Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051018\ Data File : VX001600.D Acq On : 10 May 2018 14:14 Operator : JC/MD Sample : VX0510WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 5 Sample Multiplier: 1 Quant Time: May 11 07:00:29 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 281129 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 351578 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 335636 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 243780 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 216832 53.66 ug/l 0.00 Spiked Amount 50.000 Recovery = 107.32% 35) Dibromofluoromethane 5.51 113 174555 55.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 111.64% 50) Toluene-d8 8.72 98 635607 55.68 ug/l 0.00 Spiked Amount 50.000 Recovery = 111.36% 62) 4-Bromofluorobenzene 11.14 95 240400 54.86 ug/l 0.00 Spiked Amount 50.000 Recovery = 109.72% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 82594 21.82 ug/l 100 3) Chloromethane 1.32 50 74372 20.18 ug/l 99 4) Vinyl Chloride 1.40 62 80083 20.82 ug/l 98 5) Bromomethane 1.64 94 44100 23.20 ug/l 98 6) Chloroethane 1.72 64 51580 20.29 ug/l 99 7) Trichlorofluoromethane 1.93 101 126808 21.90 ug/l 99 8) Diethyl Ether 2.19 74 47514 20.94 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 76799 22.63 ug/l 100 10) Methyl Iodide 2.51 142 81397 16.62 ug/l 98 11) Tert butyl alcohol 3.07 59 90161 105.83 ug/l 99 12) 1,1-Dichloroethene 2.37 96 65567 21.08 ug/l 96 13) Acrolein 2.29 56 12144 63.61 ug/l 93 14) Allyl chloride 2.73 41 124154 21.40 ug/l 99 15) Acrylonitrile 3.15 53 202344 105.11 ug/l 99 16) Acetone 2.45 43 208308 113.53 ug/l 98 17) Carbon Disulfide 2.57 76 147614 18.65 ug/l 99 18) Methyl Acetate 2.78 43 110830 22.99 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 231163 21.34 ug/l 100 20) Methylene Chloride 2.86 84 73962 20.36 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 69932 20.14 ug/l 93 22) Diisopropyl ether 3.87 45 239368 22.09 ug/l 97 23) Vinyl Acetate 3.82 43 1001700 110.91 ug/l 100 24) 1,1-Dichloroethane 3.70 63 131821 21.78 ug/l 100 25) 2-Butanone 4.71 43 288861 108.91 ug/l 99 26) 2,2-Dichloropropane 4.59 77 105499 22.57 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 78745 21.30 ug/l 99 28) Bromochloromethane 5.03 49 60175 22.93 ug/l 99 29) Tetrahydrofuran 5.17 42 177776 104.76 ug/l 100 30) Chloroform 5.22 83 137993 22.13 ug/l 100 31) Cyclohexane 5.57 56 111180 21.38 ug/l 93 32) 1,1,1-Trichloroethane 5.50 97 121277 22.25 ug/l 99 36) 1,1-Dichloropropene 5.80 75 96753 21.63 ug/l 99 37) Ethyl Acetate 4.87 43 106105 21.64 ug/l 100 38) Carbon Tetrachloride 5.79 117 109151 22.88 ug/l 99 39) Methylcyclohexane 7.46 83 120541 22.80 ug/l 97 40) Benzene 6.15 78 295783 22.64 ug/l 98 41) Methacrylonitrile 5.06 41 61411 21.89 ug/l 99 42) 1,2-Dichloroethane 6.20 62 114829 22.87 ug/l 100 43) Isopropyl Acetate 6.47 43 165845 22.04 ug/l 99 44) Trichloroethene 7.21 130 90800 22.74 ug/l 99 45) 1,2-Dichloropropane 7.52 63 75301 23.12 ug/l 99 46) Dibromomethane 7.67 93 51675 22.41 ug/l 99 47) Bromodichloromethane 7.90 83 96270 22.56 ug/l 99 48) Methyl methacrylate 7.78 41 90231 22.02 ug/l 100 49) 1,4-Dioxane 7.76 88 38508 434.95 ug/l 98 51) 4-Methyl-2-Pentanone 8.65 43 569987 113.98 ug/l 99 52) Toluene 8.79 92 195414 22.88 ug/l 98 53) t-1,3-Dichloropropene 8.44 75 110434 22.90 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 98250 21.08 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 78900 22.93 ug/l 95 56) Ethyl methacrylate 9.19 69 109133 22.00 ug/l 100 57) 1,3-Dichloropropane 9.38 76 128596 22.60 ug/l 99 58) 2-Chloroethyl Vinyl ether 8.32 63 240865 99.00 ug/l 99 59) 2-Hexanone 9.50 43 434532 113.47 ug/l 99 60) Dibromochloromethane 9.59 129 79326 22.51 ug/l 98 61) 1,2-Dibromoethane 9.68 107 81975 22.69 ug/l 100 64) Tetrachloroethene 9.34 164 107969 23.08 ug/l 97 65) Chlorobenzene 10.14 112 222100 22.56 ug/l 98 66) 1,1,1,2-Tetrachloroethane 10.23 131 82040 23.30 ug/l 99 67) Ethyl Benzene 10.26 91 366632 22.72 ug/l 99 68) m/p-Xylenes 10.37 106 293710 46.07 ug/l 100 69) o-Xylene 10.70 106 140220 22.63 ug/l 97 70) Styrene 10.72 104 232051 23.05 ug/l 100 71) Bromoform 10.86 173 62012 20.57 ug/l 100 73) Isopropylbenzene 11.02 105 386851 22.92 ug/l 100 74) N-amyl acetate 6.47 43 165845 21.64 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 109747 22.02 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 110204m 22.29 ug/l 77) Bromobenzene 11.26 156 106785 21.76 ug/l 99 78) n-propylbenzene 11.37 91 437692 23.82 ug/l 99 79) 2-Chlorotoluene 11.43 91 256997 22.72 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 325072 23.14 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 27824 20.69 ug/l 93 82) 4-Chlorotoluene 11.52 91 302787 23.21 ug/l 99 83) tert-Butylbenzene 11.77 119 314524 22.50 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 336482 23.30 ug/l 100 85) sec-Butylbenzene 11.95 105 399836 23.83 ug/l 99 86) p-Isopropyltoluene 12.07 119 365703 23.76 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 197708 22.54 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 199344 22.28 ug/l 99 89) n-Butylbenzene 12.40 91 298785 23.42 ug/l 99 90) Hexachloroethane 12.60 117 52548 22.67 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 199723 22.38 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 24719 22.57 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 148073 22.68 ug/l 100 94) Hexachlorobutadiene 13.79 225 84328 23.60 ug/l 100 95) Naphthalene 13.84 128 410273 22.72 ug/l 99 96) 1,2,3-Trichlorobenzene 14.02 180 153119 22.85 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed