Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001577.D Acq On : 10 May 2018 01:34 Operator : JC/MD Sample : VX0509MBSD02 Misc : 5.0g/10mL/100ul/5mL/MSVOA_X/MEOH ALS Vial : 27 Sample Multiplier: 1 Quant Time: May 10 05:16:40 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 214914 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 288019 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 274432 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 188632 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 150673 48.78 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.56% 35) Dibromofluoromethane 5.51 113 121660 47.49 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.98% 50) Toluene-d8 8.72 98 430214 46.01 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.02% 62) 4-Bromofluorobenzene 11.14 95 158363 44.11 ug/l 0.00 Spiked Amount 50.000 Recovery = 88.22% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 63022 21.78 ug/l 100 3) Chloromethane 1.32 50 57761 20.50 ug/l 99 4) Vinyl Chloride 1.40 62 62730 21.33 ug/l 99 5) Bromomethane 1.64 94 34405 23.75 ug/l 100 6) Chloroethane 1.72 64 42895 22.07 ug/l 99 7) Trichlorofluoromethane 1.93 101 99089 22.39 ug/l 99 8) Diethyl Ether 2.19 74 40231 23.19 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 56137 21.64 ug/l 99 10) Methyl Iodide 2.51 142 63604 16.99 ug/l 99 11) Tert butyl alcohol 3.08 59 78163 120.01 ug/l 99 12) 1,1-Dichloroethene 2.37 96 52123 21.92 ug/l 98 13) Acrolein 2.30 56 12066 86.34 ug/l 94 14) Allyl chloride 2.73 41 96242 21.70 ug/l 99 15) Acrylonitrile 3.15 53 171396 116.46 ug/l 100 16) Acetone 2.45 43 154673 110.27 ug/l 99 17) Carbon Disulfide 2.57 76 120695 19.94 ug/l 98 18) Methyl Acetate 2.78 43 94362 25.61 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 191337 23.11 ug/l 100 20) Methylene Chloride 2.86 84 63672 22.93 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 55685 20.98 ug/l 95 22) Diisopropyl ether 3.88 45 186024 22.45 ug/l 99 23) Vinyl Acetate 3.83 43 747323 108.24 ug/l 100 24) 1,1-Dichloroethane 3.70 63 100119 21.63 ug/l 99 25) 2-Butanone 4.71 43 228495 112.70 ug/l 99 26) 2,2-Dichloropropane 4.59 77 57391 16.06 ug/l 96 27) cis-1,2-Dichloroethene 4.60 96 61584 21.79 ug/l 98 28) Bromochloromethane 5.02 49 49102 24.47 ug/l 96 29) Tetrahydrofuran 5.18 42 144353 111.27 ug/l 100 30) Chloroform 5.22 83 109343 22.94 ug/l 99 31) Cyclohexane 5.57 56 83545 21.02 ug/l 95 32) 1,1,1-Trichloroethane 5.50 97 94899 22.78 ug/l 99 36) 1,1-Dichloropropene 5.81 75 74068 20.22 ug/l 98 37) Ethyl Acetate 4.87 43 87612 21.82 ug/l 99 38) Carbon Tetrachloride 5.79 117 84923 21.73 ug/l 97 39) Methylcyclohexane 7.46 83 83715 19.33 ug/l 98 40) Benzene 6.15 78 232486 21.73 ug/l 97 41) Methacrylonitrile 5.07 41 49487 21.54 ug/l 99 42) 1,2-Dichloroethane 6.21 62 93525 22.74 ug/l 99 43) Isopropyl Acetate 6.48 43 133541 21.66 ug/l 100 44) Trichloroethene 7.22 130 70923 21.68 ug/l 98 45) 1,2-Dichloropropane 7.52 63 59247 22.21 ug/l 100 46) Dibromomethane 7.67 93 41665 22.06 ug/l 99 47) Bromodichloromethane 7.91 83 76624 21.92 ug/l 98 48) Methyl methacrylate 7.79 41 71218 21.21 ug/l 100 49) 1,4-Dioxane 7.76 88 31649 436.37 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 462784 112.96 ug/l 99 52) Toluene 8.79 92 152130 21.74 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 82221 20.81 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 74208 19.61 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 62690 22.24 ug/l 97 56) Ethyl methacrylate 9.19 69 86007 21.17 ug/l 100 57) 1,3-Dichloropropane 9.38 76 101806 21.84 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 221377 111.07 ug/l 100 59) 2-Hexanone 9.51 43 344006 109.65 ug/l 99 60) Dibromochloromethane 9.59 129 62796 21.75 ug/l 99 61) 1,2-Dibromoethane 9.68 107 65249 22.04 ug/l 100 64) Tetrachloroethene 9.34 164 85296 22.30 ug/l 99 65) Chlorobenzene 10.15 112 170313 21.16 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 63539 22.07 ug/l 100 67) Ethyl Benzene 10.26 91 277078 21.00 ug/l 98 68) m/p-Xylenes 10.37 106 222185 42.63 ug/l 99 69) o-Xylene 10.71 106 108375 21.39 ug/l 100 70) Styrene 10.72 104 176114 21.40 ug/l 99 71) Bromoform 10.87 173 49259 20.09 ug/l 100 73) Isopropylbenzene 11.02 105 289028 22.13 ug/l 100 74) N-amyl acetate 6.48 43 133541 22.51 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 86350 22.39 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 85144m 22.26 ug/l 77) Bromobenzene 11.26 156 82513 21.73 ug/l 99 78) n-propylbenzene 11.37 91 314643 22.13 ug/l 99 79) 2-Chlorotoluene 11.43 91 194550 22.23 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 239311 22.01 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 18907 18.69 ug/l 92 82) 4-Chlorotoluene 11.52 91 221934 21.98 ug/l 98 83) tert-Butylbenzene 11.77 119 237778 21.98 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 248785 22.26 ug/l 100 85) sec-Butylbenzene 11.95 105 287372 22.13 ug/l 99 86) p-Isopropyltoluene 12.07 119 259740 21.81 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 146066 21.52 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 146705 21.19 ug/l 98 89) n-Butylbenzene 12.40 91 199862 20.25 ug/l 99 90) Hexachloroethane 12.60 117 37781 21.06 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 152722 22.12 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19522 23.04 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 103952 20.57 ug/l 100 94) Hexachlorobutadiene 13.79 225 57135 20.67 ug/l 98 95) Naphthalene 13.84 128 310855 22.25 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 112895 21.78 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed