Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001638.D Acq On : 11 May 2018 14:38 Operator : JC/MD Sample : VX0511WBS02 Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 4 Sample Multiplier: 1 Quant Time: May 12 05:59:51 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 280261 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 355144 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 329307 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 236982 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 182247 45.24 ug/l 0.00 Spiked Amount 50.000 Recovery = 90.48% 35) Dibromofluoromethane 5.51 113 150411 47.61 ug/l 0.00 Spiked Amount 50.000 Recovery = 95.22% 50) Toluene-d8 8.72 98 537831 46.64 ug/l 0.00 Spiked Amount 50.000 Recovery = 93.28% 62) 4-Bromofluorobenzene 11.14 95 204799 46.27 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.54% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 76117 20.18 ug/l 98 3) Chloromethane 1.32 50 69223 18.84 ug/l 100 4) Vinyl Chloride 1.40 62 74521 19.43 ug/l 99 5) Bromomethane 1.64 94 41176 21.50 ug/l 97 6) Chloroethane 1.72 64 52158 20.58 ug/l 99 7) Trichlorofluoromethane 1.93 101 118151 20.47 ug/l 99 8) Diethyl Ether 2.19 74 44680 19.75 ug/l 95 9) 1,1,2-Trichlorotrifluoroet 2.39 101 71812 21.22 ug/l 99 10) Methyl Iodide 2.51 142 59379 12.16 ug/l 99 11) Tert butyl alcohol 3.07 59 84453 99.44 ug/l 99 12) 1,1-Dichloroethene 2.37 96 61270 19.76 ug/l 97 13) Acrolein 2.29 56 10452 53.24 ug/l 93 14) Allyl chloride 2.73 41 117049 20.24 ug/l 99 15) Acrylonitrile 3.15 53 187154 97.52 ug/l 99 16) Acetone 2.45 43 192427 105.20 ug/l 97 17) Carbon Disulfide 2.57 76 143613 18.20 ug/l 98 18) Methyl Acetate 2.78 43 104746 21.80 ug/l 98 19) Methyl tert-butyl Ether 3.21 73 223367 20.69 ug/l 99 20) Methylene Chloride 2.86 84 72197 19.94 ug/l 96 21) trans-1,2-Dichloroethene 3.17 96 66793 19.30 ug/l 98 22) Diisopropyl ether 3.87 45 231030 21.38 ug/l 98 23) Vinyl Acetate 3.82 43 948140 105.31 ug/l 99 24) 1,1-Dichloroethane 3.70 63 125305 20.76 ug/l 99 25) 2-Butanone 4.71 43 271541 102.70 ug/l 99 26) 2,2-Dichloropropane 4.59 77 105111 22.55 ug/l 99 27) cis-1,2-Dichloroethene 4.60 96 76559 20.77 ug/l 98 28) Bromochloromethane 5.02 49 55356 21.16 ug/l 98 29) Tetrahydrofuran 5.17 42 163833 96.84 ug/l 100 30) Chloroform 5.22 83 131519 21.16 ug/l 99 31) Cyclohexane 5.58 56 107742 20.79 ug/l 96 32) 1,1,1-Trichloroethane 5.49 97 117072 21.55 ug/l 100 36) 1,1-Dichloropropene 5.80 75 93917 20.79 ug/l 99 37) Ethyl Acetate 4.87 43 99989 20.19 ug/l 99 38) Carbon Tetrachloride 5.79 117 104654 21.72 ug/l 99 39) Methylcyclohexane 7.46 83 114255 21.39 ug/l 99 40) Benzene 6.15 78 280087 21.23 ug/l 99 41) Methacrylonitrile 5.07 41 58016 20.48 ug/l 99 42) 1,2-Dichloroethane 6.20 62 109018 21.50 ug/l 100 43) Isopropyl Acetate 6.47 43 159425 20.97 ug/l 100 44) Trichloroethene 7.21 130 85462 21.19 ug/l 99 45) 1,2-Dichloropropane 7.52 63 69112 21.01 ug/l 98 46) Dibromomethane 7.67 93 48995 21.04 ug/l 99 47) Bromodichloromethane 7.90 83 94335 21.89 ug/l 99 48) Methyl methacrylate 7.78 41 85439 20.64 ug/l 100 49) 1,4-Dioxane 7.76 88 35522 397.20 ug/l 98 51) 4-Methyl-2-Pentanone 8.66 43 531322 105.18 ug/l 99 52) Toluene 8.79 92 186253 21.59 ug/l 99 53) t-1,3-Dichloropropene 8.44 75 108555 22.29 ug/l 99 54) cis-1,3-Dichloropropene 9.05 75 96254 20.51 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 76075 21.89 ug/l 98 56) Ethyl methacrylate 9.19 69 106698 21.29 ug/l 99 57) 1,3-Dichloropropane 9.38 76 121807 21.19 ug/l 100 58) 2-Chloroethyl Vinyl ether 8.32 63 243564 99.11 ug/l 99 59) 2-Hexanone 9.50 43 401179 103.71 ug/l 100 60) Dibromochloromethane 9.59 129 76399 21.46 ug/l 97 61) 1,2-Dibromoethane 9.68 107 76800 21.04 ug/l 100 64) Tetrachloroethene 9.34 164 100576 21.91 ug/l 99 65) Chlorobenzene 10.14 112 210478 21.79 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 77771 22.51 ug/l 99 67) Ethyl Benzene 10.26 91 345503 21.83 ug/l 100 68) m/p-Xylenes 10.37 106 276028 44.13 ug/l 100 69) o-Xylene 10.70 106 132786 21.84 ug/l 99 70) Styrene 10.72 104 219277 22.20 ug/l 99 71) Bromoform 10.86 173 59924 20.32 ug/l 100 73) Isopropylbenzene 11.02 105 367011 22.37 ug/l 100 74) N-amyl acetate 6.47 43 159425 21.39 ug/l # 100 75) 1,1,2,2-Tetrachloroethane 11.27 83 105228 21.72 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 103033m 21.44 ug/l 77) Bromobenzene 11.26 156 101977 21.38 ug/l 99 78) n-propylbenzene 11.37 91 407463 22.81 ug/l 99 79) 2-Chlorotoluene 11.43 91 242531 22.06 ug/l 100 80) 1,3,5-Trimethylbenzene 11.51 105 306013 22.40 ug/l 99 81) trans-1,4-Dichloro-2-buten 11.08 75 26657 20.46 ug/l 94 82) 4-Chlorotoluene 11.52 91 280026 22.08 ug/l 100 83) tert-Butylbenzene 11.77 119 300931 22.14 ug/l 99 84) 1,2,4-Trimethylbenzene 11.81 105 316666 22.56 ug/l 99 85) sec-Butylbenzene 11.95 105 378993 23.23 ug/l 99 86) p-Isopropyltoluene 12.07 119 347220 23.20 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 186088 21.83 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 189703 21.81 ug/l 99 89) n-Butylbenzene 12.40 91 282110 22.75 ug/l 100 90) Hexachloroethane 12.60 117 51319 22.77 ug/l 98 91) 1,2-Dichlorobenzene 12.40 146 188152 21.69 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 23133 21.73 ug/l 97 93) 1,2,4-Trichlorobenzene 13.65 180 141342 22.27 ug/l 99 94) Hexachlorobutadiene 13.79 225 80586 23.20 ug/l 99 95) Naphthalene 13.84 128 384303 21.89 ug/l 100 96) 1,2,3-Trichlorobenzene 14.03 180 145143 22.28 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed