Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001558.D Acq On : 09 May 2018 16:39 Operator : JC/MD Sample : VX0509WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 7 Sample Multiplier: 1 Quant Time: May 10 04:45:05 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 250478 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 322963 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 307079 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 215412 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 183304 50.92 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.84% 35) Dibromofluoromethane 5.51 113 147427 51.32 ug/l 0.00 Spiked Amount 50.000 Recovery = 102.64% 50) Toluene-d8 8.72 98 526126 50.17 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.34% 62) 4-Bromofluorobenzene 11.14 95 197435 49.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.10% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 72571 21.52 ug/l 98 3) Chloromethane 1.32 50 67523 20.56 ug/l 99 4) Vinyl Chloride 1.40 62 72445 21.14 ug/l 100 5) Bromomethane 1.64 94 43268 25.92 ug/l 99 6) Chloroethane 1.72 64 47423 20.93 ug/l 95 7) Trichlorofluoromethane 1.93 101 113327 21.97 ug/l 100 8) Diethyl Ether 2.19 74 43348 21.44 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 66038 21.84 ug/l 98 10) Methyl Iodide 2.51 142 84432 19.35 ug/l 99 11) Tert butyl alcohol 3.09 59 81676 107.60 ug/l 99 12) 1,1-Dichloroethene 2.37 96 60302 21.76 ug/l 98 13) Acrolein 2.30 56 13934 85.44 ug/l 100 14) Allyl chloride 2.73 41 112837 21.83 ug/l 99 15) Acrylonitrile 3.15 53 188780 110.06 ug/l 100 16) Acetone 2.45 43 202845 124.08 ug/l 97 17) Carbon Disulfide 2.57 76 135269 19.18 ug/l 100 18) Methyl Acetate 2.78 43 104001 24.21 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 214326 22.21 ug/l 97 20) Methylene Chloride 2.86 84 68906 21.29 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 63728 20.60 ug/l 97 22) Diisopropyl ether 3.88 45 205865 21.32 ug/l 98 23) Vinyl Acetate 3.83 43 854551 106.20 ug/l 99 24) 1,1-Dichloroethane 3.70 63 121285 22.49 ug/l 98 25) 2-Butanone 4.72 43 267865 113.36 ug/l 99 26) 2,2-Dichloropropane 4.59 77 92706 22.26 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 70991 21.55 ug/l 99 28) Bromochloromethane 5.02 49 56173 24.02 ug/l 98 29) Tetrahydrofuran 5.18 42 161602 106.88 ug/l 100 30) Chloroform 5.22 83 123467 22.22 ug/l 98 31) Cyclohexane 5.57 56 96469 20.82 ug/l 95 32) 1,1,1-Trichloroethane 5.50 97 108894 22.43 ug/l 99 36) 1,1-Dichloropropene 5.81 75 86969 21.17 ug/l 99 37) Ethyl Acetate 4.87 43 97460 21.64 ug/l 99 38) Carbon Tetrachloride 5.79 117 96892 22.11 ug/l 98 39) Methylcyclohexane 7.46 83 101773 20.95 ug/l 99 40) Benzene 6.15 78 260757 21.73 ug/l 99 41) Methacrylonitrile 5.07 41 56192 21.81 ug/l 98 42) 1,2-Dichloroethane 6.21 62 104411 22.64 ug/l 99 43) Isopropyl Acetate 6.48 43 148997 21.55 ug/l 100 44) Trichloroethene 7.22 130 80331 21.90 ug/l 98 45) 1,2-Dichloropropane 7.52 63 66585 22.26 ug/l 98 46) Dibromomethane 7.67 93 46441 21.93 ug/l 99 47) Bromodichloromethane 7.91 83 87470 22.32 ug/l 99 48) Methyl methacrylate 7.79 41 80620 21.42 ug/l 99 49) 1,4-Dioxane 7.76 88 33605 413.20 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 510550 111.14 ug/l 99 52) Toluene 8.79 92 172860 22.03 ug/l 100 53) t-1,3-Dichloropropene 8.45 75 98760 22.30 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 87365 20.48 ug/l 100 55) 1,1,2-Trichloroethane 9.22 97 70241 22.22 ug/l 97 56) Ethyl methacrylate 9.19 69 97806 21.46 ug/l 99 57) 1,3-Dichloropropane 9.38 76 114888 21.98 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 243940 109.15 ug/l 99 59) 2-Hexanone 9.51 43 392589 111.60 ug/l 99 60) Dibromochloromethane 9.59 129 71025 21.94 ug/l 99 61) 1,2-Dibromoethane 9.68 107 73229 22.06 ug/l 99 64) Tetrachloroethene 9.34 164 92307 21.57 ug/l 99 65) Chlorobenzene 10.15 112 196967 21.87 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 71648 22.24 ug/l 99 67) Ethyl Benzene 10.26 91 319044 21.61 ug/l 99 68) m/p-Xylenes 10.37 106 256505 43.98 ug/l 100 69) o-Xylene 10.71 106 124548 21.97 ug/l 100 70) Styrene 10.72 104 202256 21.96 ug/l 100 71) Bromoform 10.87 173 55493 20.20 ug/l # 100 73) Isopropylbenzene 11.02 105 333698 22.38 ug/l 100 74) N-amyl acetate 6.48 43 148997 22.00 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 99668 22.63 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 97795m 22.38 ug/l 77) Bromobenzene 11.26 156 94217 21.73 ug/l 98 78) n-propylbenzene 11.37 91 368245 22.68 ug/l 99 79) 2-Chlorotoluene 11.43 91 223996 22.42 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 281391 22.66 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 24765 20.81 ug/l 91 82) 4-Chlorotoluene 11.52 91 258670 22.44 ug/l 99 83) tert-Butylbenzene 11.77 119 280454 22.70 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 290497 22.77 ug/l 100 85) sec-Butylbenzene 11.95 105 337978 22.79 ug/l 100 86) p-Isopropyltoluene 12.07 119 307335 22.59 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 170519 22.00 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 172461 21.82 ug/l 99 89) n-Butylbenzene 12.40 91 246115 21.84 ug/l 99 90) Hexachloroethane 12.60 117 44927 21.93 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 174749 22.16 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 21832 22.56 ug/l 96 93) 1,2,4-Trichlorobenzene 13.65 180 123562 21.42 ug/l 100 94) Hexachlorobutadiene 13.79 225 67841 21.49 ug/l 99 95) Naphthalene 13.84 128 358899 22.49 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 130367 22.02 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed