Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX050918\ Data File : VX001588.D Acq On : 10 May 2018 06:27 Operator : JC/MD Sample : VX0509WBSD02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 38 Sample Multiplier: 1 Quant Time: May 10 08:37:16 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 229024 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 304311 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 288960 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 199148 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 164727 50.04 ug/l 0.00 Spiked Amount 50.000 Recovery = 100.08% 35) Dibromofluoromethane 5.51 113 132596 48.99 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.98% 50) Toluene-d8 8.72 98 468889 47.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.92% 62) 4-Bromofluorobenzene 11.14 95 175847 46.36 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.72% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 62971 20.43 ug/l 99 3) Chloromethane 1.32 50 60721 20.22 ug/l 99 4) Vinyl Chloride 1.40 62 64412 20.55 ug/l 98 5) Bromomethane 1.64 94 35539 22.91 ug/l 96 6) Chloroethane 1.73 64 42375 20.46 ug/l 96 7) Trichlorofluoromethane 1.93 101 98769 20.94 ug/l 100 8) Diethyl Ether 2.19 74 40329 21.82 ug/l 96 9) 1,1,2-Trichlorotrifluoroet 2.39 101 57134 20.66 ug/l 100 10) Methyl Iodide 2.51 142 68386 17.14 ug/l 99 11) Tert butyl alcohol 3.08 59 82965 119.54 ug/l 99 12) 1,1-Dichloroethene 2.37 96 53955 21.29 ug/l 99 13) Acrolein 2.30 56 11233 73.88 ug/l 98 14) Allyl chloride 2.73 41 94882 20.08 ug/l 98 15) Acrylonitrile 3.15 53 177919 113.45 ug/l 100 16) Acetone 2.45 43 161201 107.85 ug/l 99 17) Carbon Disulfide 2.57 76 114104 17.69 ug/l 99 18) Methyl Acetate 2.78 43 97628 24.86 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 195952 22.21 ug/l 100 20) Methylene Chloride 2.86 84 62831 21.23 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 55680 19.69 ug/l 98 22) Diisopropyl ether 3.88 45 191978 21.75 ug/l 99 23) Vinyl Acetate 3.83 43 770843 104.77 ug/l 98 24) 1,1-Dichloroethane 3.70 63 103060 20.90 ug/l 99 25) 2-Butanone 4.71 43 239231 110.72 ug/l 98 26) 2,2-Dichloropropane 4.59 77 47080 12.36 ug/l 94 27) cis-1,2-Dichloroethene 4.60 96 63936 21.23 ug/l 94 28) Bromochloromethane 5.02 49 50353 23.55 ug/l 95 29) Tetrahydrofuran 5.18 42 151928 109.90 ug/l 99 30) Chloroform 5.22 83 112755 22.20 ug/l 99 31) Cyclohexane 5.58 56 86733 20.48 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 96351 21.70 ug/l 99 36) 1,1-Dichloropropene 5.81 75 76285 19.71 ug/l 99 37) Ethyl Acetate 4.87 43 91501 21.56 ug/l 100 38) Carbon Tetrachloride 5.79 117 83919 20.33 ug/l 96 39) Methylcyclohexane 7.46 83 86683 18.94 ug/l 96 40) Benzene 6.15 78 240480 21.27 ug/l 100 41) Methacrylonitrile 5.07 41 51930 21.39 ug/l 99 42) 1,2-Dichloroethane 6.20 62 95183 21.90 ug/l 100 43) Isopropyl Acetate 6.48 43 138529 21.27 ug/l 100 44) Trichloroethene 7.22 130 71139 20.59 ug/l 96 45) 1,2-Dichloropropane 7.52 63 60177 21.35 ug/l 98 46) Dibromomethane 7.67 93 42527 21.31 ug/l 99 47) Bromodichloromethane 7.90 83 76587 20.74 ug/l 99 48) Methyl methacrylate 7.79 41 74177 20.91 ug/l 99 49) 1,4-Dioxane 7.76 88 33698 439.74 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 484099 111.84 ug/l 98 52) Toluene 8.79 92 157029 21.24 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 80832 19.37 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 71421 18.07 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 64260 21.58 ug/l 98 56) Ethyl methacrylate 9.19 69 89252 20.79 ug/l 100 57) 1,3-Dichloropropane 9.38 76 106286 21.58 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 236588 112.35 ug/l 99 59) 2-Hexanone 9.50 43 358507 108.16 ug/l 99 60) Dibromochloromethane 9.59 129 61072 20.02 ug/l 99 61) 1,2-Dibromoethane 9.68 107 66956 21.41 ug/l 100 64) Tetrachloroethene 9.34 164 87306 21.68 ug/l 99 65) Chlorobenzene 10.14 112 175700 20.73 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 63832 21.06 ug/l 99 67) Ethyl Benzene 10.26 91 283537 20.41 ug/l 100 68) m/p-Xylenes 10.37 106 225658 41.12 ug/l 99 69) o-Xylene 10.70 106 110115 20.64 ug/l 97 70) Styrene 10.72 104 179923 20.76 ug/l 100 71) Bromoform 10.86 173 46838 18.49 ug/l 99 73) Isopropylbenzene 11.02 105 296241 21.49 ug/l 99 74) N-amyl acetate 6.48 43 138529 22.12 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 90171 22.14 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 87417m 21.64 ug/l 77) Bromobenzene 11.26 156 84094 20.98 ug/l 97 78) n-propylbenzene 11.37 91 321376 21.41 ug/l 99 79) 2-Chlorotoluene 11.43 91 200777 21.73 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 247975 21.60 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 16827 16.43 ug/l 86 82) 4-Chlorotoluene 11.52 91 230793 21.66 ug/l 99 83) tert-Butylbenzene 11.77 119 238718 20.90 ug/l 96 84) 1,2,4-Trimethylbenzene 11.81 105 254626 21.58 ug/l 99 85) sec-Butylbenzene 11.95 105 293917 21.44 ug/l 99 86) p-Isopropyltoluene 12.07 119 265881 21.14 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 150609 21.02 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 151698 20.76 ug/l 99 89) n-Butylbenzene 12.40 91 203949 19.57 ug/l 99 90) Hexachloroethane 12.60 117 37985 20.06 ug/l 97 91) 1,2-Dichlorobenzene 12.40 146 156043 21.41 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19317 21.59 ug/l 98 93) 1,2,4-Trichlorobenzene 13.65 180 107295 20.11 ug/l 98 94) Hexachlorobutadiene 13.79 225 56869 19.48 ug/l 100 95) Naphthalene 13.84 128 323247 21.91 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 114901 20.99 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed