Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001620.D Acq On : 10 May 2018 23:55 Operator : JC/MD Sample : VSTDICC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 26 Sample Multiplier: 1 Quant Time: May 11 07:07:53 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 06:59:10 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 55871 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 289307 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 269490 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 120293 29.74 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 99.13% 60) 4-Bromofluorobenzene 11.15 95 129140 28.77 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 95.90% 63) Toluene-d8 8.72 98 355374 30.44 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 101.47% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 146022 41.74 ug/l 100 3) Chloromethane 1.32 50 154968 46.22 ug/l 98 4) Vinyl Chloride 1.40 62 164580 46.73 ug/l 99 5) Bromomethane 1.64 94 72444 28.12 ug/l 96 6) Chloroethane 1.72 64 107337 48.70 ug/l 93 7) Trichlorofluoromethane 1.93 101 237806 41.55 ug/l 99 8) Diethyl Ether 2.19 74 99476 47.98 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.38 101 132407 40.60 ug/l 99 10) 1,1-Dichloroethene 2.37 96 134806 44.85 ug/l 97 11) Methyl Iodide 2.51 142 206421 54.27 ug/l 99 12) Methyl Acetate 2.78 43 227083 54.76 ug/l 99 13) Acrolein 2.30 56 120472 250.42 ug/l 99 14) Acrylonitrile 3.15 53 456508 276.38 ug/l 99 15) Acetone 2.45 58 122180 246.06 ug/l 98 16) Carbon Disulfide 2.57 76 343142 43.63 ug/l 100 17) Allyl chloride 2.73 41 255408 47.46 ug/l 98 18) Methylene Chloride 2.86 84 155490 47.04 ug/l 95 19) trans-1,2-Dichloroethene 3.17 96 146659 45.34 ug/l 100 20) Diisopropyl ether 3.88 45 478738 45.64 ug/l 99 21) 1,1-Dichloroethane 3.70 63 272549 48.06 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 162236 45.06 ug/l 98 23) tert-Butyl Alcohol 3.09 59 202104 293.65 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 481962 46.40 ug/l 100 25) Chloroform 5.22 83 283288 46.05 ug/l 98 26) Cyclohexane 5.58 56 208311 41.64 ug/l # 99 29) 1,1-Dichloropropene 5.80 75 193171 45.67 ug/l 100 30) 2-Butanone 4.72 43 631386 278.43 ug/l 100 31) 2,2-Dichloropropane 4.59 77 165037 37.39 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 244285 47.38 ug/l 99 33) Carbon Tetrachloride 5.79 117 219047 47.10 ug/l 99 34) Benzene 6.15 78 607196 48.04 ug/l 98 35) Methacrylonitrile 5.07 41 134538 53.63 ug/l 96 36) 1,2-Dichloroethane 6.21 62 236460 48.24 ug/l 100 37) Trichloroethene 7.22 130 179988 47.07 ug/l 99 38) Methylcyclohexane 7.46 83 211985 43.32 ug/l 98 39) 1,2-Dichloropropane 7.52 63 151113 47.17 ug/l 98 40) Dibromomethane 7.67 93 108694 48.04 ug/l 100 41) Bromodichloromethane 7.90 83 207313 48.54 ug/l 100 42) Vinyl Acetate 3.83 43 2080727 242.48 ug/l 99 43) Ethyl Acetate 4.87 43 237839 54.27 ug/l 98 44) Isopropyl Acetate 6.48 43 366376 50.48 ug/l 99 45) 1,4-Dioxane 7.76 88 87330 1236.98 ug/l 98 46) Methyl methacrylate 7.79 41 200662 52.64 ug/l 97 47) n-amyl Acetate 10.91 43 325659 47.57 ug/l 98 48) t-1,3-Dichloropropene 8.45 75 233589 46.96 ug/l 99 49) cis-1,3-Dichloropropene 9.05 75 209215 44.61 ug/l 97 50) 1,1,2-Trichloroethane 9.23 97 160552 47.74 ug/l 98 51) Ethyl methacrylate 9.19 69 236489 49.41 ug/l 98 52) 1,3-Dichloropropane 9.38 76 265641 48.74 ug/l 98 53) Dibromochloromethane 9.59 129 172282 46.84 ug/l 99 54) 1,2-Dibromoethane 9.68 107 170844 47.30 ug/l 98 55) 2-Chloroethyl vinyl ether 8.32 63 638725 267.91 ug/l 100 56) Bromoform 10.87 173 142289 47.18 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 1263633 273.78 ug/l 99 59) 2-Hexanone 9.51 43 957161 267.94 ug/l 99 61) Tetrachloroethene 9.34 164 207884 50.54 ug/l 99 62) Toluene 8.79 91 669880 46.59 ug/l 99 64) Chlorobenzene 10.15 112 436869 45.13 ug/l 98 65) 1,1,1,2-Tetrachloroethane 10.23 131 167329 47.31 ug/l 99 66) Ethyl Benzene 10.26 91 716822 45.21 ug/l 98 67) m/p-Xylenes 10.37 106 576477 91.00 ug/l 98 68) o-Xylene 10.71 106 281123 45.98 ug/l 99 69) Styrene 10.72 104 473919 46.56 ug/l 98 70) Isopropylbenzene 11.02 105 735910 44.53 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 231598 46.71 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 225614m 50.46 ug/l 73) Bromobenzene 11.26 156 215679 44.67 ug/l 99 74) n-propylbenzene 11.37 91 814269 43.73 ug/l 99 75) 2-Chlorotoluene 11.43 91 500004 44.16 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 620689 44.08 ug/l 100 77) t-1,4-Dichloro-2-butene 11.08 75 60639 46.04 ug/l 93 78) 4-Chlorotoluene 11.52 91 576438 43.12 ug/l 100 79) tert-butylbenzene 12.07 119 665296 44.22 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 639720 44.75 ug/l 100 81) sec-Butylbenzene 11.95 105 724086 44.35 ug/l 100 82) p-Isopropyltoluene 12.07 119 665296 44.22 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 381408 43.63 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 385853 43.48 ug/l 98 85) n-Butylbenzene 12.40 91 533431 41.55 ug/l 99 86) Hexachloroethane 12.60 117 102910 44.45 ug/l 96 87) 1,2-Dichlorobenzene 12.40 146 391399 44.74 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 57533 54.40 ug/l 97 89) 1,2,4-Trichlorobenzene 13.65 180 286413 43.88 ug/l 100 90) Hexachlorobutadiene 13.79 225 144663 46.19 ug/l 97 91) Naphthalene 13.84 128 877055 50.47 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 300936 46.00 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed