Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001573.D Acq On : 09 May 2018 23:47 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 23 Sample Multiplier: 1 Quant Time: May 10 05:07:20 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 223522 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 290283 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 276831 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 203974 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 159578 49.67 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.34% 35) Dibromofluoromethane 5.51 113 131221 50.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 101.64% 50) Toluene-d8 8.72 98 470911 49.96 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.92% 62) 4-Bromofluorobenzene 11.14 95 180175 49.80 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.60% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 154572 51.37 ug/l 99 3) Chloromethane 1.32 50 137371 46.88 ug/l 99 4) Vinyl Chloride 1.40 62 153673 50.25 ug/l 99 5) Bromomethane 1.64 94 60286 42.55 ug/l 99 6) Chloroethane 1.72 64 110405 54.61 ug/l 99 7) Trichlorofluoromethane 1.92 101 245329 53.30 ug/l 98 8) Diethyl Ether 2.19 74 96071 53.25 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 140116 51.93 ug/l 98 10) Methyl Iodide 2.51 142 156329 40.15 ug/l 100 11) Tert butyl alcohol 3.09 59 185373 273.67 ug/l 99 12) 1,1-Dichloroethene 2.37 96 130553 52.78 ug/l 98 13) Acrolein 2.30 56 31246 233.22 ug/l 98 14) Allyl chloride 2.73 41 245364 53.20 ug/l 99 15) Acrylonitrile 3.15 53 420549 274.75 ug/l 99 16) Acetone 2.45 43 370655 254.08 ug/l 99 17) Carbon Disulfide 2.57 76 319195 50.71 ug/l 98 18) Methyl Acetate 2.78 43 227696 59.41 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 469443 54.51 ug/l 99 20) Methylene Chloride 2.86 84 152252 52.71 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 140752 50.99 ug/l 95 22) Diisopropyl ether 3.88 45 467948 54.31 ug/l 98 23) Vinyl Acetate 3.83 43 1945792 270.97 ug/l 100 24) 1,1-Dichloroethane 3.70 63 241832 50.24 ug/l 99 25) 2-Butanone 4.72 43 564495 267.69 ug/l 98 26) 2,2-Dichloropropane 4.59 77 162480 43.71 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 156537 53.25 ug/l 96 28) Bromochloromethane 5.03 49 109808 52.62 ug/l 99 29) Tetrahydrofuran 5.18 42 365229 270.70 ug/l 99 30) Chloroform 5.22 83 276468 55.76 ug/l 97 31) Cyclohexane 5.58 56 215776 52.20 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 245660 56.69 ug/l 100 36) 1,1-Dichloropropene 5.80 75 194583 52.70 ug/l 100 37) Ethyl Acetate 4.87 43 217126 53.64 ug/l 100 38) Carbon Tetrachloride 5.79 117 219608 55.76 ug/l 97 39) Methylcyclohexane 7.46 83 224174 51.35 ug/l 98 40) Benzene 6.15 78 585637 54.30 ug/l 99 41) Methacrylonitrile 5.07 41 125802 54.32 ug/l 99 42) 1,2-Dichloroethane 6.20 62 227903 54.98 ug/l 100 43) Isopropyl Acetate 6.48 43 343869 55.34 ug/l 100 44) Trichloroethene 7.22 130 177156 53.74 ug/l 97 45) 1,2-Dichloropropane 7.53 63 149825 55.72 ug/l 98 46) Dibromomethane 7.67 93 103704 54.48 ug/l 100 47) Bromodichloromethane 7.90 83 204244 57.98 ug/l 99 48) Methyl methacrylate 7.79 41 187903 55.54 ug/l 100 49) 1,4-Dioxane 7.76 88 80510 1101.39 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1181082 286.04 ug/l 100 52) Toluene 8.79 92 386005 54.74 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 225049 56.53 ug/l 96 54) cis-1,3-Dichloropropene 9.05 75 206463 50.15 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 157689 55.50 ug/l 98 56) Ethyl methacrylate 9.19 69 230163 56.20 ug/l 99 57) 1,3-Dichloropropane 9.38 76 259721 55.29 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 593604 295.51 ug/l 99 59) 2-Hexanone 9.51 43 889720 281.39 ug/l 100 60) Dibromochloromethane 9.59 129 169451 58.24 ug/l 98 61) 1,2-Dibromoethane 9.68 107 167367 56.10 ug/l 99 64) Tetrachloroethene 9.34 164 213410 55.31 ug/l 98 65) Chlorobenzene 10.14 112 441296 54.35 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 166431 57.31 ug/l 99 67) Ethyl Benzene 10.26 91 730991 54.93 ug/l 100 68) m/p-Xylenes 10.37 106 584190 111.10 ug/l 99 69) o-Xylene 10.70 106 285652 55.90 ug/l 98 70) Styrene 10.72 104 478368 57.62 ug/l 99 71) Bromoform 10.86 173 140940 50.43 ug/l # 100 73) Isopropylbenzene 11.02 105 769621 54.50 ug/l 100 74) N-amyl acetate 6.48 43 343869 53.61 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 226452 54.30 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 224900m 54.37 ug/l 77) Bromobenzene 11.26 156 218605 53.25 ug/l 100 78) n-propylbenzene 11.37 91 853155 55.48 ug/l 99 79) 2-Chlorotoluene 11.43 91 510481 53.95 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 646322 54.98 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 57739 44.97 ug/l 98 82) 4-Chlorotoluene 11.52 91 597524 54.74 ug/l 100 83) tert-Butylbenzene 11.77 119 635174 54.30 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 666436 55.15 ug/l 100 85) sec-Butylbenzene 11.95 105 777056 55.34 ug/l 100 86) p-Isopropyltoluene 12.07 119 717223 55.68 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 392657 53.51 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 397254 53.07 ug/l 100 89) n-Butylbenzene 12.40 91 578044 54.16 ug/l 100 90) Hexachloroethane 12.60 117 109811 56.62 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 403045 53.98 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 53454 58.34 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 293206 53.67 ug/l 99 94) Hexachlorobutadiene 13.79 225 157154 52.57 ug/l 99 95) Naphthalene 13.84 128 861088 56.99 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 308193 54.98 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed