Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051018\ Data File : VX001597.D Acq On : 10 May 2018 11:16 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 11 06:53:24 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 284871 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 353846 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 338739 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 251135 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 184826 45.14 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.28% 35) Dibromofluoromethane 5.51 113 151847 48.25 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.50% 50) Toluene-d8 8.72 98 557324 48.51 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.02% 62) 4-Bromofluorobenzene 11.14 95 215198 48.80 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.60% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 175995 45.89 ug/l 100 3) Chloromethane 1.32 50 159858 42.80 ug/l 100 4) Vinyl Chloride 1.40 62 168812 43.31 ug/l 98 5) Bromomethane 1.64 94 71951 39.62 ug/l 100 6) Chloroethane 1.72 64 111024 43.09 ug/l 98 7) Trichlorofluoromethane 1.93 101 271423 46.27 ug/l 99 8) Diethyl Ether 2.19 74 101348 44.08 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 162655 47.30 ug/l 99 10) Methyl Iodide 2.51 142 192375 38.77 ug/l 100 11) Tert butyl alcohol 3.07 59 178178 206.40 ug/l 100 12) 1,1-Dichloroethene 2.37 96 138900 44.06 ug/l 96 13) Acrolein 2.29 56 25692 146.12 ug/l 97 14) Allyl chloride 2.73 41 262733 44.70 ug/l 98 15) Acrylonitrile 3.15 53 414233 212.34 ug/l 99 16) Acetone 2.45 43 408496 219.71 ug/l 100 17) Carbon Disulfide 2.57 76 333558 41.58 ug/l 99 18) Methyl Acetate 2.78 43 227608 46.60 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 493305 44.95 ug/l 98 20) Methylene Chloride 2.86 84 156351 42.47 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 148059 42.09 ug/l 95 22) Diisopropyl ether 3.87 45 515973 46.99 ug/l 99 23) Vinyl Acetate 3.82 43 2164755 236.54 ug/l 100 24) 1,1-Dichloroethane 3.70 63 279803 45.61 ug/l 100 25) 2-Butanone 4.71 43 598405 222.66 ug/l 96 26) 2,2-Dichloropropane 4.59 77 236202 49.86 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 169240 45.17 ug/l 98 28) Bromochloromethane 5.03 49 137079 51.54 ug/l 97 29) Tetrahydrofuran 5.17 42 372614 216.69 ug/l 100 30) Chloroform 5.21 83 298408 47.23 ug/l 99 31) Cyclohexane 5.57 56 247876 47.05 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 267249 48.39 ug/l 99 36) 1,1-Dichloropropene 5.80 75 218623 48.57 ug/l 99 37) Ethyl Acetate 4.87 43 225954 45.80 ug/l 99 38) Carbon Tetrachloride 5.79 117 240654 50.13 ug/l 97 39) Methylcyclohexane 7.46 83 271112 50.95 ug/l 99 40) Benzene 6.15 78 639370 48.63 ug/l 98 41) Methacrylonitrile 5.06 41 130912 46.37 ug/l 99 42) 1,2-Dichloroethane 6.20 62 244775 48.44 ug/l 100 43) Isopropyl Acetate 6.47 43 364660 48.14 ug/l 100 44) Trichloroethene 7.21 130 197024 49.03 ug/l 99 45) 1,2-Dichloropropane 7.52 63 161562 49.29 ug/l 100 46) Dibromomethane 7.67 93 111557 48.08 ug/l 99 47) Bromodichloromethane 7.90 83 218811 50.96 ug/l 100 48) Methyl methacrylate 7.78 41 196778 47.71 ug/l 100 49) 1,4-Dioxane 7.76 88 78069 876.15 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1224777 243.34 ug/l 100 52) Toluene 8.79 92 430398 50.07 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 256851 52.93 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 235754 47.12 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 166429 48.06 ug/l 99 56) Ethyl methacrylate 9.18 69 249124 49.90 ug/l 99 57) 1,3-Dichloropropane 9.38 76 276470 48.28 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 606738 247.79 ug/l 100 59) 2-Hexanone 9.50 43 928914 241.02 ug/l 100 60) Dibromochloromethane 9.59 129 182506 51.46 ug/l 100 61) 1,2-Dibromoethane 9.68 107 176931 48.66 ug/l 99 64) Tetrachloroethene 9.34 164 236439 50.08 ug/l 99 65) Chlorobenzene 10.14 112 484719 48.79 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 179247 50.44 ug/l 99 67) Ethyl Benzene 10.26 91 814714 50.03 ug/l 99 68) m/p-Xylenes 10.37 106 654502 101.73 ug/l 100 69) o-Xylene 10.70 106 317783 50.82 ug/l 100 70) Styrene 10.72 104 523304 51.52 ug/l 99 71) Bromoform 10.87 173 147515 43.65 ug/l # 100 73) Isopropylbenzene 11.02 105 863256 49.65 ug/l 100 74) N-amyl acetate 6.47 43 364660 46.18 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 240039 46.75 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 239173m 46.96 ug/l 77) Bromobenzene 11.26 156 239466 47.38 ug/l 99 78) n-propylbenzene 11.37 91 979350 51.73 ug/l 99 79) 2-Chlorotoluene 11.43 91 571664 49.07 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 726340 50.18 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 68649 43.58 ug/l 98 82) 4-Chlorotoluene 11.52 91 672804 50.06 ug/l 100 83) tert-Butylbenzene 11.77 119 712685 49.48 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 755734 50.80 ug/l 99 85) sec-Butylbenzene 11.95 105 897658 51.93 ug/l 100 86) p-Isopropyltoluene 12.07 119 828694 52.26 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 442404 48.96 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 449835 48.81 ug/l 100 89) n-Butylbenzene 12.40 91 696767 53.03 ug/l 100 90) Hexachloroethane 12.60 117 124951 52.33 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 442965 48.19 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54956 48.71 ug/l 100 93) 1,2,4-Trichlorobenzene 13.65 180 344497 51.21 ug/l 99 94) Hexachlorobutadiene 13.79 225 192290 52.24 ug/l 99 95) Naphthalene 13.84 128 937451 50.39 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 349377 50.62 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed