Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001623.D Acq On : 11 May 2018 01:15 Operator : JC/MD Sample : VSTDICV020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 29 Sample Multiplier: 1 Quant Time: May 11 07:29:50 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.02 128 56803 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 293085 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 262816 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 123106 29.70 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 99.00% 60) 4-Bromofluorobenzene 11.14 95 123102 29.60 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 98.67% 63) Toluene-d8 8.72 98 351603 30.00 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 100.00% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 62879 22.72 ug/l 98 3) Chloromethane 1.32 50 70401 22.97 ug/l 100 4) Vinyl Chloride 1.40 62 70342 21.98 ug/l 100 5) Bromomethane 1.64 94 51449 32.53 ug/l 100 6) Chloroethane 1.73 64 45237 21.23 ug/l 95 7) Trichlorofluoromethane 1.93 101 99506 21.64 ug/l 99 8) Diethyl Ether 2.19 74 43817 21.98 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 56162 21.99 ug/l 97 10) 1,1-Dichloroethene 2.37 96 57033 21.69 ug/l 99 11) Methyl Iodide 2.51 142 68376 17.90 ug/l 98 12) Methyl Acetate 2.78 43 96247 21.53 ug/l 99 13) Acrolein 2.30 56 50846 100.32 ug/l 99 14) Acrylonitrile 3.15 53 192795 107.97 ug/l 98 15) Acetone 2.45 58 51820 108.02 ug/l 96 16) Carbon Disulfide 2.57 76 142779 21.92 ug/l 99 17) Allyl chloride 2.73 41 106963 21.33 ug/l 97 18) Methylene Chloride 2.86 84 66162 21.32 ug/l 98 19) trans-1,2-Dichloroethene 3.17 96 61594 21.58 ug/l 99 20) Diisopropyl ether 3.88 45 203635 21.73 ug/l 99 21) 1,1-Dichloroethane 3.70 63 114009 21.16 ug/l 98 22) cis-1,2-Dichloroethene 4.60 96 69409 21.57 ug/l 99 23) tert-Butyl Alcohol 3.08 59 88127 110.92 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 206705 21.64 ug/l 99 25) Chloroform 5.23 83 117568 21.18 ug/l 99 26) Cyclohexane 5.58 56 87301 22.21 ug/l # 97 29) 1,1-Dichloropropene 5.81 75 80140 21.77 ug/l 99 30) 2-Butanone 4.72 43 260629 107.27 ug/l 100 31) 2,2-Dichloropropane 4.59 77 63649 20.11 ug/l 99 32) 1,1,1-Trichloroethane 5.50 97 100584 21.48 ug/l 99 33) Carbon Tetrachloride 5.79 117 86093 20.87 ug/l 99 34) Benzene 6.15 78 250756 21.30 ug/l 98 35) Methacrylonitrile 5.07 41 56114 21.30 ug/l 96 36) 1,2-Dichloroethane 6.21 62 98090 21.06 ug/l 99 37) Trichloroethene 7.22 130 73203 21.10 ug/l 100 38) Methylcyclohexane 7.47 83 88965 22.60 ug/l 98 39) 1,2-Dichloropropane 7.52 63 62093 21.04 ug/l 99 40) Dibromomethane 7.67 93 44271 20.93 ug/l 98 41) Bromodichloromethane 7.91 83 82119 20.64 ug/l 98 42) Vinyl Acetate 3.83 43 869891 108.55 ug/l 99 43) Ethyl Acetate 4.87 43 101707 21.96 ug/l 97 44) Isopropyl Acetate 6.48 43 150493 21.22 ug/l 99 45) 1,4-Dioxane 7.77 88 35727 429.67 ug/l 99 46) Methyl methacrylate 7.79 41 80749 21.09 ug/l 97 47) n-amyl Acetate 10.91 43 122835 20.28 ug/l 100 48) t-1,3-Dichloropropene 8.45 75 90977 20.72 ug/l 100 49) cis-1,3-Dichloropropene 9.05 75 79785 20.56 ug/l 99 50) 1,1,2-Trichloroethane 9.22 97 66467 21.22 ug/l 99 51) Ethyl methacrylate 9.19 69 95233 21.09 ug/l 98 52) 1,3-Dichloropropane 9.38 76 109861 21.29 ug/l 100 53) Dibromochloromethane 9.59 129 66302 20.39 ug/l 98 54) 1,2-Dibromoethane 9.68 107 69589 21.07 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 261324 108.87 ug/l 99 56) Bromoform 10.87 173 52668 19.81 ug/l 97 58) 4-Methyl-2-Pentanone 8.66 43 516006 109.15 ug/l 99 59) 2-Hexanone 9.51 43 380236 107.36 ug/l 100 61) Tetrachloroethene 9.34 164 82967 21.70 ug/l 99 62) Toluene 8.79 91 273951 21.67 ug/l 99 64) Chlorobenzene 10.15 112 180135 21.68 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 66926 21.32 ug/l 98 66) Ethyl Benzene 10.26 91 284988 21.72 ug/l 97 67) m/p-Xylenes 10.37 106 228411 43.60 ug/l 99 68) o-Xylene 10.71 106 111118 21.44 ug/l 99 69) Styrene 10.72 104 182846 21.38 ug/l 99 70) Isopropylbenzene 11.02 105 292669 21.92 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 95918 21.42 ug/l 99 72) 1,2,3-Trichloropropane 11.30 75 90382m 20.83 ug/l 73) Bromobenzene 11.26 156 85595 21.15 ug/l 99 74) n-propylbenzene 11.37 91 320251 21.79 ug/l 99 75) 2-Chlorotoluene 11.43 91 199014 21.59 ug/l 100 76) 1,3,5-Trimethylbenzene 11.51 105 246454 21.93 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 21156 18.96 ug/l 96 78) 4-Chlorotoluene 11.52 91 227887 21.74 ug/l 99 79) tert-butylbenzene 12.07 119 259115 21.79 ug/l 100 80) 1,2,4-Trimethylbenzene 11.81 105 250410 21.83 ug/l 100 81) sec-Butylbenzene 11.95 105 286343 22.00 ug/l 99 82) p-Isopropyltoluene 12.07 119 259115 21.79 ug/l 100 83) 1,3-Dichlorobenzene 12.03 146 150914 21.39 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 152113 21.44 ug/l 99 85) n-Butylbenzene 12.40 91 201780 21.34 ug/l 100 86) Hexachloroethane 12.60 117 39338 20.85 ug/l 99 87) 1,2-Dichlorobenzene 12.40 146 154806 21.16 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 21120 20.24 ug/l 96 89) 1,2,4-Trichlorobenzene 13.65 180 109566 21.08 ug/l 100 90) Hexachlorobutadiene 13.79 225 55769 20.97 ug/l 97 91) Naphthalene 13.84 128 334190 21.47 ug/l 100 92) 1,2,3-Trichlorobenzene 14.03 180 117751 21.42 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed