Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001619.D Acq On : 10 May 2018 23:29 Operator : JC/MD Sample : VSTDICCC020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 25 Sample Multiplier: 1 Quant Time: May 11 07:06:11 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 06:59:10 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 54186 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 274955 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 250743 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.08 65 121099 30.87 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 102.90% 60) 4-Bromofluorobenzene 11.14 95 119529 28.62 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 95.40% 63) Toluene-d8 8.72 98 338460 31.16 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 103.87% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 61853 18.23 ug/l 100 3) Chloromethane 1.32 50 65143 20.03 ug/l 100 4) Vinyl Chloride 1.40 62 68435 20.04 ug/l 100 5) Bromomethane 1.64 94 41007 16.41 ug/l 100 6) Chloroethane 1.73 64 45303 21.19 ug/l 100 7) Trichlorofluoromethane 1.93 101 98363 17.72 ug/l 100 8) Diethyl Ether 2.19 74 41459 20.62 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 55511 17.55 ug/l 100 10) 1,1-Dichloroethene 2.37 96 54662 18.75 ug/l 100 11) Methyl Iodide 2.51 142 74230 20.12 ug/l 100 12) Methyl Acetate 2.78 43 92373 22.97 ug/l 100 13) Acrolein 2.30 56 48477 103.90 ug/l 100 14) Acrylonitrile 3.15 53 183529 114.57 ug/l 100 15) Acetone 2.45 58 49438 102.66 ug/l 100 16) Carbon Disulfide 2.57 76 130596 17.12 ug/l 100 17) Allyl chloride 2.73 41 103349 19.80 ug/l 100 18) Methylene Chloride 2.86 84 64059 19.98 ug/l 100 19) trans-1,2-Dichloroethene 3.17 96 58962 18.79 ug/l 100 20) Diisopropyl ether 3.88 45 188622 18.54 ug/l 100 21) 1,1-Dichloroethane 3.70 63 111744 20.32 ug/l 100 22) cis-1,2-Dichloroethene 4.60 96 65421 18.74 ug/l 100 23) tert-Butyl Alcohol 3.08 59 80715 120.92 ug/l 100 24) Methyl tert-Butyl Ether 3.21 73 197783 19.64 ug/l 100 25) Chloroform 5.22 83 113684 19.05 ug/l 100 26) Cyclohexane 5.58 56 81670 16.83 ug/l # 100 29) 1,1-Dichloropropene 5.81 75 75189 18.70 ug/l 100 30) 2-Butanone 4.72 43 246258 114.26 ug/l 100 31) 2,2-Dichloropropane 4.59 77 64245 15.32 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 96210 19.64 ug/l 100 33) Carbon Tetrachloride 5.79 117 83788 18.96 ug/l 100 34) Benzene 6.15 78 239692 19.95 ug/l 100 35) Methacrylonitrile 5.07 41 52894 22.19 ug/l 100 36) 1,2-Dichloroethane 6.21 62 95963 20.60 ug/l 100 37) Trichloroethene 7.22 130 71076 19.56 ug/l 100 38) Methylcyclohexane 7.46 83 80456 17.30 ug/l 100 39) 1,2-Dichloropropane 7.52 63 59528 19.55 ug/l 100 40) Dibromomethane 7.67 93 43137 20.06 ug/l 100 41) Bromodichloromethane 7.91 83 79312 19.54 ug/l 100 42) Vinyl Acetate 3.83 43 801568 98.29 ug/l 100 43) Ethyl Acetate 4.87 43 93356 22.41 ug/l 100 44) Isopropyl Acetate 6.48 43 138519 20.08 ug/l 100 45) 1,4-Dioxane 7.76 88 33030 492.27 ug/l 100 46) Methyl methacrylate 7.79 41 75934 20.96 ug/l 100 47) n-amyl Acetate 10.91 43 118096 18.15 ug/l 100 48) t-1,3-Dichloropropene 8.44 75 86358 18.27 ug/l 100 49) cis-1,3-Dichloropropene 9.05 75 74956 16.82 ug/l 100 50) 1,1,2-Trichloroethane 9.22 97 64836 20.28 ug/l 100 51) Ethyl methacrylate 9.19 69 87500 19.24 ug/l 100 52) 1,3-Dichloropropane 9.38 76 105482 20.36 ug/l 100 53) Dibromochloromethane 9.59 129 63905 18.28 ug/l 100 54) 1,2-Dibromoethane 9.68 107 68395 19.93 ug/l 100 55) 2-Chloroethyl vinyl ether 8.32 63 241737 106.69 ug/l 100 56) Bromoform 10.87 173 49937 17.42 ug/l 100 58) 4-Methyl-2-Pentanone 8.66 43 487325 113.48 ug/l 100 59) 2-Hexanone 9.51 43 363946 109.50 ug/l 100 61) Tetrachloroethene 9.34 164 80395 21.01 ug/l 100 62) Toluene 8.79 91 260892 19.50 ug/l 100 64) Chlorobenzene 10.15 112 173256 19.23 ug/l 100 65) 1,1,1,2-Tetrachloroethane 10.23 131 64285 19.54 ug/l 100 66) Ethyl Benzene 10.26 91 271237 18.39 ug/l 100 67) m/p-Xylenes 10.37 106 218849 37.13 ug/l 100 68) o-Xylene 10.71 106 106518 18.72 ug/l 100 69) Styrene 10.72 104 175524 18.53 ug/l 100 70) Isopropylbenzene 11.02 105 281191 18.29 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 91123 19.75 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 89570m 21.53 ug/l 73) Bromobenzene 11.26 156 82678 18.41 ug/l 100 74) n-propylbenzene 11.37 91 309311 17.85 ug/l 100 75) 2-Chlorotoluene 11.43 91 193544 18.37 ug/l 100 76) 1,3,5-Trimethylbenzene 11.51 105 235421 17.97 ug/l 100 77) t-1,4-Dichloro-2-butene 11.08 75 20798 16.97 ug/l 100 78) 4-Chlorotoluene 11.52 91 218313 17.55 ug/l 100 79) tert-butylbenzene 12.07 119 249603 17.83 ug/l 100 80) 1,2,4-Trimethylbenzene 11.81 105 241647 18.17 ug/l 100 81) sec-Butylbenzene 11.95 105 272536 17.94 ug/l 100 82) p-Isopropyltoluene 12.07 119 249603 17.83 ug/l 100 83) 1,3-Dichlorobenzene 12.03 146 144348 17.75 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 144778 17.53 ug/l 100 85) n-Butylbenzene 12.40 91 190670 15.96 ug/l 100 86) Hexachloroethane 12.60 117 37514 17.41 ug/l 100 87) 1,2-Dichlorobenzene 12.40 146 149495 18.36 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 20661 21.00 ug/l 100 89) 1,2,4-Trichlorobenzene 13.65 180 102711 16.91 ug/l 100 90) Hexachlorobutadiene 13.79 225 55091 18.91 ug/l 100 91) Naphthalene 13.84 128 312230 19.31 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 110538 18.16 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed