Quantitation Report (QT Reviewed) Data Path : W:\HPCHEM1\MSVOA_X\DATA\VX051118\ Data File : VX001655.D Acq On : 11 May 2018 22:22 Operator : JC/MD Sample : J2741-08MS Misc : 5.0mL/MSVOA_X/WATER ALS Vial : 21 Sample Multiplier: 1 Quant Time: May 12 07:26:58 2018 Quant Method : W:\HPCHEM1\MSVOA_X\METHOD\82X050518W.M Quant Title : SW846 8260 QLast Update : Sun May 06 07:59:25 2018 Response via : Initial Calibration Internal Standards R.T. QIon Response Conc Units Dev(Min) -------------------------------------------------------------------------- 1) Pentafluorobenzene 5.67 168 224552 50.00 ug/l 0.00 34) 1,4-Difluorobenzene 6.87 114 293588 50.00 ug/l 0.00 63) Chlorobenzene-d5 10.12 117 275348 50.00 ug/l 0.00 72) 1,4-Dichlorobenzene-d4 12.09 152 196006 50.00 ug/l 0.00 System Monitoring Compounds 33) 1,2-Dichloroethane-d4 6.07 65 151938 47.08 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.16% 35) Dibromofluoromethane 5.51 113 129155 49.46 ug/l 0.00 Spiked Amount 50.000 Recovery = 98.92% 50) Toluene-d8 8.72 98 449490 47.16 ug/l 0.00 Spiked Amount 50.000 Recovery = 94.32% 62) 4-Bromofluorobenzene 11.14 95 168611 46.08 ug/l 0.00 Spiked Amount 50.000 Recovery = 92.16% Target Compounds Qvalue 2) Dichlorodifluoromethane 1.20 85 145593 48.16 ug/l 100 3) Chloromethane 1.32 50 142166 48.29 ug/l 98 4) Vinyl Chloride 1.40 62 410288 133.54 ug/l 100 5) Bromomethane 1.64 94 65184 46.08 ug/l 97 6) Chloroethane 1.72 64 104491 51.45 ug/l 96 7) Trichlorofluoromethane 1.93 101 237973 51.46 ug/l 99 8) Diethyl Ether 2.19 74 95988 52.96 ug/l 99 9) 1,1,2-Trichlorotrifluoroet 2.38 101 138280 51.01 ug/l 100 10) Methyl Iodide 2.51 142 156230 39.94 ug/l 99 11) Tert butyl alcohol 3.09 59 163305 239.98 ug/l 98 12) 1,1-Dichloroethene 2.37 96 135144 54.39 ug/l 99 13) Acrolein 2.30 56 23694 173.04 ug/l 97 14) Allyl chloride 2.73 41 244130 52.69 ug/l 98 15) Acrylonitrile 3.15 53 414277 269.41 ug/l 99 16) Acetone 2.45 43 349495 238.47 ug/l 99 17) Carbon Disulfide 2.57 76 302426 47.83 ug/l 99 18) Methyl Acetate 2.78 43 219746 57.07 ug/l 100 19) Methyl tert-butyl Ether 3.21 73 466868 53.97 ug/l 98 20) Methylene Chloride 2.86 84 147967 50.99 ug/l 99 21) trans-1,2-Dichloroethene 3.17 96 143341 51.69 ug/l 98 22) Diisopropyl ether 3.88 45 468687 54.15 ug/l 100 23) Vinyl Acetate 3.83 43 1863262 258.29 ug/l 100 24) 1,1-Dichloroethane 3.70 63 275055 56.88 ug/l 99 25) 2-Butanone 4.72 43 549423 259.35 ug/l 99 26) 2,2-Dichloropropane 4.59 77 174760 46.80 ug/l # 1 27) cis-1,2-Dichloroethene 4.60 96 2758213 933.95 ug/l 86 28) Bromochloromethane 5.03 49 115280 54.99 ug/l 99 29) Tetrahydrofuran 5.18 42 357933 264.07 ug/l 100 30) Chloroform 5.22 83 278010 55.82 ug/l 99 31) Cyclohexane 5.58 56 212822 51.25 ug/l 98 32) 1,1,1-Trichloroethane 5.50 97 247536 56.86 ug/l 99 36) 1,1-Dichloropropene 5.81 75 191425 51.26 ug/l 100 37) Ethyl Acetate 4.87 43 204003 49.83 ug/l # 81 38) Carbon Tetrachloride 5.79 117 220816 55.44 ug/l 99 39) Methylcyclohexane 7.46 83 217512 49.26 ug/l 98 40) Benzene 6.15 78 589915 54.08 ug/l 99 41) Methacrylonitrile 5.07 41 125925 53.76 ug/l 99 42) 1,2-Dichloroethane 6.21 62 228384 54.47 ug/l 100 43) Isopropyl Acetate 6.48 43 335310 53.36 ug/l 99 44) Trichloroethene 7.22 130 181810 54.53 ug/l 100 45) 1,2-Dichloropropane 7.52 63 151188 55.60 ug/l 99 46) Dibromomethane 7.67 93 105273 54.68 ug/l 99 47) Bromodichloromethane 7.90 83 207327 58.19 ug/l 99 48) Methyl methacrylate 7.79 41 186308 54.45 ug/l 99 49) 1,4-Dioxane 7.76 88 71501 967.14 ug/l 99 51) 4-Methyl-2-Pentanone 8.66 43 1165569 279.11 ug/l 100 52) Toluene 8.79 92 390223 54.71 ug/l 100 53) t-1,3-Dichloropropene 8.44 75 223178 55.43 ug/l 96 54) cis-1,3-Dichloropropene 9.05 75 211767 50.83 ug/l 99 55) 1,1,2-Trichloroethane 9.22 97 158018 54.99 ug/l 97 56) Ethyl methacrylate 9.19 69 227373 54.89 ug/l 99 57) 1,3-Dichloropropane 9.38 76 258927 54.50 ug/l 100 59) 2-Hexanone 9.51 43 851678 266.33 ug/l 100 60) Dibromochloromethane 9.59 129 170445 57.92 ug/l 99 61) 1,2-Dibromoethane 9.68 107 164802 54.62 ug/l 100 64) Tetrachloroethene 9.34 164 202437 52.75 ug/l 98 65) Chlorobenzene 10.15 112 436288 54.03 ug/l 100 66) 1,1,1,2-Tetrachloroethane 10.23 131 167728 58.07 ug/l 100 67) Ethyl Benzene 10.26 91 718827 54.31 ug/l 100 68) m/p-Xylenes 10.37 106 574552 109.86 ug/l 98 69) o-Xylene 10.70 106 280453 55.18 ug/l 100 70) Styrene 10.72 104 464173 56.21 ug/l 99 71) Bromoform 10.87 173 138487 49.86 ug/l 100 73) Isopropylbenzene 11.02 105 751548 55.39 ug/l 100 74) N-amyl acetate 6.48 43 335310 54.41 ug/l # 99 75) 1,1,2,2-Tetrachloroethane 11.27 83 229984 57.39 ug/l 99 76) 1,2,3-Trichloropropane 11.30 75 216366m 54.43 ug/l 77) Bromobenzene 11.26 156 213442 54.11 ug/l 99 78) n-propylbenzene 11.37 91 826827 55.96 ug/l 99 79) 2-Chlorotoluene 11.43 91 496009 54.55 ug/l 99 80) 1,3,5-Trimethylbenzene 11.51 105 623356 55.18 ug/l 100 81) trans-1,4-Dichloro-2-buten 11.08 75 58878 47.46 ug/l 99 82) 4-Chlorotoluene 11.52 91 571965 54.53 ug/l 99 83) tert-Butylbenzene 11.77 119 642341 57.14 ug/l 98 84) 1,2,4-Trimethylbenzene 11.81 105 646734 55.70 ug/l 100 85) sec-Butylbenzene 11.95 105 754630 55.93 ug/l 99 86) p-Isopropyltoluene 12.07 119 694161 56.08 ug/l 100 87) 1,3-Dichlorobenzene 12.03 146 379249 53.78 ug/l 100 88) 1,4-Dichlorobenzene 12.10 146 386927 53.80 ug/l 99 89) n-Butylbenzene 12.40 91 552585 53.88 ug/l 100 90) Hexachloroethane 12.60 117 111842 60.01 ug/l 99 91) 1,2-Dichlorobenzene 12.40 146 390575 54.44 ug/l 100 92) 1,2-Dibromo-3-Chloropropan 13.01 75 51690 58.71 ug/l 99 93) 1,2,4-Trichlorobenzene 13.65 180 287074 54.68 ug/l 99 94) Hexachlorobutadiene 13.79 225 150855 52.52 ug/l 100 95) Naphthalene 13.84 128 839842 57.84 ug/l 100 96) 1,2,3-Trichlorobenzene 14.02 180 301769 56.02 ug/l 100 -------------------------------------------------------------------------- (#) = qualifier out of range (m) = manual integration (+) = signals summed