) Dibromomethane 7.67 93 104891 53.95 ug/l 99 47) Bromodichloromethane 7.90 83 202342 56.24 ug/l 100 48) Methyl methacrylate 7.78 41 190482 55.12 ug/l 100 49) 1,4-Dioxane 7.76 88 78661 1053.59 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1186502 281.34 ug/l 100 52) Toluene 8.79 92 397174 55.14 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 239951 59.01 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 222843 52.87 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 158261 54.54 ug/l 98 56) Ethyl methacrylate 9.19 69 235735 56.36 ug/l 100 57) 1,3-Dichloropropane 9.38 76 259524 54.09 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 619593 301.99 ug/l 100 59) 2-Hexanone 9.51 43 902925 279.60 ug/l 100 60) Dibromochloromethane 9.59 129 169831 57.15 ug/l 99 61) 1,2-Dibromoethane 9.68 107 167542 54.99 ug/l 100 64) Tetrachloroethene 9.34 164 213690 53.66 ug/l 98 65) Chlorobenzene 10.15 112 446639 53.31 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 167681 55.95 ug/l 100 67) Ethyl Benzene 10.26 91 744651 54.22 ug/l 100 68) m/p-Xylenes 10.37 106 597049 110.03 ug/l 99 69) o-Xylene 10.70 106 291199 55.22 ug/l 99 70) Styrene 10.72 104 485205 56.63 ug/l 99 71) Bromoform 10.87 173 139817 48.61 ug/l 100 73) Isopropylbenzene 11.02 105 786479 54.53 ug/l 100 74) N-amyl acetate 6.48 43 351509 53.66 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 227802 53.48 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 228992m 54.19 ug/l 77) Bromobenzene 11.26 156 218559 52.12 ug/l 99 78) n-propylbenzene 11.37 91 873820 55.64 ug/l 99 79) 2-Chlorotoluene 11.43 91 520037 53.81 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 659455 54.92 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 65430 49.43 ug/l 100 82) 4-Chlorotoluene 11.52 91 606413 54.39 ug/l 99 83) tert-Butylbenzene 11.77 119 644494 53.94 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 674271 54.63 ug/l 100 85) sec-Butylbenzene 11.95 105 795904 55.50 ug/l 100 86) p-Isopropyltoluene 12.07 119 736550 55.98 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 398475 53.16 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 403179 52.74 ug/l 100 89) n-Butylbenzene 12.40 91 608524 55.82 ug/l 99 90) Hexachloroethane 12.60 117 112278 56.68 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 404787 53.08 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 52518 56.11 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 306706 54.96 ug/l 99 94) Hexachlorobutadiene 13.79 225 168178 55.08 ug/l 98 95) Naphthalene 13.84 128 871080 56.44 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 315309 55.07 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed