Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051018\ Data File : VX001605.D Acq On : 10 May 2018 16:47 Operator : JC/MD Sample : VX0510WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 10 Sample Multiplier: 1 Quant Time: May 11 07:41:45 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 234253 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 301013 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 280168 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 200610 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 161399 47.94 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.88% 35) Dibromofluoromethane 5.51 113 130711 48.82 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.64% 50) Toluene-d8 8.72 98 460542 47.12 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.24% 62) 4-Bromofluorobenzene 11.14 95 172130 45.88 ug/l 0.00 Spiked Amount 50.000 Recovery = 91.76% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 62571 19.84 ug/l 99 3) Chloromethane 1.32 50 59658 19.43 ug/l 99 4) Vinyl Chloride 1.40 62 64672 20.18 ug/l 99 5) Bromomethane 1.64 94 34955 21.89 ug/l 98 6) Chloroethane 1.72 64 42084 19.86 ug/l 98 7) Trichlorofluoromethane 1.93 101 99531 20.63 ug/l 99 8) Diethyl Ether 2.19 74 39304 20.79 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 58514 20.69 ug/l 98 10) Methyl Iodide 2.51 142 65290 16.00 ug/l 100 11) Tert butyl alcohol 3.09 59 80435 113.31 ug/l 99 12) 1,1-Dichloroethene 2.37 96 53862 20.78 ug/l 98 13) Acrolein 2.30 56 12792 83.64 ug/l 98 14) Allyl chloride 2.73 41 102506 21.21 ug/l 99 15) Acrylonitrile 3.15 53 176555 110.06 ug/l 100 16) Acetone 2.45 43 176856 115.68 ug/l 97 17) Carbon Disulfide 2.57 76 118760 18.00 ug/l 98 18) Methyl Acetate 2.78 43 97019 24.15 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 192011 21.28 ug/l 99 20) Methylene Chloride 2.86 84 62257 20.57 ug/l 98 21) trans-1,2-Dichloroethene 3.17 96 57202 19.77 ug/l 97 22) Diisopropyl ether 3.88 45 180319 19.97 ug/l 97 23) Vinyl Acetate 3.83 43 794997 105.64 ug/l 99 24) 1,1-Dichloroethane 3.70 63 109362 21.68 ug/l 100 25) 2-Butanone 4.72 43 246399 111.49 ug/l 98 26) 2,2-Dichloropropane 4.59 77 83628 21.47 ug/l 100 27) cis-1,2-Dichloroethene 4.60 96 62341 20.23 ug/l 99 28) Bromochloromethane 5.03 49 47127 21.55 ug/l 97 29) Tetrahydrofuran 5.18 42 151697 107.28 ug/l 99 30) Chloroform 5.22 83 110446 21.26 ug/l 98 31) Cyclohexane 5.58 56 84064 19.40 ug/l 94 32) 1,1,1-Trichloroethane 5.50 97 96479 21.25 ug/l 99 36) 1,1-Dichloropropene 5.80 75 75981 19.84 ug/l 99 37) Ethyl Acetate 4.87 43 90088 21.46 ug/l 100 38) Carbon Tetrachloride 5.78 117 85515 20.94 ug/l 99 39) Methylcyclohexane 7.46 83 86830 19.18 ug/l 97 40) Benzene 6.15 78 235259 21.04 ug/l 97 41) Methacrylonitrile 5.07 41 51149 21.30 ug/l 99 42) 1,2-Dichloroethane 6.20 62 92605 21.54 ug/l 100 43) Isopropyl Acetate 6.48 43 135486 21.03 ug/l 99 44) Trichloroethene 7.22 130 70943 20.75 ug/l 100 45) 1,2-Dichloropropane 7.53 63 57951 20.78 ug/l 96 46) Dibromomethane 7.67 93 41575 21.06 ug/l 99 47) Bromodichloromethane 7.90 83 76856 21.04 ug/l 98 48) Methyl methacrylate 7.79 41 73943 21.08 ug/l 100 49) 1,4-Dioxane 7.77 88 33297 439.27 ug/l 97 51) 4-Methyl-2-Pentanone 8.66 43 481860 112.54 ug/l 98 52) Toluene 8.79 92 152932 20.91 ug/l 99 53) t-1,3-Dichloropropene 8.45 75 86359 20.92 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 75853 19.23 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 62992 21.38 ug/l 98 56) Ethyl methacrylate 9.19 69 86544 20.38 ug/l 99 57) 1,3-Dichloropropane 9.38 76 103286 21.20 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 223357 107.23 ug/l 100 59) 2-Hexanone 9.51 43 365747 111.55 ug/l 99 60) Dibromochloromethane 9.59 129 61489 20.38 ug/l 98 61) 1,2-Dibromoethane 9.68 107 66247 21.42 ug/l 99 64) Tetrachloroethene 9.34 164 82045 21.01 ug/l 99 65) Chlorobenzene 10.15 112 171369 20.86 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 63639 21.65 ug/l 100 67) Ethyl Benzene 10.26 91 281533 20.90 ug/l 98 68) m/p-Xylenes 10.37 106 225195 42.32 ug/l 100 69) o-Xylene 10.71 106 109096 21.09 ug/l 99 70) Styrene 10.72 104 179644 21.38 ug/l 100 71) Bromoform 10.87 173 48608 19.54 ug/l # 100 73) Isopropylbenzene 11.02 105 293983 21.17 ug/l 100 74) N-amyl acetate 6.48 43 135486 21.48 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 88470 21.57 ug/l 100 76) 1,2,3-Trichloropropane 11.30 75 88921m 21.86 ug/l 77) Bromobenzene 11.26 156 82874 20.53 ug/l 99 78) n-propylbenzene 11.37 91 325712 21.54 ug/l 99 79) 2-Chlorotoluene 11.43 91 197084 21.18 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 244695 21.16 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 22006 20.05 ug/l 92 82) 4-Chlorotoluene 11.52 91 228816 21.31 ug/l 99 83) tert-Butylbenzene 11.77 119 243607 21.17 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 252881 21.28 ug/l 100 85) sec-Butylbenzene 11.95 105 294299 21.31 ug/l 100 86) p-Isopropyltoluene 12.07 119 269242 21.25 ug/l 99 87) 1,3-Dichlorobenzene 12.03 146 149156 20.67 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 151922 20.64 ug/l 99 89) n-Butylbenzene 12.40 91 212872 20.28 ug/l 99 90) Hexachloroethane 12.60 117 39555 20.74 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 153692 20.93 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 20305 22.53 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 108161 20.13 ug/l 99 94) Hexachlorobutadiene 13.79 225 60612 20.62 ug/l 99 95) Naphthalene 13.84 128 316210 21.28 ug/l 99 96) 1,2,3-Trichlorobenzene 14.03 180 114571 20.78 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed