Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001587.D Acq On : 10 May 2018 06:00 Operator : JC/MD Sample : VX0509WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 37 Sample Multiplier: 1 Quant Time: May 10 08:35:44 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 236307 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 316605 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 296421 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 205801 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 169210 49.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 99.64% 35) Dibromofluoromethane 5.51 113 134432 47.74 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.48% 50) Toluene-d8 8.72 98 482801 46.97 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.94% 62) 4-Bromofluorobenzene 11.14 95 177766 45.05 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.10% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 65926 20.72 ug/l 100 3) Chloromethane 1.32 50 63032 20.35 ug/l 98 4) Vinyl Chloride 1.40 62 67602 20.91 ug/l 97 5) Bromomethane 1.64 94 36090 22.49 ug/l 97 6) Chloroethane 1.72 64 44298 20.73 ug/l 98 7) Trichlorofluoromethane 1.93 101 102140 20.99 ug/l 98 8) Diethyl Ether 2.19 74 40901 21.44 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 59405 20.82 ug/l 99 10) Methyl Iodide 2.51 142 66069 16.05 ug/l 99 11) Tert butyl alcohol 3.08 59 79376 110.84 ug/l 98 12) 1,1-Dichloroethene 2.37 96 54055 20.67 ug/l 98 13) Acrolein 2.30 56 10874 68.56 ug/l 99 14) Allyl chloride 2.73 41 96486 19.79 ug/l 98 15) Acrylonitrile 3.15 53 176633 109.15 ug/l 99 16) Acetone 2.45 43 161365 104.63 ug/l 99 17) Carbon Disulfide 2.57 76 114232 17.17 ug/l 99 18) Methyl Acetate 2.78 43 98130 24.22 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 197954 21.74 ug/l 99 20) Methylene Chloride 2.86 84 64614 21.16 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 58492 20.04 ug/l 95 22) Diisopropyl ether 3.88 45 195206 21.43 ug/l 99 23) Vinyl Acetate 3.83 43 770708 101.52 ug/l 99 24) 1,1-Dichloroethane 3.70 63 106027 20.84 ug/l 99 25) 2-Butanone 4.71 43 240257 107.77 ug/l 98 26) 2,2-Dichloropropane 4.59 77 48333 12.30 ug/l 97 27) cis-1,2-Dichloroethene 4.60 96 65292 21.01 ug/l 95 28) Bromochloromethane 5.03 49 51114 23.17 ug/l 98 29) Tetrahydrofuran 5.17 42 155207 108.81 ug/l 99 30) Chloroform 5.22 83 113704 21.69 ug/l 97 31) Cyclohexane 5.58 56 90315 20.67 ug/l 93 32) 1,1,1-Trichloroethane 5.50 97 98788 21.56 ug/l 99 36) 1,1-Dichloropropene 5.81 75 78288 19.44 ug/l 99 37) Ethyl Acetate 4.87 43 91287 20.68 ug/l 100 38) Carbon Tetrachloride 5.79 117 85791 19.97 ug/l 98 39) Methylcyclohexane 7.46 83 90422 18.99 ug/l 98 40) Benzene 6.15 78 248251 21.10 ug/l 99 41) Methacrylonitrile 5.07 41 52646 20.84 ug/l 99 42) 1,2-Dichloroethane 6.20 62 97673 21.60 ug/l 99 43) Isopropyl Acetate 6.48 43 138587 20.45 ug/l 99 44) Trichloroethene 7.22 130 74199 20.64 ug/l 100 45) 1,2-Dichloropropane 7.52 63 61714 21.04 ug/l 99 46) Dibromomethane 7.67 93 42744 20.59 ug/l 99 47) Bromodichloromethane 7.90 83 75873 19.75 ug/l 98 48) Methyl methacrylate 7.79 41 75462 20.45 ug/l 100 49) 1,4-Dioxane 7.76 88 33318 417.90 ug/l 96 51) 4-Methyl-2-Pentanone 8.66 43 488826 108.54 ug/l 99 52) Toluene 8.79 92 159043 20.68 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 82560 19.01 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 70771 17.31 ug/l 97 55) 1,1,2-Trichloroethane 9.22 97 64958 20.96 ug/l 98 56) Ethyl methacrylate 9.19 69 88963 19.92 ug/l 98 57) 1,3-Dichloropropane 9.38 76 108040 21.09 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 236437 107.92 ug/l 100 59) 2-Hexanone 9.51 43 358066 103.83 ug/l 100 60) Dibromochloromethane 9.59 129 60000 18.91 ug/l 98 61) 1,2-Dibromoethane 9.68 107 67043 20.61 ug/l 99 64) Tetrachloroethene 9.34 164 90670 21.95 ug/l 97 65) Chlorobenzene 10.14 112 180141 20.72 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 63353 20.37 ug/l 98 67) Ethyl Benzene 10.26 91 291744 20.48 ug/l 99 68) m/p-Xylenes 10.37 106 232429 41.28 ug/l 99 69) o-Xylene 10.70 106 114210 20.87 ug/l 99 70) Styrene 10.72 104 184038 20.70 ug/l 99 71) Bromoform 10.87 173 46147 17.90 ug/l # 99 73) Isopropylbenzene 11.02 105 307060 21.55 ug/l 100 74) N-amyl acetate 6.48 43 138587 21.42 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 91595 21.77 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 88335m 21.16 ug/l 77) Bromobenzene 11.26 156 88553 21.38 ug/l 99 78) n-propylbenzene 11.37 91 335261 21.61 ug/l 98 79) 2-Chlorotoluene 11.43 91 205625 21.54 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 254773 21.48 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 17006 16.16 ug/l 87 82) 4-Chlorotoluene 11.52 91 234124 21.26 ug/l 100 83) tert-Butylbenzene 11.77 119 248450 21.05 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 263591 21.62 ug/l 100 85) sec-Butylbenzene 11.95 105 303999 21.46 ug/l 99 86) p-Isopropyltoluene 12.07 119 273269 21.03 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 153323 20.71 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 156241 20.69 ug/l 99 89) n-Butylbenzene 12.40 91 211015 19.60 ug/l 100 90) Hexachloroethane 12.60 117 38361 19.60 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 159776 21.21 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19190 20.76 ug/l 95 93) 1,2,4-Trichlorobenzene 13.65 180 110330 20.01 ug/l 100 94) Hexachlorobutadiene 13.79 225 59534 19.74 ug/l 99 95) Naphthalene 13.84 128 330848 21.70 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 119086 21.05 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed