Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001560.D Acq On : 09 May 2018 17:32 Operator : JC/MD Sample : VX0509WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 9 Sample Multiplier: 1 Quant Time: May 10 04:48:58 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 231719 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 299833 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 280577 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 200100 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 157564 47.31 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.62% 35) Dibromofluoromethane 5.51 113 127409 47.77 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.54% 50) Toluene-d8 8.72 98 451855 46.42 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.84% 62) 4-Bromofluorobenzene 11.15 95 167998 44.95 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.90% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 60174 19.29 ug/l 98 3) Chloromethane 1.32 50 58594 19.29 ug/l 98 4) Vinyl Chloride 1.40 62 61119 19.28 ug/l 97 5) Bromomethane 1.64 94 37288 23.90 ug/l 99 6) Chloroethane 1.72 64 41364 19.74 ug/l 99 7) Trichlorofluoromethane 1.93 101 97367 20.41 ug/l 100 8) Diethyl Ether 2.19 74 37260 19.92 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 56392 20.16 ug/l 99 10) Methyl Iodide 2.51 142 72437 17.95 ug/l 98 11) Tert butyl alcohol 3.08 59 74294 105.80 ug/l 98 12) 1,1-Dichloroethene 2.37 96 50168 19.57 ug/l 97 13) Acrolein 2.30 56 12810 84.83 ug/l 98 14) Allyl chloride 2.73 41 97083 20.31 ug/l 99 15) Acrylonitrile 3.15 53 166681 105.04 ug/l 99 16) Acetone 2.45 43 170533 112.76 ug/l 99 17) Carbon Disulfide 2.57 76 115878 17.76 ug/l 100 18) Methyl Acetate 2.78 43 89063 22.42 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 184911 20.71 ug/l 99 20) Methylene Chloride 2.86 84 60274 20.13 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 54702 19.12 ug/l 99 22) Diisopropyl ether 3.88 45 173605 19.44 ug/l 99 23) Vinyl Acetate 3.83 43 722944 97.12 ug/l 99 24) 1,1-Dichloroethane 3.70 63 103218 20.69 ug/l 100 25) 2-Butanone 4.72 43 229702 105.07 ug/l 100 26) 2,2-Dichloropropane 4.59 77 77660 20.15 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 60153 19.74 ug/l 100 28) Bromochloromethane 5.03 49 45967 21.25 ug/l 97 29) Tetrahydrofuran 5.18 42 139891 100.01 ug/l 99 30) Chloroform 5.22 83 105496 20.53 ug/l 98 31) Cyclohexane 5.57 56 81762 19.08 ug/l 90 32) 1,1,1-Trichloroethane 5.50 97 92591 20.61 ug/l 100 36) 1,1-Dichloropropene 5.80 75 73121 19.17 ug/l 99 37) Ethyl Acetate 4.87 43 84875 20.30 ug/l 100 38) Carbon Tetrachloride 5.79 117 81015 19.92 ug/l 97 39) Methylcyclohexane 7.46 83 82976 18.40 ug/l 99 40) Benzene 6.15 78 222244 19.95 ug/l 99 41) Methacrylonitrile 5.07 41 47759 19.97 ug/l 98 42) 1,2-Dichloroethane 6.21 62 88246 20.61 ug/l 99 43) Isopropyl Acetate 6.48 43 129037 20.11 ug/l 100 44) Trichloroethene 7.22 130 66717 19.59 ug/l 99 45) 1,2-Dichloropropane 7.52 63 54559 19.64 ug/l 97 46) Dibromomethane 7.67 93 39612 20.15 ug/l 98 47) Bromodichloromethane 7.91 83 73341 20.16 ug/l 100 48) Methyl methacrylate 7.79 41 69042 19.76 ug/l 99 49) 1,4-Dioxane 7.77 88 31056 411.32 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 447448 104.91 ug/l 98 52) Toluene 8.79 92 145401 19.96 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 83030 20.19 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 73443 18.76 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 59338 20.22 ug/l 97 56) Ethyl methacrylate 9.19 69 81930 19.37 ug/l 99 57) 1,3-Dichloropropane 9.38 76 97547 20.10 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 225664 108.76 ug/l 99 59) 2-Hexanone 9.51 43 341957 104.71 ug/l 99 60) Dibromochloromethane 9.59 129 58069 19.32 ug/l 97 61) 1,2-Dibromoethane 9.68 107 62038 20.13 ug/l 100 64) Tetrachloroethene 9.34 164 79982 20.45 ug/l 98 65) Chlorobenzene 10.15 112 164567 20.00 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 61179 20.79 ug/l 99 67) Ethyl Benzene 10.26 91 266541 19.76 ug/l 100 68) m/p-Xylenes 10.37 106 216567 40.64 ug/l 99 69) o-Xylene 10.71 106 103085 19.90 ug/l 98 70) Styrene 10.72 104 170024 20.21 ug/l 99 71) Bromoform 10.87 173 45770 18.58 ug/l # 100 73) Isopropylbenzene 11.02 105 280288 20.23 ug/l 100 74) N-amyl acetate 6.48 43 129037 20.51 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 85411 20.88 ug/l 97 76) 1,2,3-Trichloropropane 11.30 75 83776m 20.64 ug/l 77) Bromobenzene 11.26 156 78972 19.61 ug/l 98 78) n-propylbenzene 11.37 91 308521 20.45 ug/l 99 79) 2-Chlorotoluene 11.43 91 185861 20.02 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 232498 20.16 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 20173 18.78 ug/l 92 82) 4-Chlorotoluene 11.52 91 216841 20.25 ug/l 100 83) tert-Butylbenzene 11.77 119 230834 20.12 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 241812 20.40 ug/l 99 85) sec-Butylbenzene 11.95 105 280877 20.39 ug/l 99 86) p-Isopropyltoluene 12.07 119 257372 20.37 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 141096 19.60 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 144503 19.68 ug/l 99 89) n-Butylbenzene 12.40 91 202528 19.34 ug/l 99 90) Hexachloroethane 12.60 117 36837 19.36 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 144389 19.71 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 18746 20.85 ug/l 93 93) 1,2,4-Trichlorobenzene 13.65 180 102370 19.10 ug/l 99 94) Hexachlorobutadiene 13.79 225 55786 19.02 ug/l 99 95) Naphthalene 13.84 128 299295 20.19 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 109312 19.88 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed