Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001634.D Acq On : 11 May 2018 11:13 Operator : JC/MD Sample : VSTDCCC020 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 41 Sample Multiplier: 1 Quant Time: May 11 12:25:39 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\624X051118W.M Quant Title : METHOD 624 VOLATILE ORGANIC ANALYSIS QLast Update : Fri May 11 07:16:13 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Bromochloromethane 5.03 128 56419 30.00 ug/l 0.00 28) 1,4-Difluorobenzene 6.87 114 300710 30.00 ug/l 0.00 57) Chlorobenzene-d5 10.12 117 274497 30.00 ug/l 0.00 System Monitoring Compounds 27) 1,2-Dichloroethane-d4 6.07 65 122394 29.73 ug/l 0.00 Spiked Amount 30.000 Range 50 - 169 Recovery = 99.10% 60) 4-Bromofluorobenzene 11.14 95 130834 30.12 ug/l 0.00 Spiked Amount 30.000 Range 56 - 143 Recovery = 100.40% 63) Toluene-d8 8.72 98 363141 29.66 ug/l 0.00 Spiked Amount 30.000 Range 66 - 137 Recovery = 98.87% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 65377 23.78 ug/l 99 3) Chloromethane 1.32 50 60605 19.91 ug/l 99 4) Vinyl Chloride 1.40 62 64095 20.17 ug/l 99 5) Bromomethane 1.64 94 34271 21.81 ug/l 96 6) Chloroethane 1.73 64 43582 20.60 ug/l 98 7) Trichlorofluoromethane 1.93 101 104913 22.98 ug/l 99 8) Diethyl Ether 2.19 74 40364 20.39 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.39 101 62151 24.50 ug/l 97 10) 1,1-Dichloroethene 2.38 96 54856 21.01 ug/l 99 11) Methyl Iodide 2.51 142 38501 10.15 ug/l 98 12) Methyl Acetate 2.78 43 91163 20.53 ug/l 99 13) Acrolein 2.30 56 9160 18.20 ug/l 93 14) Acrylonitrile 3.15 53 163138 91.99 ug/l 100 15) Acetone 2.45 58 54398 114.17 ug/l 99 16) Carbon Disulfide 2.57 76 127682 19.74 ug/l 100 17) Allyl chloride 2.73 41 103664 20.81 ug/l 97 18) Methylene Chloride 2.86 84 63453 20.59 ug/l 93 19) trans-1,2-Dichloroethene 3.17 96 57581 20.32 ug/l 97 20) Diisopropyl ether 3.88 45 193675 20.81 ug/l 98 21) 1,1-Dichloroethane 3.70 63 105337 19.68 ug/l 99 22) cis-1,2-Dichloroethene 4.60 96 66866 20.92 ug/l 99 23) tert-Butyl Alcohol 3.08 59 67973 86.14 ug/l # 100 24) Methyl tert-Butyl Ether 3.21 73 196758 20.74 ug/l 100 25) Chloroform 5.22 83 115816 21.00 ug/l 94 26) Cyclohexane 5.58 56 92907 23.80 ug/l # 98 29) 1,1-Dichloropropene 5.81 75 79650 21.08 ug/l 99 30) 2-Butanone 4.71 43 235121 94.32 ug/l 100 31) 2,2-Dichloropropane 4.59 77 91912 28.30 ug/l 96 32) 1,1,1-Trichloroethane 5.50 97 102307 21.29 ug/l 99 33) Carbon Tetrachloride 5.79 117 89993 21.27 ug/l 99 34) Benzene 6.15 78 241255 19.97 ug/l 98 35) Methacrylonitrile 5.07 41 50224 18.58 ug/l 97 36) 1,2-Dichloroethane 6.20 62 96812 20.26 ug/l 99 37) Trichloroethene 7.22 130 74153 20.83 ug/l 100 38) Methylcyclohexane 7.47 83 97063 24.03 ug/l 98 39) 1,2-Dichloropropane 7.52 63 61245 20.22 ug/l 99 40) Dibromomethane 7.66 93 43123 19.87 ug/l 99 41) Bromodichloromethane 7.91 83 81175 19.88 ug/l 100 42) Vinyl Acetate 3.83 43 803622 97.74 ug/l 100 43) Ethyl Acetate 4.87 43 87955 18.51 ug/l 97 44) Isopropyl Acetate 6.48 43 136090 18.71 ug/l 99 45) 1,4-Dioxane 7.76 88 28108 329.47 ug/l 97 46) Methyl methacrylate 7.79 41 74060 18.85 ug/l 99 47) n-amyl Acetate 10.91 43 119095 19.17 ug/l 99 48) t-1,3-Dichloropropene 8.44 75 92958 20.63 ug/l 99 49) cis-1,3-Dichloropropene 9.05 75 82127 20.63 ug/l 100 50) 1,1,2-Trichloroethane 9.22 97 64797 20.17 ug/l 97 51) Ethyl methacrylate 9.19 69 89206 19.26 ug/l 99 52) 1,3-Dichloropropane 9.38 76 105474 19.92 ug/l 99 53) Dibromochloromethane 9.59 129 65501 19.63 ug/l 98 54) 1,2-Dibromoethane 9.68 107 66677 19.67 ug/l 99 55) 2-Chloroethyl vinyl ether 8.32 63 232106 94.24 ug/l 100 56) Bromoform 10.87 173 50830 18.63 ug/l 99 58) 4-Methyl-2-Pentanone 8.66 43 456797 92.52 ug/l 100 59) 2-Hexanone 9.51 43 342588 92.61 ug/l 100 61) Tetrachloroethene 9.34 164 86252 21.60 ug/l 99 62) Toluene 8.79 91 272813 20.66 ug/l 99 64) Chlorobenzene 10.15 112 181405 20.91 ug/l 99 65) 1,1,1,2-Tetrachloroethane 10.23 131 65686 20.04 ug/l 99 66) Ethyl Benzene 10.26 91 299439 21.85 ug/l 97 67) m/p-Xylenes 10.37 106 240426 43.94 ug/l 97 68) o-Xylene 10.71 106 114853 21.22 ug/l 100 69) Styrene 10.72 104 186578 20.89 ug/l 100 70) Isopropylbenzene 11.02 105 313399 22.47 ug/l 100 71) 1,1,2,2-Tetrachloroethane 11.27 83 89202 19.07 ug/l 99 72) 1,2,3-Trichloropropane 11.30 75 86980m 19.19 ug/l 73) Bromobenzene 11.26 156 87152 20.62 ug/l 100 74) n-propylbenzene 11.37 91 350889 22.86 ug/l 99 75) 2-Chlorotoluene 11.43 91 210621 21.87 ug/l 99 76) 1,3,5-Trimethylbenzene 11.51 105 263445 22.45 ug/l 99 77) t-1,4-Dichloro-2-butene 11.08 75 22325 19.15 ug/l 95 78) 4-Chlorotoluene 11.52 91 243925 22.28 ug/l 99 79) tert-butylbenzene 12.07 119 292785 23.58 ug/l 100 80) 1,2,4-Trimethylbenzene 11.81 105 270243 22.55 ug/l 100 81) sec-Butylbenzene 11.95 105 321550 23.66 ug/l 100 82) p-Isopropyltoluene 12.07 119 292785 23.58 ug/l 100 83) 1,3-Dichlorobenzene 12.03 146 158176 21.46 ug/l 99 84) 1,4-Dichlorobenzene 12.10 146 159558 21.54 ug/l 99 85) n-Butylbenzene 12.40 91 236516 23.95 ug/l 100 86) Hexachloroethane 12.60 117 42228 21.43 ug/l 97 87) 1,2-Dichlorobenzene 12.40 146 161232 21.10 ug/l 100 88) 1,2-Dibromo-3-Chloropropan 13.01 75 19966 18.32 ug/l 99 89) 1,2,4-Trichlorobenzene 13.65 180 118599 21.85 ug/l 100 90) Hexachlorobutadiene 13.79 225 65472 23.57 ug/l 97 91) Naphthalene 13.84 128 322452 19.83 ug/l 99 92) 1,2,3-Trichlorobenzene 14.02 180 122219 21.29 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed