Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001622.D Acq On : 11 May 2018 00:49 Operator : JC/MD Sample : VSTDICC150 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 28 Sample Multiplier: 1 Quant Time: May 11 07:13:42 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 06:59:10 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 56995 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 302132 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 266250 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 124553 30.18 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 100.60% 60) 4-Bromofluorobenzene 11.15 95 129124 29.12 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 97.07% 63) Toluene-d8 8.72 98 355738 30.84 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 102.80% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.19 85 293768 82.31 ug/l 99 3) Chloromethane 1.32 50 362789 106.06 ug/l 98 4) Vinyl Chloride 1.40 62 363389 101.15 ug/l 98 5) Bromomethane 1.64 94 157089 59.78 ug/l 98 6) Chloroethane 1.71 64 240055 106.76 ug/l 94 7) Trichlorofluoromethane 1.92 101 477200 81.74 ug/l 100 8) Diethyl Ether 2.19 74 238931 112.98 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.37 101 255565 76.83 ug/l 98 10) 1,1-Dichloroethene 2.37 96 293226 95.64 ug/l 98 11) Methyl Iodide 2.51 142 491519 126.68 ug/l 99 12) Methyl Acetate 2.78 43 533675 126.15 ug/l 100 13) Acrolein 2.30 56 378820 771.92 ug/l 100 14) Acrylonitrile 3.16 53 1061975 630.27 ug/l 100 15) Acetone 2.46 58 283234 559.17 ug/l 95 16) Carbon Disulfide 2.56 76 779991 97.21 ug/l 100 17) Allyl chloride 2.73 41 598310 108.99 ug/l 95 18) Methylene Chloride 2.85 84 356966 105.85 ug/l 97 19) trans-1,2-Dichloroethene 3.16 96 326430 98.92 ug/l 98 20) Diisopropyl ether 3.88 45 1179587 110.25 ug/l 99 21) 1,1-Dichloroethane 3.70 63 618398 106.89 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 384918 104.80 ug/l 96 23) tert-Butyl Alcohol 3.10 59 488847 696.27 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 1138972 107.50 ug/l 99 25) Chloroform 5.22 83 652002 103.89 ug/l 98 26) Cyclohexane 5.57 56 413635 81.06 ug/l # 99 29) 1,1-Dichloropropene 5.80 75 420267 95.13 ug/l 99 30) 2-Butanone 4.72 43 1485955 627.46 ug/l 99 31) 2,2-Dichloropropane 4.59 77 369674 80.20 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 546152 101.44 ug/l 99 33) Carbon Tetrachloride 5.78 117 464155 95.57 ug/l 100 34) Benzene 6.15 78 1397838 105.89 ug/l 100 35) Methacrylonitrile 5.07 41 329699 125.86 ug/l 96 36) 1,2-Dichloroethane 6.21 62 543518 106.17 ug/l 100 37) Trichloroethene 7.22 130 400801 100.37 ug/l 99 38) Methylcyclohexane 7.46 83 425484 83.25 ug/l 97 39) 1,2-Dichloropropane 7.52 63 355177 106.16 ug/l 99 40) Dibromomethane 7.67 93 256958 108.74 ug/l 98 41) Bromodichloromethane 7.91 83 498862 111.83 ug/l 98 42) Vinyl Acetate 3.83 43 5122481 571.61 ug/l 99 43) Ethyl Acetate 4.88 43 577490 126.17 ug/l 98 44) Isopropyl Acetate 6.48 43 919828 121.35 ug/l 98 45) 1,4-Dioxane 7.77 88 212020 2875.66 ug/l 97 46) Methyl methacrylate 7.79 41 492106 123.62 ug/l 97 47) n-amyl Acetate 10.91 43 816900 114.26 ug/l 97 48) t-1,3-Dichloropropene 8.44 75 579151 111.48 ug/l 98 49) cis-1,3-Dichloropropene 9.05 75 523515 106.88 ug/l 96 50) 1,1,2-Trichloroethane 9.22 97 376523 107.20 ug/l 97 51) Ethyl methacrylate 9.19 69 596250 119.30 ug/l 98 52) 1,3-Dichloropropane 9.38 76 619773 108.88 ug/l 99 53) Dibromochloromethane 9.59 129 424941 110.62 ug/l 99 54) 1,2-Dibromoethane 9.68 107 404254 107.18 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 1585624 636.84 ug/l 99 56) Bromoform 10.87 173 377210 119.76 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 3052149 669.33 ug/l 98 59) 2-Hexanone 9.51 43 2273160 644.08 ug/l 98 61) Tetrachloroethene 9.34 164 414613 102.03 ug/l 98 62) Toluene 8.79 91 1489046 104.82 ug/l 99 64) Chlorobenzene 10.15 112 974285 101.87 ug/l 100 65) 1,1,1,2-Tetrachloroethane 10.23 131 391655 112.09 ug/l 100 66) Ethyl Benzene 10.26 91 1523863 97.29 ug/l 98 67) m/p-Xylenes 10.37 106 1221456 195.16 ug/l 98 68) o-Xylene 10.71 106 618304 102.35 ug/l 98 69) Styrene 10.72 104 1060628 105.46 ug/l 98 70) Isopropylbenzene 11.02 105 1512722 92.65 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 574131 117.20 ug/l 99 72) 1,2,3-Trichloropropane 11.30 75 542777m 122.88 ug/l 73) Bromobenzene 11.26 156 490846 102.91 ug/l 99 74) n-propylbenzene 11.37 91 1675750 91.09 ug/l 99 75) 2-Chlorotoluene 11.43 91 1066719 95.37 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 1293975 93.02 ug/l 99 77) t-1,4-Dichloro-2-butene 11.09 75 168847 129.75 ug/l 82 78) 4-Chlorotoluene 11.52 91 1231122 93.22 ug/l 100 79) tert-butylbenzene 12.07 119 1383893 93.10 ug/l 99 80) 1,2,4-Trimethylbenzene 11.82 105 1350725 95.64 ug/l 99 81) sec-Butylbenzene 11.95 105 1472771 91.31 ug/l 100 82) p-Isopropyltoluene 12.07 119 1383893 93.10 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 847390 98.11 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 859596 98.03 ug/l 99 85) n-Butylbenzene 12.40 91 1129392 89.05 ug/l 98 86) Hexachloroethane 12.60 117 234772 102.63 ug/l 96 87) 1,2-Dichlorobenzene 12.40 146 890642 103.04 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 141650 135.56 ug/l 94 89) 1,2,4-Trichlorobenzene 13.65 180 663907 102.96 ug/l 100 90) Hexachlorobutadiene 13.79 225 303578 98.11 ug/l 98 91) Naphthalene 13.84 128 2100432 122.34 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 695860 107.66 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed