Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001625.D Acq On : 11 May 2018 02:35 Operator : JC/MD Sample : VX0510WBS01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 32 Sample Multiplier: 1 Quant Time: May 11 07:34:46 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 54709 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 278831 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 251575 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 122280 30.63 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 102.10% 60) 4-Bromofluorobenzene 11.14 95 116119 29.17 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 97.23% 63) Toluene-d8 8.72 98 337248 30.06 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 100.20% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 58546 21.96 ug/l 96 3) Chloromethane 1.32 50 65721 22.27 ug/l 98 4) Vinyl Chloride 1.40 62 67864 22.02 ug/l 99 5) Bromomethane 1.64 94 47474 31.16 ug/l 100 6) Chloroethane 1.73 64 45856 22.35 ug/l 94 7) Trichlorofluoromethane 1.93 101 96532 21.80 ug/l 99 8) Diethyl Ether 2.19 74 42285 22.03 ug/l 100 9) 1,1,2-Trichlorotrifluoroet 2.39 101 54611 22.20 ug/l 99 10) 1,1-Dichloroethene 2.37 96 54079 21.36 ug/l 98 11) Methyl Iodide 2.51 142 64012 17.40 ug/l 97 12) Methyl Acetate 2.78 43 94251 21.89 ug/l 99 13) Acrolein 2.30 56 47698 97.71 ug/l 99 14) Acrylonitrile 3.15 53 188760 109.76 ug/l 100 15) Acetone 2.45 58 51263 110.95 ug/l 96 16) Carbon Disulfide 2.57 76 132458 21.12 ug/l 99 17) Allyl chloride 2.73 41 102498 21.22 ug/l 98 18) Methylene Chloride 2.86 84 66095 22.12 ug/l 97 19) trans-1,2-Dichloroethene 3.17 96 59201 21.54 ug/l 96 20) Diisopropyl ether 3.88 45 197528 21.89 ug/l 98 21) 1,1-Dichloroethane 3.70 63 113437 21.86 ug/l 98 22) cis-1,2-Dichloroethene 4.60 96 66460 21.45 ug/l 99 23) tert-Butyl Alcohol 3.08 59 86242 112.71 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 202856 22.05 ug/l 100 25) Chloroform 5.23 83 115225 21.55 ug/l 99 26) Cyclohexane 5.58 56 81582 21.55 ug/l # 99 29) 1,1-Dichloropropene 5.81 75 76020 21.70 ug/l 99 30) 2-Butanone 4.72 43 254364 110.04 ug/l 99 31) 2,2-Dichloropropane 4.59 77 57278 19.02 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 96828 21.73 ug/l 99 33) Carbon Tetrachloride 5.79 117 83811 21.36 ug/l 98 34) Benzene 6.15 78 245135 21.89 ug/l 99 35) Methacrylonitrile 5.07 41 54160 21.61 ug/l 98 36) 1,2-Dichloroethane 6.21 62 98420 22.21 ug/l 100 37) Trichloroethene 7.22 130 71492 21.66 ug/l 97 38) Methylcyclohexane 7.46 83 81169 21.67 ug/l 99 39) 1,2-Dichloropropane 7.53 63 62435 22.23 ug/l 100 40) Dibromomethane 7.67 93 44429 22.08 ug/l 100 41) Bromodichloromethane 7.90 83 80904 21.37 ug/l 99 42) Vinyl Acetate 3.83 43 836857 109.76 ug/l 99 43) Ethyl Acetate 4.87 43 96505 21.90 ug/l 97 44) Isopropyl Acetate 6.48 43 144583 21.43 ug/l 99 45) 1,4-Dioxane 7.76 88 34646 437.97 ug/l 100 46) Methyl methacrylate 7.79 41 77986 21.41 ug/l 99 47) n-amyl Acetate 10.91 43 120659 20.94 ug/l 100 48) t-1,3-Dichloropropene 8.44 75 86430 20.69 ug/l 100 49) cis-1,3-Dichloropropene 9.05 75 75558 20.47 ug/l 99 50) 1,1,2-Trichloroethane 9.22 97 64842 21.76 ug/l 96 51) Ethyl methacrylate 9.19 69 92522 21.54 ug/l 99 52) 1,3-Dichloropropane 9.38 76 107268 21.85 ug/l 100 53) Dibromochloromethane 9.59 129 64792 20.94 ug/l 98 54) 1,2-Dibromoethane 9.68 107 68027 21.65 ug/l 98 55) 2-Chloroethyl vinyl ether 8.32 63 245864 107.66 ug/l 100 56) Bromoform 10.87 173 51443 20.34 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 505950 111.81 ug/l 100 59) 2-Hexanone 9.51 43 378752 111.72 ug/l 100 61) Tetrachloroethene 9.34 164 80713 22.05 ug/l 100 62) Toluene 8.79 91 263134 21.74 ug/l 100 64) Chlorobenzene 10.15 112 172772 21.73 ug/l 100 65) 1,1,1,2-Tetrachloroethane 10.23 131 64741 21.55 ug/l 100 66) Ethyl Benzene 10.26 91 272869 21.73 ug/l 99 67) m/p-Xylenes 10.37 106 216741 43.22 ug/l 99 68) o-Xylene 10.71 106 108475 21.86 ug/l 99 69) Styrene 10.72 104 176030 21.50 ug/l 99 70) Isopropylbenzene 11.02 105 280460 21.94 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 92839 21.66 ug/l 99 72) 1,2,3-Trichloropropane 11.30 75 91402m 22.00 ug/l 73) Bromobenzene 11.26 156 83918 21.67 ug/l 99 74) n-propylbenzene 11.37 91 308332 21.91 ug/l 99 75) 2-Chlorotoluene 11.43 91 193122 21.88 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 234357 21.79 ug/l 100 77) t-1,4-Dichloro-2-butene 11.08 75 20871 19.54 ug/l 96 78) 4-Chlorotoluene 11.52 91 214993 21.43 ug/l 99 79) tert-butylbenzene 12.07 119 248941 21.87 ug/l 99 80) 1,2,4-Trimethylbenzene 11.81 105 241074 21.95 ug/l 99 81) sec-Butylbenzene 11.95 105 273351 21.94 ug/l 100 82) p-Isopropyltoluene 12.07 119 248941 21.87 ug/l 99 83) 1,3-Dichlorobenzene 12.03 146 144190 21.35 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 143835 21.18 ug/l 100 85) n-Butylbenzene 12.40 91 192241 21.24 ug/l 99 86) Hexachloroethane 12.60 117 36616 20.28 ug/l 97 87) 1,2-Dichlorobenzene 12.40 146 150241 21.45 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 20685 20.71 ug/l 96 89) 1,2,4-Trichlorobenzene 13.65 180 102354 20.57 ug/l 100 90) Hexachlorobutadiene 13.79 225 54647 21.46 ug/l 98 91) Naphthalene 13.84 128 317436 21.30 ug/l 100 92) 1,2,3-Trichlorobenzene 14.02 180 111392 21.17 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed