Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051018\ Data File : VX001601.D Acq On : 10 May 2018 14:49 Operator : JC/MD Sample : VX0510MBS01 Misc : 5.0g/10mL/100uL/5mL/MSVOA_X/MEOH ALS Vial : 6 Sample Multiplier: 1 Quant Time: May 11 07:02:24 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 233674 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 295374 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 280438 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 199131 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 158398 47.16 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.32% 35) Dibromofluoromethane 5.51 113 126933 48.31 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.62% 50) Toluene-d8 8.72 98 444781 46.38 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.76% 62) 4-Bromofluorobenzene 11.14 95 168376 45.74 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.48% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 63979 20.34 ug/l 100 3) Chloromethane 1.32 50 58406 19.06 ug/l 98 4) Vinyl Chloride 1.40 62 62640 19.59 ug/l 100 5) Bromomethane 1.64 94 33926 21.20 ug/l 99 6) Chloroethane 1.72 64 41006 19.40 ug/l 97 7) Trichlorofluoromethane 1.93 101 98546 20.48 ug/l 97 8) Diethyl Ether 2.19 74 39744 21.07 ug/l 97 9) 1,1,2-Trichlorotrifluoroet 2.39 101 59054 20.93 ug/l 99 10) Methyl Iodide 2.51 142 68727 16.88 ug/l 99 11) Tert butyl alcohol 3.07 59 80702 113.97 ug/l 100 12) 1,1-Dichloroethene 2.37 96 51496 19.92 ug/l 99 13) Acrolein 2.30 56 12085 78.57 ug/l 90 14) Allyl chloride 2.73 41 98765 20.49 ug/l 98 15) Acrylonitrile 3.15 53 171365 107.09 ug/l 99 16) Acetone 2.45 43 167351 109.73 ug/l 98 17) Carbon Disulfide 2.57 76 116089 17.64 ug/l 99 18) Methyl Acetate 2.78 43 95132 23.74 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 194630 21.62 ug/l 99 20) Methylene Chloride 2.86 84 60818 20.14 ug/l 95 21) trans-1,2-Dichloroethene 3.17 96 54678 18.95 ug/l 96 22) Diisopropyl ether 3.87 45 185356 20.58 ug/l 96 23) Vinyl Acetate 3.83 43 819883 109.22 ug/l 100 24) 1,1-Dichloroethane 3.70 63 106141 21.09 ug/l 100 25) 2-Butanone 4.71 43 240388 109.04 ug/l 99 26) 2,2-Dichloropropane 4.59 77 81491 20.97 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 63019 20.51 ug/l 99 28) Bromochloromethane 5.03 49 47346 21.70 ug/l 95 29) Tetrahydrofuran 5.17 42 146768 104.05 ug/l 99 30) Chloroform 5.22 83 112022 21.61 ug/l 100 31) Cyclohexane 5.57 56 85396 19.76 ug/l 96 32) 1,1,1-Trichloroethane 5.49 97 94989 20.97 ug/l 99 36) 1,1-Dichloropropene 5.80 75 75960 20.22 ug/l 99 37) Ethyl Acetate 4.87 43 89500 21.73 ug/l 100 38) Carbon Tetrachloride 5.79 117 84882 21.18 ug/l 97 39) Methylcyclohexane 7.46 83 90769 20.43 ug/l 97 40) Benzene 6.15 78 232128 21.15 ug/l 100 41) Methacrylonitrile 5.07 41 50943 21.62 ug/l 99 42) 1,2-Dichloroethane 6.20 62 95593 22.66 ug/l 100 43) Isopropyl Acetate 6.47 43 138644 21.93 ug/l 99 44) Trichloroethene 7.22 130 71111 21.20 ug/l 99 45) 1,2-Dichloropropane 7.52 63 60144 21.98 ug/l 98 46) Dibromomethane 7.67 93 42627 22.01 ug/l 99 47) Bromodichloromethane 7.90 83 77983 21.76 ug/l 97 48) Methyl methacrylate 7.78 41 74477 21.63 ug/l 99 49) 1,4-Dioxane 7.76 88 32848 441.62 ug/l 96 51) 4-Methyl-2-Pentanone 8.65 43 472623 112.49 ug/l 99 52) Toluene 8.79 92 154582 21.54 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 88696 21.89 ug/l 96 54) cis-1,3-Dichloropropene 9.05 75 80858 20.69 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 64294 22.24 ug/l 96 56) Ethyl methacrylate 9.19 69 87783 21.06 ug/l 99 57) 1,3-Dichloropropane 9.38 76 105354 22.04 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 239607 117.23 ug/l 99 59) 2-Hexanone 9.50 43 353659 109.92 ug/l 99 60) Dibromochloromethane 9.59 129 64584 21.81 ug/l 100 61) 1,2-Dibromoethane 9.68 107 65449 21.56 ug/l 98 64) Tetrachloroethene 9.34 164 82879 21.20 ug/l 99 65) Chlorobenzene 10.14 112 174080 21.17 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 65088 22.12 ug/l 99 67) Ethyl Benzene 10.26 91 280823 20.83 ug/l 99 68) m/p-Xylenes 10.37 106 226437 42.51 ug/l 100 69) o-Xylene 10.70 106 110162 21.28 ug/l 100 70) Styrene 10.72 104 179578 21.35 ug/l 99 71) Bromoform 10.86 173 49119 19.69 ug/l # 99 73) Isopropylbenzene 11.02 105 295896 21.46 ug/l 100 74) N-amyl acetate 6.47 43 138644 22.14 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 89776 22.05 ug/l 98 76) 1,2,3-Trichloropropane 11.30 75 91765m 22.72 ug/l 77) Bromobenzene 11.26 156 84276 21.03 ug/l 99 78) n-propylbenzene 11.37 91 329438 21.95 ug/l 99 79) 2-Chlorotoluene 11.43 91 196958 21.32 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 249694 21.76 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 21979 20.15 ug/l 89 82) 4-Chlorotoluene 11.52 91 232451 21.81 ug/l 99 83) tert-Butylbenzene 11.77 119 240086 21.02 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 257771 21.85 ug/l 100 85) sec-Butylbenzene 11.95 105 301134 21.97 ug/l 99 86) p-Isopropyltoluene 12.07 119 278299 22.13 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 152405 21.27 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 154543 21.15 ug/l 99 89) n-Butylbenzene 12.40 91 220382 21.15 ug/l 99 90) Hexachloroethane 12.60 117 39917 21.08 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 155454 21.33 ug/l 99 92) 1,2-Dibromo-3-Chloropropan 13.01 75 19943 22.29 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 113901 21.35 ug/l 100 94) Hexachlorobutadiene 13.79 225 62664 21.47 ug/l 100 95) Naphthalene 13.84 128 323900 21.96 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 118312 21.62 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed