Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001576.D Acq On : 10 May 2018 01:07 Operator : JC/MD Sample : VX0509MBS02 Misc : 5.0g/10mL/100ul/5mL/MSVOA_X/MEOH ALS Vial : 26 Sample Multiplier: 1 Quant Time: May 10 05:15:13 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 218424 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 292476 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 278116 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 192879 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 153939 49.03 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.06% 35) Dibromofluoromethane 5.51 113 123466 47.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.92% 50) Toluene-d8 8.72 98 437267 46.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.10% 62) 4-Bromofluorobenzene 11.14 95 162704 44.63 ug/l 0.00 Spiked Amount 50.000 Recovery = 89.26% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 63042 21.44 ug/l 98 3) Chloromethane 1.32 50 58829 20.54 ug/l 98 4) Vinyl Chloride 1.40 62 64360 21.53 ug/l 99 5) Bromomethane 1.64 94 35890 24.48 ug/l 98 6) Chloroethane 1.72 64 45228 22.89 ug/l 100 7) Trichlorofluoromethane 1.93 101 101276 22.52 ug/l 98 8) Diethyl Ether 2.19 74 39604 22.46 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 57419 21.78 ug/l 99 10) Methyl Iodide 2.51 142 60318 15.85 ug/l 99 11) Tert butyl alcohol 3.08 59 77224 116.67 ug/l 98 12) 1,1-Dichloroethene 2.37 96 53259 22.04 ug/l 96 13) Acrolein 2.30 56 12297 86.61 ug/l 96 14) Allyl chloride 2.73 41 98336 21.82 ug/l 99 15) Acrylonitrile 3.15 53 170618 114.07 ug/l 99 16) Acetone 2.45 43 153343 107.57 ug/l 100 17) Carbon Disulfide 2.57 76 123878 20.14 ug/l 97 18) Methyl Acetate 2.78 43 91871 24.53 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 192455 22.87 ug/l 100 20) Methylene Chloride 2.86 84 64560 22.87 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 57210 21.21 ug/l 96 22) Diisopropyl ether 3.88 45 183189 21.76 ug/l 99 23) Vinyl Acetate 3.83 43 747335 106.50 ug/l 100 24) 1,1-Dichloroethane 3.70 63 100450 21.36 ug/l 100 25) 2-Butanone 4.71 43 226163 109.75 ug/l 96 26) 2,2-Dichloropropane 4.59 77 59534 16.39 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 63094 21.96 ug/l 96 28) Bromochloromethane 5.03 49 48255 23.66 ug/l 97 29) Tetrahydrofuran 5.17 42 144855 109.87 ug/l 100 30) Chloroform 5.22 83 110202 22.75 ug/l 99 31) Cyclohexane 5.57 56 83959 20.78 ug/l 95 32) 1,1,1-Trichloroethane 5.50 97 96863 22.88 ug/l 99 36) 1,1-Dichloropropene 5.81 75 75654 20.34 ug/l 100 37) Ethyl Acetate 4.87 43 86524 21.22 ug/l 100 38) Carbon Tetrachloride 5.79 117 86703 21.85 ug/l 99 39) Methylcyclohexane 7.46 83 85025 19.33 ug/l 97 40) Benzene 6.15 78 232883 21.43 ug/l 99 41) Methacrylonitrile 5.07 41 49484 21.21 ug/l 99 42) 1,2-Dichloroethane 6.20 62 94043 22.52 ug/l 99 43) Isopropyl Acetate 6.48 43 132640 21.19 ug/l 100 44) Trichloroethene 7.22 130 71202 21.44 ug/l 99 45) 1,2-Dichloropropane 7.52 63 59934 22.12 ug/l 100 46) Dibromomethane 7.67 93 41710 21.75 ug/l 98 47) Bromodichloromethane 7.90 83 78145 22.02 ug/l 99 48) Methyl methacrylate 7.78 41 71697 21.03 ug/l 99 49) 1,4-Dioxane 7.76 88 31108 422.37 ug/l 95 51) 4-Methyl-2-Pentanone 8.66 43 461219 110.86 ug/l 98 52) Toluene 8.79 92 153336 21.58 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 84265 21.01 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 74562 19.43 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 62578 21.86 ug/l 97 56) Ethyl methacrylate 9.19 69 83906 20.33 ug/l 99 57) 1,3-Dichloropropane 9.38 76 102973 21.76 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 222388 109.88 ug/l 98 59) 2-Hexanone 9.51 43 341529 107.21 ug/l 99 60) Dibromochloromethane 9.59 129 62709 21.39 ug/l 100 61) 1,2-Dibromoethane 9.68 107 65191 21.69 ug/l 99 64) Tetrachloroethene 9.34 164 86617 22.34 ug/l 97 65) Chlorobenzene 10.15 112 173786 21.31 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 64671 22.17 ug/l 100 67) Ethyl Benzene 10.26 91 279466 20.90 ug/l 100 68) m/p-Xylenes 10.37 106 223913 42.39 ug/l 100 69) o-Xylene 10.71 106 109812 21.39 ug/l 100 70) Styrene 10.72 104 179748 21.55 ug/l 99 71) Bromoform 10.86 173 49277 19.88 ug/l 100 73) Isopropylbenzene 11.02 105 295448 22.13 ug/l 100 74) N-amyl acetate 6.48 43 132640 21.87 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 86970 22.05 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 86539m 22.12 ug/l 77) Bromobenzene 11.26 156 84302 21.72 ug/l 99 78) n-propylbenzene 11.37 91 319413 21.97 ug/l 99 79) 2-Chlorotoluene 11.43 91 198521 22.19 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 245235 22.06 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 18312 17.93 ug/l 87 82) 4-Chlorotoluene 11.52 91 226554 21.95 ug/l 100 83) tert-Butylbenzene 11.77 119 236514 21.38 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 254801 22.30 ug/l 99 85) sec-Butylbenzene 11.95 105 290453 21.88 ug/l 100 86) p-Isopropyltoluene 12.07 119 267521 21.96 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 148536 21.40 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 150629 21.28 ug/l 99 89) n-Butylbenzene 12.40 91 205579 20.37 ug/l 99 90) Hexachloroethane 12.60 117 38663 21.08 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 152648 21.62 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19428 22.42 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 105107 20.34 ug/l 99 94) Hexachlorobutadiene 13.79 225 57258 20.26 ug/l 99 95) Naphthalene 13.84 128 310262 21.71 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 114611 21.62 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed