Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051018\ Data File : VX001616.D Acq On : 10 May 2018 21:42 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 21 Sample Multiplier: 1 Quant Time: May 11 07:05:51 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 229486 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 300295 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 288022 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 207963 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 160898 48.78 ug/l 0.00 Spiked Amount 50.000 Recovery = 97.56% 35) Dibromofluoromethane 5.51 113 131841 49.36 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.72% 50) Toluene-d8 8.72 98 470000 48.21 ug/l 0.00 Spiked Amount 50.000 Recovery = 96.42% 62) 4-Bromofluorobenzene 11.14 95 178392 47.66 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.32% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 143309 46.39 ug/l 99 3) Chloromethane 1.32 50 140818 46.80 ug/l 99 4) Vinyl Chloride 1.40 62 148724 47.36 ug/l 99 5) Bromomethane 1.64 94 64327 44.37 ug/l 99 6) Chloroethane 1.72 64 100916 48.62 ug/l 97 7) Trichlorofluoromethane 1.92 101 233963 49.51 ug/l 99 8) Diethyl Ether 2.19 74 93348 50.40 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.38 101 131857 47.59 ug/l 99 10) Methyl Iodide 2.51 142 175478 43.90 ug/l 100 11) Tert butyl alcohol 3.09 59 189052 271.85 ug/l 99 12) 1,1-Dichloroethene 2.37 96 125267 49.33 ug/l 99 13) Acrolein 2.30 56 28305 204.33 ug/l 95 14) Allyl chloride 2.73 41 238384 50.35 ug/l 98 15) Acrylonitrile 3.15 53 419473 266.93 ug/l 100 16) Acetone 2.45 43 370313 247.25 ug/l 99 17) Carbon Disulfide 2.57 76 290250 44.91 ug/l 99 18) Methyl Acetate 2.78 43 229846 58.41 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 456895 51.68 ug/l 99 20) Methylene Chloride 2.86 84 143692 48.45 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 135552 47.83 ug/l 96 22) Diisopropyl ether 3.88 45 447186 50.55 ug/l 99 23) Vinyl Acetate 3.83 43 1862631 252.65 ug/l 99 24) 1,1-Dichloroethane 3.70 63 258055 52.22 ug/l 99 25) 2-Butanone 4.72 43 572490 264.43 ug/l 99 26) 2,2-Dichloropropane 4.59 77 166105 43.53 ug/l 98 27) cis-1,2-Dichloroethene 4.60 96 151874 50.32 ug/l 97 28) Bromochloromethane 5.03 49 116270 54.27 ug/l 98 29) Tetrahydrofuran 5.18 42 369980 267.09 ug/l 100 30) Chloroform 5.22 83 267175 52.49 ug/l 97 31) Cyclohexane 5.57 56 204708 48.23 ug/l 95 32) 1,1,1-Trichloroethane 5.50 97 235805 53.00 ug/l 100 36) 1,1-Dichloropropene 5.81 75 184864 48.40 ug/l 99 37) Ethyl Acetate 4.87 43 218913 52.28 ug/l 100 38) Carbon Tetrachloride 5.79 117 210349 51.63 ug/l 98 39) Methylcyclohexane 7.46 83 212376 47.03 ug/l 98 40) Benzene 6.15 78 567554 50.87 ug/l 100 41) Methacrylonitrile 5.07 41 124335 51.90 ug/l 99 42) 1,2-Dichloroethane 6.21 62 222144 51.80 ug/l 99 43) Isopropyl Acetate 6.48 43 342242 53.24 ug/l 100 44) Trichloroethene 7.22 130 170895 50.11 ug/l 99 45) 1,2-Dichloropropane 7.53 63 145992 52.49 ug/l 98 46) Dibromomethane 7.67 93 101923 51.76 ug/l 99 47) Bromodichloromethane 7.90 83 199307 54.69 ug/l 99 48) Methyl methacrylate 7.79 41 186266 53.22 ug/l 99 49) 1,4-Dioxane 7.76 88 81820 1081.99 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 1176993 275.55 ug/l 99 52) Toluene 8.79 92 372413 51.05 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 221625 53.81 ug/l 98 54) cis-1,3-Dichloropropene 9.05 75 198369 46.74 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 154513 52.57 ug/l 96 56) Ethyl methacrylate 9.19 69 228848 54.01 ug/l 98 57) 1,3-Dichloropropane 9.38 76 250880 51.62 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 590170 284.00 ug/l 99 59) 2-Hexanone 9.51 43 890979 272.40 ug/l 99 60) Dibromochloromethane 9.59 129 164676 54.71 ug/l 99 61) 1,2-Dibromoethane 9.68 107 161779 52.42 ug/l 100 64) Tetrachloroethene 9.34 164 201867 50.28 ug/l 99 65) Chlorobenzene 10.15 112 426363 50.47 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 161913 53.59 ug/l 100 67) Ethyl Benzene 10.26 91 708360 51.16 ug/l 100 68) m/p-Xylenes 10.37 106 563441 102.99 ug/l 100 69) o-Xylene 10.71 106 276352 51.98 ug/l 99 70) Styrene 10.72 104 464534 53.78 ug/l 98 71) Bromoform 10.87 173 136863 47.31 ug/l 100 73) Isopropylbenzene 11.02 105 744413 51.71 ug/l 100 74) N-amyl acetate 6.48 43 342242 52.34 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 226083 53.17 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 222030m 52.64 ug/l 77) Bromobenzene 11.26 156 210187 50.22 ug/l 100 78) n-propylbenzene 11.37 91 820507 52.34 ug/l 99 79) 2-Chlorotoluene 11.43 91 495124 51.32 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 618650 51.61 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 59191 45.20 ug/l 98 82) 4-Chlorotoluene 11.52 91 573954 51.57 ug/l 100 83) tert-Butylbenzene 11.77 119 606133 50.82 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 641219 52.05 ug/l 100 85) sec-Butylbenzene 11.95 105 752837 52.59 ug/l 100 86) p-Isopropyltoluene 12.07 119 689445 52.50 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 380469 50.85 ug/l 99 88) 1,4-Dichlorobenzene 12.10 146 383312 50.23 ug/l 100 89) n-Butylbenzene 12.40 91 560814 51.54 ug/l 99 90) Hexachloroethane 12.60 117 108967 55.11 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 386662 50.80 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 54835 58.70 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 285506 51.26 ug/l 100 94) Hexachlorobutadiene 13.79 225 151479 49.70 ug/l 99 95) Naphthalene 13.84 128 843033 54.72 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 299553 52.41 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed