Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001571.D Acq On : 09 May 2018 22:27 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 20 Sample Multiplier: 1 Quant Time: May 10 05:05:39 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 231208 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 302692 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 295685 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 212813 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 160991 48.44 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.88% 35) Dibromofluoromethane 5.51 113 132116 49.07 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.14% 50) Toluene-d8 8.72 98 468651 47.69 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.38% 62) 4-Bromofluorobenzene 11.14 95 180666 47.89 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.78% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 151675 48.73 ug/l 99 3) Chloromethane 1.32 50 138339 45.64 ug/l 99 4) Vinyl Chloride 1.40 62 149894 47.38 ug/l 100 5) Bromomethane 1.64 94 46169 30.54 ug/l 100 6) Chloroethane 1.72 64 109199 52.22 ug/l 99 7) Trichlorofluoromethane 1.92 101 244330 51.32 ug/l 99 8) Diethyl Ether 2.19 74 96077 51.49 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.38 101 141603 50.73 ug/l 99 10) Methyl Iodide 2.51 142 107915 26.79 ug/l 99 11) Tert butyl alcohol 3.09 59 185899 265.32 ug/l 99 12) 1,1-Dichloroethene 2.37 96 130164 50.88 ug/l 99 13) Acrolein 2.30 56 30502 219.41 ug/l 95 14) Allyl chloride 2.73 41 245419 51.45 ug/l 99 15) Acrylonitrile 3.15 53 419623 265.03 ug/l 100 16) Acetone 2.45 43 378370 250.74 ug/l 100 17) Carbon Disulfide 2.57 76 315800 48.50 ug/l 100 18) Methyl Acetate 2.78 43 226415 57.11 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 469603 52.72 ug/l 100 20) Methylene Chloride 2.86 84 148806 49.81 ug/l 95 21) trans-1,2-Dichloroethene 3.17 96 139469 48.85 ug/l 97 22) Diisopropyl ether 3.88 45 462525 51.90 ug/l 99 23) Vinyl Acetate 3.83 43 1933628 260.32 ug/l 100 24) 1,1-Dichloroethane 3.70 63 265521 53.33 ug/l 99 25) 2-Butanone 4.72 43 569987 261.31 ug/l 99 26) 2,2-Dichloropropane 4.59 77 163327 42.48 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 154821 50.91 ug/l 95 28) Bromochloromethane 5.03 49 115336 53.43 ug/l 97 29) Tetrahydrofuran 5.18 42 369436 264.71 ug/l 100 30) Chloroform 5.22 83 274219 53.47 ug/l 98 31) Cyclohexane 5.58 56 215196 50.33 ug/l 97 32) 1,1,1-Trichloroethane 5.50 97 242071 54.01 ug/l 100 36) 1,1-Dichloropropene 5.80 75 189960 49.34 ug/l 99 37) Ethyl Acetate 4.87 43 219539 52.01 ug/l 99 38) Carbon Tetrachloride 5.79 117 219350 53.42 ug/l 100 39) Methylcyclohexane 7.46 83 227031 49.87 ug/l 99 40) Benzene 6.15 78 582787 51.82 ug/l 99 41) Methacrylonitrile 5.07 41 126086 52.21 ug/l 99 42) 1,2-Dichloroethane 6.20 62 228706 52.91 ug/l 99 43) Isopropyl Acetate 6.48 43 347221 53.59 ug/l 100 44) Trichloroethene 7.22 130 175432 51.04 ug/l 98 45) 1,2-Dichloropropane 7.52 63 145149 51.77 ug/l 98 46) Dibromomethane 7.67 93 102823 51.80 ug/l 100 47) Bromodichloromethane 7.90 83 203108 55.29 ug/l 99 48) Methyl methacrylate 7.79 41 189066 53.59 ug/l 100 49) 1,4-Dioxane 7.77 88 79212 1039.21 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 1183730 274.93 ug/l 99 52) Toluene 8.79 92 387656 52.72 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 225288 54.27 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 203763 47.59 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 156187 52.72 ug/l 99 56) Ethyl methacrylate 9.19 69 228851 53.59 ug/l 99 57) 1,3-Dichloropropane 9.38 76 256893 52.44 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 612423 292.38 ug/l 99 59) 2-Hexanone 9.51 43 892874 270.81 ug/l 100 60) Dibromochloromethane 9.59 129 171444 56.51 ug/l 99 61) 1,2-Dibromoethane 9.68 107 165684 53.26 ug/l 99 64) Tetrachloroethene 9.34 164 212909 51.66 ug/l 99 65) Chlorobenzene 10.15 112 439870 50.72 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 166695 53.74 ug/l 99 67) Ethyl Benzene 10.26 91 731042 51.43 ug/l 99 68) m/p-Xylenes 10.37 106 584216 104.02 ug/l 99 69) o-Xylene 10.71 106 284661 52.15 ug/l 99 70) Styrene 10.72 104 471629 53.19 ug/l 100 71) Bromoform 10.87 173 140458 47.29 ug/l 100 73) Isopropylbenzene 11.02 105 760765 51.64 ug/l 100 74) N-amyl acetate 6.48 43 347221 51.89 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 227495 52.28 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 223080m 51.69 ug/l 77) Bromobenzene 11.26 156 216657 50.58 ug/l 99 78) n-propylbenzene 11.37 91 838622 52.27 ug/l 100 79) 2-Chlorotoluene 11.43 91 507554 51.41 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 640283 52.20 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 57606 43.19 ug/l 98 82) 4-Chlorotoluene 11.52 91 589611 51.77 ug/l 99 83) tert-Butylbenzene 11.77 119 637502 52.23 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 661086 52.44 ug/l 100 85) sec-Butylbenzene 11.95 105 772486 52.73 ug/l 99 86) p-Isopropyltoluene 12.07 119 708324 52.71 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 389448 50.86 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 389763 49.91 ug/l 100 89) n-Butylbenzene 12.40 91 573102 51.47 ug/l 99 90) Hexachloroethane 12.60 117 108885 53.81 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 398929 51.21 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 52996 55.44 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 291549 51.15 ug/l 100 94) Hexachlorobutadiene 13.79 225 154180 49.43 ug/l 100 95) Naphthalene 13.84 128 863486 54.77 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 302824 51.77 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed