Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001626.D Acq On : 11 May 2018 03:02 Operator : JC/MD Sample : VX0510WBSD01 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 33 Sample Multiplier: 1 Quant Time: May 11 07:36:38 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 55695 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 280553 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 251917 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 122349 30.11 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 100.37% 60) 4-Bromofluorobenzene 11.15 95 118445 29.71 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 99.03% 63) Toluene-d8 8.72 98 340747 30.33 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 101.10% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 53478 19.70 ug/l 99 3) Chloromethane 1.32 50 64701 21.53 ug/l 99 4) Vinyl Chloride 1.40 62 66803 21.29 ug/l 100 5) Bromomethane 1.64 94 45330 29.23 ug/l 98 6) Chloroethane 1.73 64 43852 20.99 ug/l 94 7) Trichlorofluoromethane 1.93 101 91205 20.23 ug/l 99 8) Diethyl Ether 2.19 74 41732 21.35 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 46566 18.59 ug/l 98 10) 1,1-Dichloroethene 2.37 96 52739 20.46 ug/l 99 11) Methyl Iodide 2.51 142 69501 18.56 ug/l 98 12) Methyl Acetate 2.78 43 93076 21.24 ug/l 100 13) Acrolein 2.30 56 48713 98.02 ug/l 99 14) Acrylonitrile 3.15 53 187864 107.30 ug/l 99 15) Acetone 2.45 58 51629 109.76 ug/l 98 16) Carbon Disulfide 2.57 76 128236 20.08 ug/l 98 17) Allyl chloride 2.73 41 101630 20.67 ug/l 99 18) Methylene Chloride 2.86 84 64538 21.21 ug/l 94 19) trans-1,2-Dichloroethene 3.17 96 57861 20.68 ug/l 98 20) Diisopropyl ether 3.88 45 196373 21.38 ug/l 99 21) 1,1-Dichloroethane 3.70 63 110345 20.89 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 66206 20.99 ug/l 100 23) tert-Butyl Alcohol 3.08 59 84313 108.24 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 199841 21.34 ug/l 100 25) Chloroform 5.22 83 113646 20.88 ug/l 94 26) Cyclohexane 5.58 56 69217 17.96 ug/l # 99 29) 1,1-Dichloropropene 5.81 75 70816 20.09 ug/l 99 30) 2-Butanone 4.71 43 256188 110.15 ug/l 100 31) 2,2-Dichloropropane 4.59 77 55549 18.33 ug/l 100 32) 1,1,1-Trichloroethane 5.50 97 94114 20.99 ug/l 98 33) Carbon Tetrachloride 5.79 117 78821 19.96 ug/l 98 34) Benzene 6.15 78 243841 21.64 ug/l 99 35) Methacrylonitrile 5.07 41 54635 21.66 ug/l 93 36) 1,2-Dichloroethane 6.20 62 98327 22.06 ug/l 99 37) Trichloroethene 7.22 130 69307 20.87 ug/l 99 38) Methylcyclohexane 7.46 83 65532 17.39 ug/l 99 39) 1,2-Dichloropropane 7.52 63 60930 21.57 ug/l 99 40) Dibromomethane 7.67 93 44098 21.78 ug/l 100 41) Bromodichloromethane 7.90 83 80659 21.18 ug/l 98 42) Vinyl Acetate 3.83 43 831859 108.44 ug/l 99 43) Ethyl Acetate 4.87 43 97600 22.01 ug/l 97 44) Isopropyl Acetate 6.48 43 145852 21.49 ug/l 100 45) 1,4-Dioxane 7.76 88 35155 441.67 ug/l 98 46) Methyl methacrylate 7.79 41 79025 21.56 ug/l 95 47) n-amyl Acetate 10.91 43 118947 20.52 ug/l 99 48) t-1,3-Dichloropropene 8.44 75 86625 20.61 ug/l 94 49) cis-1,3-Dichloropropene 9.05 75 75720 20.38 ug/l 96 50) 1,1,2-Trichloroethane 9.22 97 65674 21.91 ug/l 98 51) Ethyl methacrylate 9.19 69 92039 21.30 ug/l 99 52) 1,3-Dichloropropane 9.38 76 106329 21.53 ug/l 99 53) Dibromochloromethane 9.59 129 63917 20.53 ug/l 99 54) 1,2-Dibromoethane 9.68 107 67299 21.28 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 249498 108.58 ug/l 99 56) Bromoform 10.87 173 51045 20.05 ug/l 98 58) 4-Methyl-2-Pentanone 8.66 43 503474 111.11 ug/l 100 59) 2-Hexanone 9.51 43 373257 109.95 ug/l 100 61) Tetrachloroethene 9.34 164 73846 20.15 ug/l 98 62) Toluene 8.79 91 258431 21.33 ug/l 99 64) Chlorobenzene 10.15 112 167360 21.02 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 63825 21.21 ug/l 100 66) Ethyl Benzene 10.26 91 258523 20.56 ug/l 98 67) m/p-Xylenes 10.37 106 203243 40.47 ug/l 99 68) o-Xylene 10.71 106 102199 20.57 ug/l 99 69) Styrene 10.72 104 169997 20.74 ug/l 99 70) Isopropylbenzene 11.02 105 253387 19.80 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 91693 21.36 ug/l 100 72) 1,2,3-Trichloropropane 11.30 75 89070m 21.41 ug/l 73) Bromobenzene 11.26 156 81053 20.90 ug/l 99 74) n-propylbenzene 11.37 91 273656 19.42 ug/l 100 75) 2-Chlorotoluene 11.43 91 180233 20.40 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 213968 19.86 ug/l 100 77) t-1,4-Dichloro-2-butene 11.08 75 19647 18.37 ug/l 98 78) 4-Chlorotoluene 11.52 91 203251 20.23 ug/l 100 79) tert-butylbenzene 12.07 119 218021 19.13 ug/l 100 80) 1,2,4-Trimethylbenzene 11.81 105 222051 20.19 ug/l 100 81) sec-Butylbenzene 11.95 105 232260 18.62 ug/l 100 82) p-Isopropyltoluene 12.07 119 218021 19.13 ug/l 100 83) 1,3-Dichlorobenzene 12.03 146 135477 20.03 ug/l 100 84) 1,4-Dichlorobenzene 12.10 146 137962 20.29 ug/l 99 85) n-Butylbenzene 12.40 91 161064 17.77 ug/l 99 86) Hexachloroethane 12.60 117 32853 18.17 ug/l 97 87) 1,2-Dichlorobenzene 12.40 146 144716 20.64 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 20800 20.80 ug/l 97 89) 1,2,4-Trichlorobenzene 13.65 180 98379 19.75 ug/l 99 90) Hexachlorobutadiene 13.79 225 45380 17.80 ug/l 97 91) Naphthalene 13.84 128 314233 21.06 ug/l 100 92) 1,2,3-Trichlorobenzene 14.02 180 108058 20.51 ug/l 99 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed