Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001621.D Acq On : 11 May 2018 00:22 Operator : JC/MD Sample : VSTDICC100 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 27 Sample Multiplier: 1 Quant Time: May 11 07:10:29 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 06:59:10 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 57686 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 314664 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 286791 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 124256 29.75 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 99.17% 60) 4-Bromofluorobenzene 11.15 95 138687 29.04 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 96.80% 63) Toluene-d8 8.72 98 382627 30.80 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 102.67% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 316631 87.66 ug/l 99 3) Chloromethane 1.32 50 320855 92.68 ug/l 100 4) Vinyl Chloride 1.40 62 343358 94.42 ug/l 99 5) Bromomethane 1.64 94 140541 52.84 ug/l 98 6) Chloroethane 1.71 64 223243 98.09 ug/l 95 7) Trichlorofluoromethane 1.92 101 507526 85.89 ug/l 99 8) Diethyl Ether 2.19 74 207861 97.11 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.38 101 290476 86.28 ug/l 98 10) 1,1-Dichloroethene 2.37 96 286347 92.28 ug/l 99 11) Methyl Iodide 2.51 142 457812 116.58 ug/l 99 12) Methyl Acetate 2.78 43 460176 107.48 ug/l 100 13) Acrolein 2.30 56 239608 482.40 ug/l 99 14) Acrylonitrile 3.16 53 922353 540.85 ug/l 100 15) Acetone 2.45 58 245344 478.56 ug/l 99 16) Carbon Disulfide 2.56 76 766219 94.35 ug/l 99 17) Allyl chloride 2.73 41 541040 97.38 ug/l 96 18) Methylene Chloride 2.85 84 318977 93.46 ug/l 97 19) trans-1,2-Dichloroethene 3.16 96 308274 92.30 ug/l 99 20) Diisopropyl ether 3.88 45 1028799 95.00 ug/l 99 21) 1,1-Dichloroethane 3.70 63 561652 95.92 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 350157 94.19 ug/l 97 23) tert-Butyl Alcohol 3.10 59 404979 569.91 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 995257 92.81 ug/l 99 25) Chloroform 5.22 83 587192 92.45 ug/l 97 26) Cyclohexane 5.57 56 486218 94.14 ug/l # 99 29) 1,1-Dichloropropene 5.81 75 436495 94.87 ug/l 100 30) 2-Butanone 4.72 43 1275867 517.29 ug/l 100 31) 2,2-Dichloropropane 4.59 77 354567 73.86 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 531105 94.72 ug/l 99 33) Carbon Tetrachloride 5.79 117 485154 95.92 ug/l 98 34) Benzene 6.15 78 1297125 94.35 ug/l 99 35) Methacrylonitrile 5.07 41 279107 102.30 ug/l 96 36) 1,2-Dichloroethane 6.21 62 485270 91.02 ug/l 100 37) Trichloroethene 7.22 130 390418 93.88 ug/l 100 38) Methylcyclohexane 7.46 83 506641 95.19 ug/l 97 39) 1,2-Dichloropropane 7.52 63 319364 91.65 ug/l 99 40) Dibromomethane 7.67 93 226144 91.89 ug/l 99 41) Bromodichloromethane 7.91 83 450914 97.06 ug/l 99 42) Vinyl Acetate 3.83 43 4419062 473.48 ug/l 99 43) Ethyl Acetate 4.87 43 496726 104.20 ug/l 99 44) Isopropyl Acetate 6.48 43 790219 100.10 ug/l 99 45) 1,4-Dioxane 7.77 88 184310 2400.26 ug/l 97 46) Methyl methacrylate 7.79 41 425812 102.71 ug/l 97 47) n-amyl Acetate 10.91 43 716704 96.25 ug/l 97 48) t-1,3-Dichloropropene 8.45 75 519007 95.93 ug/l 100 49) cis-1,3-Dichloropropene 9.05 75 465882 91.33 ug/l 97 50) 1,1,2-Trichloroethane 9.22 97 333996 91.30 ug/l 98 51) Ethyl methacrylate 9.19 69 521358 100.16 ug/l 98 52) 1,3-Dichloropropane 9.38 76 553092 93.29 ug/l 98 53) Dibromochloromethane 9.59 129 377101 94.26 ug/l 99 54) 1,2-Dibromoethane 9.68 107 357018 90.88 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 1320900 509.39 ug/l 100 56) Bromoform 10.87 173 327118 99.72 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 2628826 535.21 ug/l 97 59) 2-Hexanone 9.51 43 1967084 517.44 ug/l 99 61) Tetrachloroethene 9.34 164 444454 101.54 ug/l 98 62) Toluene 8.79 91 1453026 94.96 ug/l 100 64) Chlorobenzene 10.15 112 953380 92.54 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 361649 96.09 ug/l 100 66) Ethyl Benzene 10.26 91 1585010 93.95 ug/l 98 67) m/p-Xylenes 10.37 106 1267292 187.98 ug/l 98 68) o-Xylene 10.71 106 620517 95.36 ug/l 99 69) Styrene 10.72 104 1040033 96.01 ug/l 99 70) Isopropylbenzene 11.02 105 1644114 93.48 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 499354 94.64 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 480044m 100.89 ug/l 73) Bromobenzene 11.26 156 471529 91.78 ug/l 99 74) n-propylbenzene 11.37 91 1860730 93.90 ug/l 99 75) 2-Chlorotoluene 11.43 91 1100665 91.35 ug/l 98 76) 1,3,5-Trimethylbenzene 11.51 105 1384543 92.41 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 146748 104.69 ug/l 87 78) 4-Chlorotoluene 11.52 91 1276649 89.74 ug/l 100 79) tert-butylbenzene 12.07 119 1543787 96.42 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 1408420 92.58 ug/l 99 81) sec-Butylbenzene 11.95 105 1675971 96.46 ug/l 100 82) p-Isopropyltoluene 12.07 119 1543787 96.42 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 850062 91.37 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 861950 91.26 ug/l 99 85) n-Butylbenzene 12.40 91 1305240 95.54 ug/l 99 86) Hexachloroethane 12.60 117 255571 103.72 ug/l 96 87) 1,2-Dichlorobenzene 12.40 146 863818 92.78 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 123188 109.45 ug/l 93 89) 1,2,4-Trichlorobenzene 13.65 180 668471 96.24 ug/l 99 90) Hexachlorobutadiene 13.79 225 346730 104.03 ug/l 98 91) Naphthalene 13.84 128 1913052 103.45 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 676755 97.21 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed