Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001618.D Acq On : 10 May 2018 23:02 Operator : JC/MD Sample : VSTDICC005 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 24 Sample Multiplier: 1 Quant Time: May 11 07:04:39 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 06:59:10 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 54429 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 264183 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 242225 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 120706 30.63 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 102.10% 60) 4-Bromofluorobenzene 11.15 95 108852 26.98 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 89.93% 63) Toluene-d8 8.72 98 327179 31.18 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 103.93% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 12263 3.60 ug/l 98 3) Chloromethane 1.32 50 15268 4.67 ug/l 95 4) Vinyl Chloride 1.40 62 15661 4.56 ug/l 100 5) Bromomethane 1.64 94 8904 3.55 ug/l 96 6) Chloroethane 1.72 64 11028 5.14 ug/l 97 7) Trichlorofluoromethane 1.93 101 23130 4.15 ug/l 99 8) Diethyl Ether 2.19 74 10236 5.07 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 12510 3.94 ug/l 99 10) 1,1-Dichloroethene 2.37 96 13275 4.53 ug/l 94 11) Methyl Iodide 2.51 142 15509 4.19 ug/l 99 12) Methyl Acetate 2.78 43 23065 5.71 ug/l 97 13) Acrolein 2.30 56 13436 28.67 ug/l 96 14) Acrylonitrile 3.15 53 45991 28.58 ug/l 99 15) Acetone 2.45 58 12551 25.95 ug/l 99 16) Carbon Disulfide 2.57 76 28800 3.76 ug/l 98 17) Allyl chloride 2.73 41 24729 4.72 ug/l 99 18) Methylene Chloride 2.86 84 16682 5.18 ug/l 93 19) trans-1,2-Dichloroethene 3.17 96 14330 4.55 ug/l 97 20) Diisopropyl ether 3.89 45 44365 4.34 ug/l 98 21) 1,1-Dichloroethane 3.70 63 28277 5.12 ug/l 98 22) cis-1,2-Dichloroethene 4.60 96 16071 4.58 ug/l # 81 23) tert-Butyl Alcohol 3.09 59 20534 30.63 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 48999 4.84 ug/l 98 25) Chloroform 5.22 83 28386 4.74 ug/l 98 26) Cyclohexane 5.58 56 17254 3.54 ug/l # 98 29) 1,1-Dichloropropene 5.81 75 16700 4.32 ug/l 99 30) 2-Butanone 4.72 43 60081 29.01 ug/l 100 31) 2,2-Dichloropropane 4.59 77 15170 3.76 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 21899 4.65 ug/l 98 33) Carbon Tetrachloride 5.79 117 18924 4.46 ug/l 97 34) Benzene 6.15 78 57098 4.95 ug/l 99 35) Methacrylonitrile 5.07 41 13052 5.70 ug/l 93 36) 1,2-Dichloroethane 6.20 62 24091 5.38 ug/l 98 37) Trichloroethene 7.22 130 16615 4.76 ug/l 98 38) Methylcyclohexane 7.47 83 16374 3.66 ug/l 97 39) 1,2-Dichloropropane 7.52 63 14657 5.01 ug/l 96 40) Dibromomethane 7.67 93 10393 5.03 ug/l 99 41) Bromodichloromethane 7.90 83 18210 4.67 ug/l 94 42) Vinyl Acetate 3.83 43 185596 23.69 ug/l 100 43) Ethyl Acetate 4.87 43 22540 5.63 ug/l # 78 44) Isopropyl Acetate 6.48 43 33084 4.99 ug/l 100 45) 1,4-Dioxane 7.77 88 7650 118.66 ug/l 97 46) Methyl methacrylate 7.79 41 17516 5.03 ug/l 96 47) n-amyl Acetate 10.91 43 24457 3.91 ug/l 100 48) t-1,3-Dichloropropene 8.44 75 18221 4.01 ug/l 96 49) cis-1,3-Dichloropropene 9.05 75 15521 3.62 ug/l 99 50) 1,1,2-Trichloroethane 9.23 97 15342 5.00 ug/l 98 51) Ethyl methacrylate 9.19 69 19866 4.55 ug/l 97 52) 1,3-Dichloropropane 9.38 76 25389 5.10 ug/l 97 53) Dibromochloromethane 9.59 129 13995 4.17 ug/l 99 54) 1,2-Dibromoethane 9.68 107 15635 4.74 ug/l 97 55) 2-Chloroethyl vinyl ether 8.32 63 52400 24.07 ug/l 100 56) Bromoform 10.87 173 10204 3.71 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 109778 26.46 ug/l 99 59) 2-Hexanone 9.51 43 82089 25.57 ug/l 97 61) Tetrachloroethene 9.34 164 18648 5.04 ug/l 99 62) Toluene 8.79 91 61549 4.76 ug/l 98 64) Chlorobenzene 10.15 112 40487 4.65 ug/l 97 65) 1,1,1,2-Tetrachloroethane 10.23 131 14605 4.59 ug/l 98 66) Ethyl Benzene 10.26 91 59218 4.16 ug/l 98 67) m/p-Xylenes 10.37 106 46190 8.11 ug/l 99 68) o-Xylene 10.71 106 23472 4.27 ug/l 97 69) Styrene 10.72 104 35989 3.93 ug/l 100 70) Isopropylbenzene 11.02 105 58305 3.93 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 21863 4.91 ug/l 98 72) 1,2,3-Trichloropropane 11.30 75 21351m 5.31 ug/l 73) Bromobenzene 11.26 156 19084 4.40 ug/l 99 74) n-propylbenzene 11.37 91 61382 3.67 ug/l 99 75) 2-Chlorotoluene 11.43 91 41899 4.12 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 48572 3.84 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 3924 3.31 ug/l 74 78) 4-Chlorotoluene 11.52 91 45736 3.81 ug/l 100 79) tert-butylbenzene 12.07 119 46691 3.45 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 48028 3.74 ug/l 98 81) sec-Butylbenzene 11.95 105 53525 3.65 ug/l 100 82) p-Isopropyltoluene 12.07 119 46691 3.45 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 31862 4.05 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 31334 3.93 ug/l 98 85) n-Butylbenzene 12.40 91 34452 2.99 ug/l 99 86) Hexachloroethane 12.60 117 7244 3.48 ug/l 98 87) 1,2-Dichlorobenzene 12.40 146 33790 4.30 ug/l 99 88) 1,2-Dibromo-3-Chloropropan 13.01 75 4380 4.61 ug/l 96 89) 1,2,4-Trichlorobenzene 13.65 180 20849 3.55 ug/l 99 90) Hexachlorobutadiene 13.79 225 11129 3.95 ug/l 97 91) Naphthalene 13.84 128 59981 3.84 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 23247 3.95 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed