Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001636.D Acq On : 11 May 2018 13:08 Operator : JC/MD Sample : VSTDCCC050 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 2 Sample Multiplier: 1 Quant Time: May 12 03:34:48 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 258406 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 322716 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 302195 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.08 152 221504 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 161765 43.55 ug/l 0.00 Spiked Amount 50.000 Recovery = 87.10% 35) Dibromofluoromethane 5.51 113 137082 47.76 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.52% 50) Toluene-d8 8.72 98 492679 47.02 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.04% 62) 4-Bromofluorobenzene 11.14 95 186869 46.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.92% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 170423 48.99 ug/l 98 3) Chloromethane 1.32 50 153069 45.18 ug/l 100 4) Vinyl Chloride 1.41 62 167535 47.38 ug/l 99 5) Bromomethane 1.64 94 72548 44.45 ug/l 100 6) Chloroethane 1.71 64 110325 47.21 ug/l 100 7) Trichlorofluoromethane 1.93 101 261100 49.07 ug/l 99 8) Diethyl Ether 2.19 74 100930 48.39 ug/l 98 9) 1,1,2-Trichlorotrifluoroet 2.39 101 160389 51.41 ug/l 99 10) Methyl Iodide 2.51 142 159185 35.36 ug/l 99 11) Tert butyl alcohol 3.08 59 171216 218.64 ug/l 100 12) 1,1-Dichloroethene 2.37 96 139255 48.70 ug/l 99 13) Acrolein 2.30 56 23546 147.76 ug/l 98 14) Allyl chloride 2.73 41 263759 49.47 ug/l 100 15) Acrylonitrile 3.15 53 402493 227.46 ug/l 100 16) Acetone 2.45 43 406497 241.03 ug/l 98 17) Carbon Disulfide 2.57 76 338108 46.46 ug/l 100 18) Methyl Acetate 2.78 43 222727 50.27 ug/l 99 19) Methyl tert-butyl Ether 3.21 73 494334 49.65 ug/l 97 20) Methylene Chloride 2.85 84 154825 46.37 ug/l 97 21) trans-1,2-Dichloroethene 3.17 96 149401 46.82 ug/l 99 22) Diisopropyl ether 3.87 45 514486 51.65 ug/l 97 23) Vinyl Acetate 3.83 43 2131789 256.80 ug/l 100 24) 1,1-Dichloroethane 3.70 63 280853 50.47 ug/l 99 25) 2-Butanone 4.71 43 586534 240.59 ug/l 99 26) 2,2-Dichloropropane 4.59 77 242567 56.45 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 173091 50.93 ug/l 98 28) Bromochloromethane 5.03 49 118547 49.14 ug/l 99 29) Tetrahydrofuran 5.17 42 355543 227.94 ug/l 100 30) Chloroform 5.22 83 297060 51.83 ug/l 99 31) Cyclohexane 5.57 56 248581 52.01 ug/l 95 32) 1,1,1-Trichloroethane 5.50 97 266531 53.21 ug/l 98 36) 1,1-Dichloropropene 5.80 75 216033 52.63 ug/l 99 37) Ethyl Acetate 4.87 43 218829 48.63 ug/l 100 38) Carbon Tetrachloride 5.79 117 241924 55.26 ug/l 99 39) Methylcyclohexane 7.46 83 268099 55.24 ug/l 99 40) Benzene 6.15 78 639116 53.30 ug/l 98 41) Methacrylonitrile 5.07 41 128118 49.76 ug/l 99 42) 1,2-Dichloroethane 6.20 62 240759 52.24 ug/l 100 43) Isopropyl Acetate 6.47 43 363300 52.59 ug/l 99 44) Trichloroethene 7.22 130 195770 53.42 ug/l 100 45) 1,2-Dichloropropane 7.52 63 160736 53.77 ug/l 99 46) Dibromomethane 7.66 93 109591 51.79 ug/l 99 47) Bromodichloromethane 7.90 83 221456 56.55 ug/l 99 48) Methyl methacrylate 7.78 41 193153 51.35 ug/l 99 49) 1,4-Dioxane 7.76 88 77646 955.46 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1173073 255.55 ug/l 100 52) Toluene 8.79 92 428400 54.64 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 260136 58.77 ug/l 97 54) cis-1,3-Dichloropropene 9.05 75 243808 53.13 ug/l 98 55) 1,1,2-Trichloroethane 9.22 97 171668 54.35 ug/l 98 56) Ethyl methacrylate 9.19 69 252182 55.39 ug/l 100 57) 1,3-Dichloropropane 9.38 76 269945 51.69 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 626595 280.58 ug/l 100 59) 2-Hexanone 9.51 43 881143 250.67 ug/l 99 60) Dibromochloromethane 9.59 129 182350 56.37 ug/l 99 61) 1,2-Dibromoethane 9.68 107 173468 52.31 ug/l 99 64) Tetrachloroethene 9.34 164 230373 54.69 ug/l 98 65) Chlorobenzene 10.14 112 475417 53.64 ug/l 99 66) 1,1,1,2-Tetrachloroethane 10.23 131 179619 56.66 ug/l 100 67) Ethyl Benzene 10.26 91 795259 54.75 ug/l 100 68) m/p-Xylenes 10.37 106 635633 110.74 ug/l 99 69) o-Xylene 10.70 106 310193 55.61 ug/l 100 70) Styrene 10.72 104 514937 56.82 ug/l 98 71) Bromoform 10.87 173 149785 49.19 ug/l 100 73) Isopropylbenzene 11.02 105 848492 55.33 ug/l 100 74) N-amyl acetate 6.47 43 363300 52.16 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 239133 52.80 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 228201m 50.80 ug/l 77) Bromobenzene 11.26 156 235517 52.83 ug/l 99 78) n-propylbenzene 11.37 91 954445 57.16 ug/l 99 79) 2-Chlorotoluene 11.43 91 556491 54.16 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 710576 55.66 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 68618 48.81 ug/l 97 82) 4-Chlorotoluene 11.52 91 651730 54.98 ug/l 99 83) tert-Butylbenzene 11.77 119 705110 55.51 ug/l 100 84) 1,2,4-Trimethylbenzene 11.81 105 732436 55.82 ug/l 99 85) sec-Butylbenzene 11.95 105 876505 57.49 ug/l 100 86) p-Isopropyltoluene 12.07 119 813681 58.17 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 436393 54.76 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 439500 54.07 ug/l 100 89) n-Butylbenzene 12.40 91 680862 58.75 ug/l 100 90) Hexachloroethane 12.60 117 124770 59.24 ug/l 100 91) 1,2-Dichlorobenzene 12.40 146 436339 53.82 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 53660 53.93 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 343600 57.91 ug/l 100 94) Hexachlorobutadiene 13.79 225 189658 58.42 ug/l 100 95) Naphthalene 13.84 128 917261 55.90 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 347892 57.15 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed